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प्रश्न
Which of the following transition metals shows +1 and +2 oxidation states?
पर्याय
Mn
Zn
Sc
Cu
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उत्तर
Cu
Explanation:
Cu typically exhibits the +1 oxidation state. This is due to the fact that Cu (+1) has an electrical configuration of [Ar]3d10. It is extremely stable due to the entirely filled d-orbital. Furthermore, Cu has a +2 oxidation state.
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संबंधित प्रश्न
In 3d series (Sc to Zn), which element has the lowest enthalpy of atomisation and why?
Read the passage given below and answer the following question:
The transition metals when exposed to oxygen at low and intermediate temperatures form thin, protective oxide films of up to some thousands of Angstroms in thickness. Transition metal oxides lie between the extremes of ionic and covalent binary compounds formed by elements from the left or right side of the periodic table. They range from metallic to semiconducting and deviate by both large and small degrees from stoichiometry. Since electron bonding levels are involved, the cations exist in various valence states and hence give rise to a large number of oxides. The crystal structures are often classified by considering a cubic or hexagonal close-packed lattice of one set of ions with the other set of ions filling the octahedral or tetrahedral interstices. The actual oxide structures, however, generally show departures from such regular arrays due in part to distortions caused by packing of ions of different size and to ligand field effects. These distortions depend not only on the number of d-electrons but also on the valence and the position of the transition metal in a period or group.
In the following questions, a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices on the basis of the above passage.
Assertion: Crystal structure of oxides of transition metals often show defects.
Reason: Ligand field effect cause distortions in crystal structures.
Why is \[\ce{HCl}\] not used to make the medium acidic in oxidation reactions of \[\ce{KMnO4}\] in acidic medium?
Match the properties given in Column I with the metals given in Column II.
| Column I (Property) | Column II (Metal) | |
| (i) | Element with highest second ionisation enthalpy |
(a) \[\ce{Co}\] |
| (ii) | Element with highest third ionisation enthalpy |
(b) \[\ce{Cr}\] |
| (iii) | \[\ce{M}\] in \[\ce{M(CO)6}\] is | (c) \[\ce{Cu}\] |
| (iv) | Element with highest heat of atomisation |
(d) \[\ce{Zn}\] |
| (e) \[\ce{Ni}\] |
Identify A to E and also explain the reactions involved.
The orientation of an atomic orbital is governed by
Give reasons for the following statement:
Transition metals and most of their compounds show paramagnetic behaviour.
Give reasons for the following statement:
Zn, Cd, and Hg are soft metals.
Give reason for the following statement:
Physical and chemical properties of the 4d and 5d series of the transition elements are quite similar to expected.
Which one among the following metals of the 3d series has the lowest melting point?
