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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Why do the transition elements have higher enthalpies of atomisation?

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प्रश्न

Why do the transition elements have higher enthalpies of atomisation?

Explain giving reasons:

The enthalpies of atomisation of the transition metals are high.

How would you account for the following?

The transition elements exhibit high enthalpies of atomization.

How would you account for the following:

The transition elements have high enthalpies of atomization?

Give reasons for the following:

Transition elements have high enthalpies of atomization.

स्पष्ट करा
कारण सांगा
लघु उत्तर
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उत्तर

  1. Transition elements have high enthalpies of atomization due to the presence of many unpaired electrons in their atoms.
  2. Unpaired electrons lead to strong interatomic interactions and stronger metallic bonding between atoms.
  3. The stronger the metallic bonds, the more energy is required to break these bonds, resulting in higher enthalpies of atomization.
  4. Elements of the second and third transition series have even higher enthalpies due to more frequent metal-metal bonding.
  5. This strong bonding also explains their high melting and boiling points.
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संबंधित प्रश्‍न

Which metal in the first transition series (3d series) exhibits + 1 oxidation state most frequently and why?


How would you account for the following? 

Transition metals exhibit variable oxidation states.

 


 
 
 

Complete the following chemical equations:

`(i) Cr_2O_7^(2-)+6Fe^(2+)+14H^+ ->`

`(ii) 2CrO_4^(2-)+2H^+ ->`

`(iii) 2MnO_4^-+5C_2O_4^(2-)+16H^+ ->`

 
 
 

Why is the highest oxidation state of a metal exhibited in its oxide or fluoride only?


Complete and balance the following chemical equations

`Fe^(2+) + MnO_4^(-) + H^+ ->`


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Why do transition elements show variable oxidation states ? In 3d series (Sc to Zn), which elements shows the maximum number of oxidation state and why ?


Explain why transition metals and their compounds act as a catalyst.


When a brown compound of manganese (A) is treated with \[\ce{HCl}\] it gives a gas (B). The gas taken in excess, reacts with \[\ce{NH3}\] to give an explosive compound (C). Identify compounds A, B and C.


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Column I
(Aqueous solution of salt)
Column II
(Colour)
(i) \[\ce{FeSO2.7H2O}\] (a) Green
(ii) \[\ce{NiCl2.4H2O}\] (b) Light pink
(iii) \[\ce{MnCl2.4H2O}\] (c) Blue
(iv) \[\ce{CoC12,6H2O}\] (d) Pale green
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\[\ce{Sn^{2+}_{ (aq)} + 2e^- -> Sn_{(s)}}\]; E0 = −0.14 V

\[\ce{Fe^{3+}_{ (aq)} + e^- -> Fe^{2+}_{ (aq)}}\]; E0 = +0.77 V

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Oxidation states


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