मराठी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

In what way is the electronic configuration of the transition elements different from that of the non-transition elements?

Advertisements
Advertisements

प्रश्न

In what way is the electronic configuration of the transition elements different from that of the non-transition elements?

लघु उत्तर
Advertisements

उत्तर

The general electronic configuration of transition elements is (n – 1)d1–10 ns1–2 (or ns0–2), meaning they have an incompletely filled d-subshell in their atomic or common ionic states. In contrast, non-transition elements either lack d-orbitals or have completely filled d-orbitals (d10), and their valence shell configuration is typically ns1−2 or ns1−6.

shaalaa.com
  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 4: d-and ƒ-Block Elements - 'NCERT TEXT-BOOK, Exercises [पृष्ठ ५०६]

APPEARS IN

नूतन Chemistry [English] Class 12 ISC
पाठ 4 d-and ƒ-Block Elements
'NCERT TEXT-BOOK, Exercises | Q 8.9 | पृष्ठ ५०६
एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 4 The d-block and f-block Elements
Exercises | Q 4.9 | पृष्ठ ११५

संबंधित प्रश्‍न

 
 
 

Complete the following chemical equations:

`(i) Cr_2O_7^(2-)+6Fe^(2+)+14H^+ ->`

`(ii) 2CrO_4^(2-)+2H^+ ->`

`(iii) 2MnO_4^-+5C_2O_4^(2-)+16H^+ ->`

 
 
 

`E_((M^(2+)/M)`

Cr Mn Fe Co Ni Cu
-0.91 -1.18 -0.44 -0.28 -0.25 -0.34

From the given data of E0 values, answer the following questions :

(1) Why is `E_(((Cu^(2+))/(Cu)))` value exceptionally positive

(2) Why is `E_(((Mn^(2+))/(Mn)))` value is highly negative as compared to other elements

(3) Which is the stronger reducing agents Cr2+ or Fe2+ ? Give Reason.


Account for the following : 
 Ti4+ is colourless whereas V4+  is coloured in an aqueous solutions. 


Transition elements form binary compounds with halogens. Which of the following elements will form \[\ce{MF3}\] type compounds?

(i) \[\ce{Cr}\]

(ii) \[\ce{Co}\]

(iii) \[\ce{Cu}\]

(iv) \[\ce{Ni}\]


Which of the following will not act as oxidising agents?

(i) \[\ce{CrO3}\]

(ii) \[\ce{MoO3}\]

(iii) \[\ce{WO3}\]

(iv) \[\ce{CrO^{2-}4}\]


Reactivity of transition elements decreases almost regularly from Sc to Cu. Explain.


When an oxide of manganese (A) is fused with KOH in the presence of an oxidising agent and dissolved in water, it gives a dark green solution of compound (B). Compound (B) disproportionates in neutral or acidic solution to give purple compound (C). An alkaline solution of compound (C) oxidises potassium iodide solution to a compound (D) and compound (A) is also formed. Identify compounds A to D and also explain the reactions involved.


Answer the following question:

Which element of the first transition series has highest third ionisation enthalpy?


A violet compound of manganese (A) decomposes on heating to liberate oxygen and compounds (B) and (C) of manganese are formed. Compound (C) reacts with KOH in the presence of potassium nitrate to give compound (B). On heating compound (C) with conc. \[\ce{H2SO4}\] and \[\ce{NaCl}\], chlorine gas is liberated and a compound (D) of manganese along with other products is formed. Identify compounds A to D and also explain the reactions involved.


A metallic ion 'M' reacts with chloride ion to form white precipitate which is readily soluble in aqueous ammonia. Identify 'M'?


Which of the following ions will exhibit colour in aqueous solution?


Give reasons for the following statement:

Zn, Cd, and Hg are soft metals.


How is the variability in oxidation states of transition metals different from that of p-block elements?


Which of the following ions acts as a typical transition metal ion?


A transition element X has an electronic configuration [Ar]4s23d3. Predict its likely oxidation states.


Consider the following standard electrode potential values:

\[\ce{Sn^{2+}_{ (aq)} + 2e^- -> Sn_{(s)}}\]; E0 = −0.14 V

\[\ce{Fe^{3+}_{ (aq)} + e^- -> Fe^{2+}_{ (aq)}}\]; E0 = +0.77 V

What is the cell reaction and potential for the spontaneous reaction that occurs?


A pair of coloured ions is ______.


Give a reason for the following:

Zinc, cadmium and mercury are considered as d-block elements but not regarded as transition elements.


Describe the oxidising action of potassium dichromate and write the ionic equation for its reaction with iron (II) solution.


‘Spin only’ magnetic moment is the same for which of the following ions?

  1. Ti3+
  2. Cr2+
  3. Mn2+
  4. Fe2+
  5. Sc3+

Choose the most appropriate answer from the options given below:


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×