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प्रश्न
Match the catalysts given in Column I with the processes given in Column II.
| Column I (Catalyst) | Column II (Process) |
| (i) \[\ce{Ni}\] in the presence of hydrogen | (a) Zieglar Natta catalyst |
| (ii) \[\ce{Cu2C12}\] | (b) Contact process |
| (iii) \[\ce{V2O5}\] | (c) Vegetable oil to ghee |
| (iv) Finely divided iron | (d) Sandmeyer reaction |
| (v) \[\ce{TiCl4 + Al (CH3)3}\] | (e) Haber's Process |
| (f) Decomposition of KCIO3 |
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उत्तर
| Column I (Catalyst) | Column II (Process) |
| (i) \[\ce{Ni}\] in the presence of hydrogen | (c) Vegetable oil to ghee |
| (ii) \[\ce{Cu2C12}\] | (d) Sandmeyer reaction |
| (iii) \[\ce{V2O5}\] | (b) Contact process |
| (iv) Finely divided iron | (e) Haber's Process |
| (v) \[\ce{TiCl4 + Al (CH3)3}\] | (a) Zieglar Natta catalyst |
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संबंधित प्रश्न
How would you account for the following: Transition metals form complex compounds.
How would you account for the irregular variation of ionization enthalpies (first and second) in the first series of the transition elements?
In what way is the electronic configuration of the transition elements different from that of the non-transition elements?
How would you account for the following:
Cobalt (II) is stable in aqueous solutions, but in the presence of complexing reagents, it is easily oxidised.
How would you account for the following:
The d1 configuration is very unstable in ions.
Use Hund’s rule to derive the electronic configuration of Ce3+ ion and calculate its magnetic moment on the basis of ‘spin-only’ formula.
What can be inferred from the magnetic moment value of the following complex species?
| Example | Magnetic Moment (BM) |
| K2[MnCl4] | 5.9 |
Explain why transition elements form alloys.
Transition metals with lowest melting point is ______.
In lake test for Al3+ ions, there is the formation of coloured ‘floating lake’. It is due to ______.
Metallic radii of some transition elements are given below. Which of these elements will have highest density?
| Element | \[\ce{Fe}\] | \[\ce{Co}\] | \[\ce{Ni}\] | \[\ce{Cu}\] |
| Metallic radii/pm | 126 | 125 | 125 | 128 |
Which of the following will not act as oxidising agents?
(i) \[\ce{CrO3}\]
(ii) \[\ce{MoO3}\]
(iii) \[\ce{WO3}\]
(iv) \[\ce{CrO^{2-}4}\]
A solution of \[\ce{KMnO4}\] on reduction yields either a colourless solution or a brown precipitate or a green solution depending on pH of the solution. What different stages of the reduction do these represent and how are they carried out?
Match the properties given in Column I with the metals given in Column II.
| Column I (Property) | Column II (Metal) | |
| (i) | Element with highest second ionisation enthalpy |
(a) \[\ce{Co}\] |
| (ii) | Element with highest third ionisation enthalpy |
(b) \[\ce{Cr}\] |
| (iii) | \[\ce{M}\] in \[\ce{M(CO)6}\] is | (c) \[\ce{Cu}\] |
| (iv) | Element with highest heat of atomisation |
(d) \[\ce{Zn}\] |
| (e) \[\ce{Ni}\] |
Which of the following ions acts as a typical transition metal ion?
Which one among the following metals of the 3d series has the lowest melting point?
The given graph shows the trends in melting points of transition metals:
Explain the reason why Cr has the highest melting point and manganese (Mn) has a lower melting point.
Account for the following:
Zirconium (Zr) and Hafnium (Hf) are difficult to separate.
A coordination compound has the formula \[\ce{CoCl3.4NH3}\]. It precipitates silver ions as AgCl and its molar conductance corresponds to a total of two ions.
Based on this information, answer the following question:
- Deduce the structural formula of the complex compound.
- Write the IUPAC name of the complex compound.
- Draw the geometrical isomers of the complex compound.
Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical columns. Give special emphasis on the following point:
Oxidation states
