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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

The second and third rows of transition elements resemble each other much more than they resemble the first row. Explain why?

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प्रश्न

The second and third rows of transition elements resemble each other much more than they resemble the first row. Explain why?

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उत्तर

Due to lanthanide contraction, the atomic radii of the second and third row transition elements are almost same. So, they resemble each other much more as compared to first row elements.

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पाठ 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [पृष्ठ १११]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 47 | पृष्ठ १११

संबंधित प्रश्‍न

Explain why is Fe3+ more stable than Fe2+?


 
 
 

Complete the following chemical equations:

`(i) Cr_2O_7^(2-)+6Fe^(2+)+14H^+ ->`

`(ii) 2CrO_4^(2-)+2H^+ ->`

`(iii) 2MnO_4^-+5C_2O_4^(2-)+16H^+ ->`

 
 
 

Explain briefly how +2 state becomes more and more stable in the first half of the first row transition elements with increasing atomic number?


Predict which of the following will be coloured in the aqueous solution?

Ti3+, V3+, Cu+, Sc3+, Mn2+, Fe3+ and Co2+. Give reasons for each.


What are alloys?


What are inner transition elements?


How is potassium dichromate prepared from chrome iron ore?


Electronic configuration of a transition element X in +3 oxidation state is [Ar]3d5. What is its atomic number?


Which of the following ions show higher spin only magnetic moment value?

(i) \[\ce{Ti^3+}\]

(ii) \[\ce{Mn2+}\]

(iii) \[\ce{Fe2+}\]

(iv) \[\ce{Co3+}\]


Match the catalysts given in Column I with the processes given in Column II.

Column I (Catalyst) Column II (Process)
(i) \[\ce{Ni}\] in the presence of hydrogen (a) Zieglar Natta catalyst
(ii) \[\ce{Cu2C12}\] (b) Contact process
(iii) \[\ce{V2O5}\] (c) Vegetable oil to ghee
(iv) Finely divided iron (d) Sandmeyer reaction
(v) \[\ce{TiCl4 + Al (CH3)3}\] (e) Haber's Process
  (f) Decomposition of KCIO3

When an oxide of manganese (A) is fused with KOH in the presence of an oxidising agent and dissolved in water, it gives a dark green solution of compound (B). Compound (B) disproportionates in neutral or acidic solution to give purple compound (C). An alkaline solution of compound (C) oxidises potassium iodide solution to a compound (D) and compound (A) is also formed. Identify compounds A to D and also explain the reactions involved.


Transition metals can act as catalysts because these can change their oxidation state. How does \[\ce{Fe(III)}\] catalyse the reaction between iodide and persulphate ions?


Fill in the blanks by choosing the appropriate word(s) from those given in the brackets:

(activation energy, Threshold energy, increased, lowered, partially, full, d-d transition, Benzoic acid, benzaldehyde)

Only those transition metal ions will be coloured which have ______ filled d-orbitals facilitating ______.


Read the passage given below and answer the following question.

Are there nuclear reactions going on in our bodies?

There are nuclear reactions constantly occurring in our bodies, but there are very few of them compared to the chemical reactions, and they do not affect our bodies much. All of the physical processes that take place to keep a human body running are chemical processes. Nuclear reactions can lead to chemical damage, which the body may notice and try to fix. The nuclear reaction occurring in our bodies is radioactive decay. This is the change of a less stable nucleus to a more stable nucleus. Every atom has either a stable nucleus or an unstable nucleus, depending on how big it is and on the ratio of protons to neutrons. The ratio of neutrons to protons in a stable nucleus is thus around 1 : 1 for small nuclei (Z < 20). Nuclei with too many neutrons, too few neutrons, or that are simply too big are unstable. They eventually transform to a stable form through radioactive decay. Wherever there are atoms with unstable nuclei (radioactive atoms), there are nuclear reactions occurring naturally. The interesting thing is that there are small amounts of radioactive atoms everywhere: in your chair, in the ground, in the food you eat, and yes, in your body.

The most common natural radioactive isotopes in humans are carbon-14 and potassium-40. Chemically, these isotopes behave exactly like stable carbon and potassium. For this reason, the body uses carbon-14 and potassium-40 just like it does normal carbon and potassium; building them into the different parts of the cells, without knowing that they are radioactive. In time, carbon-14 atoms decay to stable nitrogen atoms and potassium-40 atoms decay to stable calcium atoms. Chemicals in the body that relied on having a carbon-14 atom or potassium-40 atom in a certain spot will suddenly have a nitrogen or calcium atom. Such a change damages the chemical. Normally, such changes are so rare, that the body can repair the damage or filter away the damaged chemicals.

The natural occurrence of carbon-14 decay in the body is the core principle behind carbon dating. As long as a person is alive and still eating, every carbon-14 atom that decays into a nitrogen atom is replaced on average with a new carbon-14 atom. But once a person dies, he stops replacing the decaying carbon-14 atoms. Slowly the carbon-14 atoms decay to nitrogen without being replaced, so that there is less and less carbon-14 in a dead body. The rate at which carbon-14 decays is constant and follows first order kinetics. It has a half-life of nearly 6000 years, so by measuring the relative amount of carbon-14 in a bone, archeologists can calculate when the person died. All living organisms consume carbon, so carbon dating can be used to date any living organism, and any object made from a living organism. Bones, wood, leather, and even paper can be accurately dated, as long as they first existed within the last 60,000 years. This is all because of the fact that nuclear reactions naturally occur in living organisms.

Why is Carbon-14 radioactive while Carbon-12 not? (Atomic number of Carbon: 6)


The complex showing a spin-span magnetic moment of 2.82 B.M. is :-


Why Zn, Cd and Hg are not called transition metals?


Which property of transition metals enables them to behave as catalysts?


Consider the following standard electrode potential values:

\[\ce{Sn^{2+}_{ (aq)} + 2e^- -> Sn_{(s)}}\]; E0 = −0.14 V

\[\ce{Fe^{3+}_{ (aq)} + e^- -> Fe^{2+}_{ (aq)}}\]; E0 = +0.77 V

What is the cell reaction and potential for the spontaneous reaction that occurs?


The second ionization enthalpies of chromium and manganese are 1592 and 1509 kJ/mol respectively. Explain the lower value of Mn.


Describe the oxidising action of potassium dichromate and write the ionic equation for its reaction with iron (II) solution.


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