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The second and third rows of transition elements resemble each other much more than they resemble the first row. Explain why?

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प्रश्न

The second and third rows of transition elements resemble each other much more than they resemble the first row. Explain why?

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उत्तर

Due to lanthanide contraction, the atomic radii of the second and third row transition elements are almost same. So, they resemble each other much more as compared to first row elements.

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अध्याय 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [पृष्ठ १११]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 47 | पृष्ठ १११

संबंधित प्रश्न

Explain why is Fe3+ more stable than Fe2+?


How would you account for the following? 

Transition metals exhibit variable oxidation states.

 


The elements of 3d transition series are given as: Sc Ti V Cr Mn Fe Co

Answer the following: Which element shows only +3 oxidation state?


How would you account for the irregular variation of ionization enthalpies (first and second) in the first series of the transition elements?


To what extent do the electronic configurations decide the stability of oxidation states in the first series of the transition elements? Illustrate your answer with examples.


How is the variability in oxidation states of transition metals different from that of the non-transition metals? Illustrate with examples.


How would you account for the following:

Of the d4 species, Cr2+ is strongly reducing while manganese (III) is strongly oxidising.


Dissociation of H2S is suppressed in acidic medium.


Which among the following transition metal has the lowest melting point?


Maximum oxidation state is shown by ____________.


Electronic configuration of a transition element X in +3 oxidation state is [Ar]3d5. What is its atomic number?


Generally transition elements form coloured salts due to the presence of unpaired electrons. Which of the following compounds will be coloured in solid-state?


Which of the following statements is not correct?


Although Zirconium belongs to 4d transition series and Hafnium to 5d transition series even then they show similar physical and chemical properties because ______.


Transition elements show high melting points. Why?


When an oxide of manganese (A) is fused with KOH in the presence of an oxidising agent and dissolved in water, it gives a dark green solution of compound (B). Compound (B) disproportionates in neutral or acidic solution to give purple compound (C). An alkaline solution of compound (C) oxidises potassium iodide solution to a compound (D) and compound (A) is also formed. Identify compounds A to D and also explain the reactions involved.


On the basis of the figure given below, answer the following questions:

  1. Why Manganese has lower melting point than Chromium?
  2. Why do transition metals of 3d series have lower melting points as compared to 4d series?
  3. In the third transition series, identify and name the metal with the highest melting point.

Photographic film and plates have - au essential ingredient of


Assertion (A): Transition metals have high enthalpy of atomisation.

Reason (R): Greater number of unpaired electrons in transition metals results in weak metallic bonding.


‘Spin only’ magnetic moment is the same for which of the following ions?

  1. Ti3+
  2. Cr2+
  3. Mn2+
  4. Fe2+
  5. Sc3+

Choose the most appropriate answer from the options given below:


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