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प्रश्न
Which metal in the first transition series (3d series) exhibits + 1 oxidation state most frequently and why?
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उत्तर
Cu is the only metal in the first transition series (3d series) which shows +1 oxidation state most frequently. This is because the electronic configuration of Cu is 3d10 4s1 and after losing one electron it acquires a stable 3d10 configuration.
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संबंधित प्रश्न
Account for the following:
Cr2+ is a strong reducing agent.
Read the passage given below and answer the following question:
The transition metals when exposed to oxygen at low and intermediate temperatures form thin, protective oxide films of up to some thousands of Angstroms in thickness. Transition metal oxides lie between the extremes of ionic and covalent binary compounds formed by elements from the left or right side of the periodic table. They range from metallic to semiconducting and deviate by both large and small degrees from stoichiometry. Since electron bonding levels are involved, the cations exist in various valence states and hence give rise to a large number of oxides. The crystal structures are often classified by considering a cubic or hexagonal close-packed lattice of one set of ions with the other set of ions filling the octahedral or tetrahedral interstices. The actual oxide structures, however, generally show departures from such regular arrays due in part to distortions caused by packing of ions of different size and to ligand field effects. These distortions depend not only on the number of d-electrons but also on the valence and the position of the transition metal in a period or group.
In the following questions, a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices on the basis of the above passage.
Assertion: Transition metals form protective oxide films.
Reason: Oxides of transition metals are always stoichiometric.
Although Zirconium belongs to 4d transition series and Hafnium to 5d transition series even then they show similar physical and chemical properties because ______.
Ionisation enthalpies of Ce, Pr and Nd are higher than Th, Pa and U. Why?
Which of the following species has maximum magnetic momentum?
Write the number of unpaired electrons in Cr3+.
(Atomic number of Cr = 24)
Account for the following:
Copper has an exceptionally positive `"E"_("M"^(2+)//"M")^0` value.
In order to protect iron from corrosion, which one will you prefer as a sacrificial electrode, Ni or Zn? Why? (Given standard electrode potentials of Ni, Fe and Zn are -0.25 V, -0.44 V and -0.76 V respectively.)
The compounds of \[\ce{Ti^4+}\] ions are colourless due to ______.
Decide which of the following atomic numbers are the atomic numbers of the inner transition elements:
29, 59, 74, 95, 102, 104
