मराठी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

The magnetic moment is associated with its spin angular momentum and orbital angular momentum. Spin only magnetic moment value of Cr^3+ ion is ______. - Chemistry

Advertisements
Advertisements

प्रश्न

The magnetic moment is associated with its spin angular momentum and orbital angular momentum. Spin only magnetic moment value of \[\ce{Cr^{3+}}\] ion is ______.

पर्याय

  • 2.87 B.M.

  • 3.87 B.M.

  • 3.47 B.M.

  • 3.57 B.M.

MCQ
रिकाम्या जागा भरा
Advertisements

उत्तर

The magnetic moment is associated with its spin angular momentum and orbital angular momentum. Spin only magnetic moment value of \[\ce{Cr^{3+}}\] ion is 3.87 B.M..

Explanation:

\[\ce{Cr -> (Z = 24)}\]

\[\ce{Cr^{3+} -> (Z = 21)}\]

\[\ce{1s^2 2s^2 2P^6 3s^2 3p^6 3d^3 4s^0}\]

n = 3(3 unpaired electrons)

`mu = sqrt(n(n + 2))`

`mu = sqrt(3(3 + 2))`

`mu = sqrt(3(5))`

`mu = sqrt(15)` = 3.87 B.M.

shaalaa.com
  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [पृष्ठ १०८]

APPEARS IN

एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
पाठ 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 15 | पृष्ठ १०८

संबंधित प्रश्‍न

Account for the following:

Cu+2 salts are coloured, while Zn2+ salts are white.


How would you account for the irregular variation of ionization enthalpies (first and second) in the first series of the transition elements?


How is the variability in oxidation states of transition metals different from that of the non-transition metals? Illustrate with examples.


How would you account for the following? 

Zr (Z = 40) and Hf (Z = 72) have almost identical radii.

 


The paramagnetic character in the 3d-transition series elements increases up to Mn and then decreases.


How is potassium dichromate prepared from chrome iron ore?


Give reasons for the following:

The transition metals generally form coloured compounds.


Read the passage given below and answer the following question:

The transition metals when exposed to oxygen at low and intermediate temperatures form thin, protective oxide films of up to some thousands of Angstroms in thickness. Transition metal oxides lie between the extremes of ionic and covalent binary compounds formed by elements from the left or right side of the periodic table. They range from metallic to semiconducting and deviate by both large and small degrees from stoichiometry. Since electron bonding levels are involved, the cations exist in various valence states and hence give rise to a large number of oxides. The crystal structures are often classified by considering a cubic or hexagonal close-packed lattice of one set of ions with the other set of ions filling the octahedral or tetrahedral interstices. The actual oxide structures, however, generally show departures from such regular arrays due in part to distortions caused by packing of ions of different size and to ligand field effects. These distortions depend not only on the number of d-electrons but also on the valence and the position of the transition metal in a period or group.

In the following questions, a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices on the basis of the above passage.

Assertion: Crystal structure of oxides of transition metals often show defects.

Reason: Ligand field effect cause distortions in crystal structures.


Assertion: \[\ce{Cu^2+}\] iodide is not known.

Reason: \[\ce{Cu^2+}\] oxidises \[\ce{I^-}\] to iodine.


When a chromite ore (A) is fused with sodium carbonate in free excess of air and the product is dissolved in water, a yellow solution of compound (B) is obtained. After treatment of this yellow solution with sulphuric acid, compound (C) can be crystallised from the solution. When compound (C) is treated with KCl, orange crystals of compound (D) crystallise out. Identify A to D and also explain the reactions.


Answer the following question:

Which element of the first transition series has highest second ionisation enthalpy?


A metallic ion 'M' reacts with chloride ion to form white precipitate which is readily soluble in aqueous ammonia. Identify 'M'?


The element with atomic number 46 belongs to


Photographic film and plates have - au essential ingredient of


Account for the following:

Transition metals form alloys.


The oxidation state of Fe in [Fe(CO)5] is ______.


Complete the following reaction and justify that it is a disproportionation reaction:

\[\ce{3MnO^{2-}4 + 4H^+ -> \underline{}\underline{}\underline{}\underline{} + \underline{}\underline{}\underline{}\underline{} + 2H2O}\]


Give a reason for the following:

Zinc, cadmium and mercury are considered as d-block elements but not regarded as transition elements.


A coordination compound has the formula \[\ce{CoCl3.4NH3}\]. It precipitates silver ions as AgCl and its molar conductance corresponds to a total of two ions.

Based on this information, answer the following question:

  1. Deduce the structural formula of the complex compound.
  2. Write the IUPAC name of the complex compound.
  3. Draw the geometrical isomers of the complex compound.

‘Spin only’ magnetic moment is the same for which of the following ions?

  1. Ti3+
  2. Cr2+
  3. Mn2+
  4. Fe2+
  5. Sc3+

Choose the most appropriate answer from the options given below:


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×