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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

In the series Sc (Z = 21) to Zn (Z = 30), the enthalpy of atomization of zinc is the lowest, i.e., 126 kJ mol−1. Why?

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प्रश्न

In the series Sc (Z = 21) to Zn (Z = 30), the enthalpy of atomization of zinc is the lowest, i.e., 126 kJ mol−1. Why?

लघु उत्तर
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उत्तर

The electrons of the 3d orbitals of zinc are not used in bonding, whereas the electrons of the d orbitals of all the remaining metals of the 3d series are used in forming bonds. Hence the value of the atomization enthalpy of zinc is the lowest in the series.

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  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 4: The d-block and f-block Elements - Intext Question [पृष्ठ ९५]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 4 The d-block and f-block Elements
Intext Question | Q 4.2 | पृष्ठ ९५

संबंधित प्रश्‍न

Which metal in the first transition series (3d series) exhibits + 1 oxidation state most frequently and why?


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Transition metals exhibit variable oxidation states.

 


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Zn is not considered as a transition element.


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\[\ce{FeCr2O4 + Na2CO3 + O2 -> A + Fe2O3 + CO2}\]

\[\ce{A + H^+ -> B + H2O + Na^+}\]


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\[\ce{3MnO^{2-}4 + 4H^+ -> \underline{}\underline{}\underline{}\underline{} + \underline{}\underline{}\underline{}\underline{} + 2H2O}\]


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  1. Deduce the structural formula of the complex compound.
  2. Write the IUPAC name of the complex compound.
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For M2+/M and M3+/M2+systems, the EΘ values for some metals are as follows:

Cr2+/Cr −0.9 V
Mn2+/Mn −1.2 V
Fe2+/Fe −0.4 V
Cr3/Cr2+ −0.4 V
Mn3+/Mn2+ +1.5 V
Fe3+/Fe2+ +0.8 V

Use this data to comment upon:

The ease with which iron can be oxidised as compared to a similar process for either chromium or manganese metal.


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