English
Karnataka Board PUCPUC Science 2nd PUC Class 12

Answer the following question: Which element of the first transition series has highest second ionisation enthalpy?

Advertisements
Advertisements

Question

Answer the following question:

Which element of the first transition series has highest second ionisation enthalpy?

Long Answer
Advertisements

Solution

Out of all the elements of the first transition series copper has the highest second ionisation enthalpy.

Electronic configuration of Copper is: \[\ce{3d^10 4s^1}\]

After the Loss of first electron from the 4s copper acquires \[\ce{3d^10}\] configuration which is stable. Therefore, removal of second electron from the field 3-D orbital is very difficult and requires high amount of energy.

shaalaa.com
  Is there an error in this question or solution?
Chapter 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [Page 115]

APPEARS IN

NCERT Exemplar Chemistry Exemplar [English] Class 12
Chapter 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 68.(i).(a) | Page 115

RELATED QUESTIONS

What are the transition elements? Write two characteristics of the transition elements.


Which of the 3d series of the transition metals exhibits the largest number of oxidation states and why?


Explain briefly how +2 state becomes more and more stable in the first half of the first row transition elements with increasing atomic number?


Which metal in the first series of transition metals exhibits +1 oxidation state most frequently and why?


Calculate the number of unpaired electrons in the following gaseous ions:

Mn3+, Cr3+, V3+ and Ti3+. Which one of these is the most stable in an aqueous solution?


What are alloys?


An antifriction alloy made up of antimony with tin and copper, which is extensively used in machine bearings is called _______.

(A) Duralumin

(B) Babbitt metal

(C) Spiegeleisen

(D) Amalgam


Complete and balance the following chemical equations

`MnO_4^(-) + H_2O + I^(-) ->`


Give reasons: 

E° value for the Mn3+/Mn2+ couple is much more positive than that for Fe3+/Fe2+.


The transition metals show _________ character because of the presence of unpaired· electrons and Cu+ is ____________ because of its electronic configuration is [Ar]3d10


Transition elements form binary compounds with halogens. Which of the following elements will form \[\ce{MF3}\] type compounds?

(i) \[\ce{Cr}\]

(ii) \[\ce{Co}\]

(iii) \[\ce{Cu}\]

(iv) \[\ce{Ni}\]


Which of the following will not act as oxidising agents?

(i) \[\ce{CrO3}\]

(ii) \[\ce{MoO3}\]

(iii) \[\ce{WO3}\]

(iv) \[\ce{CrO^{2-}4}\]


Ionisation enthalpies of Ce, Pr and Nd are higher than Th, Pa and U. Why?


Explain why does colour of KMnO4 disappear when oxalic acid is added to its solution in acidic medium.


Match the properties given in Column I with the metals given in Column II.

  Column I (Property) Column II (Metal)
(i) Element with highest second
ionisation enthalpy
(a) \[\ce{Co}\]
(ii) Element with highest
third ionisation enthalpy
(b) \[\ce{Cr}\]
(iii) \[\ce{M}\] in \[\ce{M(CO)6}\] is (c) \[\ce{Cu}\]
(iv) Element with highest heat
of atomisation
(d) \[\ce{Zn}\]
    (e) \[\ce{Ni}\]

Read the passage given below and answer the following question.

Are there nuclear reactions going on in our bodies?

There are nuclear reactions constantly occurring in our bodies, but there are very few of them compared to the chemical reactions, and they do not affect our bodies much. All of the physical processes that take place to keep a human body running are chemical processes. Nuclear reactions can lead to chemical damage, which the body may notice and try to fix. The nuclear reaction occurring in our bodies is radioactive decay. This is the change of a less stable nucleus to a more stable nucleus. Every atom has either a stable nucleus or an unstable nucleus, depending on how big it is and on the ratio of protons to neutrons. The ratio of neutrons to protons in a stable nucleus is thus around 1 : 1 for small nuclei (Z < 20). Nuclei with too many neutrons, too few neutrons, or that are simply too big are unstable. They eventually transform to a stable form through radioactive decay. Wherever there are atoms with unstable nuclei (radioactive atoms), there are nuclear reactions occurring naturally. The interesting thing is that there are small amounts of radioactive atoms everywhere: in your chair, in the ground, in the food you eat, and yes, in your body.

The most common natural radioactive isotopes in humans are carbon-14 and potassium-40. Chemically, these isotopes behave exactly like stable carbon and potassium. For this reason, the body uses carbon-14 and potassium-40 just like it does normal carbon and potassium; building them into the different parts of the cells, without knowing that they are radioactive. In time, carbon-14 atoms decay to stable nitrogen atoms and potassium-40 atoms decay to stable calcium atoms. Chemicals in the body that relied on having a carbon-14 atom or potassium-40 atom in a certain spot will suddenly have a nitrogen or calcium atom. Such a change damages the chemical. Normally, such changes are so rare, that the body can repair the damage or filter away the damaged chemicals.

The natural occurrence of carbon-14 decay in the body is the core principle behind carbon dating. As long as a person is alive and still eating, every carbon-14 atom that decays into a nitrogen atom is replaced on average with a new carbon-14 atom. But once a person dies, he stops replacing the decaying carbon-14 atoms. Slowly the carbon-14 atoms decay to nitrogen without being replaced, so that there is less and less carbon-14 in a dead body. The rate at which carbon-14 decays is constant and follows first order kinetics. It has a half-life of nearly 6000 years, so by measuring the relative amount of carbon-14 in a bone, archeologists can calculate when the person died. All living organisms consume carbon, so carbon dating can be used to date any living organism, and any object made from a living organism. Bones, wood, leather, and even paper can be accurately dated, as long as they first existed within the last 60,000 years. This is all because of the fact that nuclear reactions naturally occur in living organisms.

Researchers have uncovered the youngest known dinosaur bone, dating around 65 million years ago. How was the age of this fossil estimated?


Catalytic hydrogenation of benzene gives


Which one of the following characters tie of the transition metal is associated with higher catalytic activity?


Give reason for the following statement:

Physical and chemical properties of the 4d and 5d series of the transition elements are quite similar to expected.


Give a reason for the following.

Some transition metals and their compounds get attracted towards the magnetic field.


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×