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Karnataka Board PUCPUC Science 2nd PUC Class 12

Transition elements show magnetic moment due to spin and orbital motion of electrons. Which of the following metallic ions have almost same spin only magnetic moment? (i) CoX2+ (ii) CrX2+ (iii) MnX2

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Question

Transition elements show magnetic moment due to spin and orbital motion of electrons. Which of the following metallic ions have almost same spin only magnetic moment?

(i) \[\ce{Co^{2+}}\]

(ii) \[\ce{Cr^{2+}}\]

(iii) \[\ce{Mn^{2+}}\]

(iv) \[\ce{Cr^{3+}}\]

Short/Brief Note
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Solution

(i) \[\ce{Co^{2+}}\]

(iv) \[\ce{Cr^{3+}}\]

Explanation:

The magnetic moment of an electron/dipole moment is caused by its intrinsic properties of spin and electric charge. It depends upon the number of unpaired electrons in its valence shell. The more the number of unpaired electrons, the greater will be the value of the magnetic moment.

\[\ce{Co^{2+}}\] and \[\ce{Cr^{3+}}\] have same unpaired electrons i.e. 3 unpaired electrons. Hence they have the same spin only magnetic moment. 
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Chapter 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [Page 109]

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NCERT Exemplar Chemistry Exemplar [English] Class 12
Chapter 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 23 | Page 109

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