English
Karnataka Board PUCPUC Science 2nd PUC Class 12

Which of the d-block elements may not be regarded as the transition elements?

Advertisements
Advertisements

Question

Which of the d-block elements may not be regarded as the transition elements?

Short Answer
Advertisements

Solution

The electronic configuration of Zn, Cd and Hg is represented by the general formula (n – 1)d10ns2. In these elements, the orbitals are completely filled in the ground (normal) state as well as in ordinary oxidation states, i.e., the subshells are not incomplete in their atomic state or any one of the ionic states. Therefore, they cannot be called transition elements.

shaalaa.com
  Is there an error in this question or solution?
Chapter 4: d-and ƒ-Block Elements - 'NCERT TEXT-BOOK, Exercises [Page 506]

APPEARS IN

Nootan Chemistry [English] Class 12 ISC
Chapter 4 d-and ƒ-Block Elements
'NCERT TEXT-BOOK, Exercises | Q 8.8 ii. | Page 506
NCERT Chemistry Part 1 and 2 [English] Class 12
Chapter 4 The d-block and f-block Elements
Exercises | Q 4.8 (ii) | Page 115

RELATED QUESTIONS

Calculate magnetic moment of  `Fe_((aq))^(2+) ion (Z=26).`


Out of Mn3+ and Cr3+, which is more paramagnetic and why ?

(Atomic nos. : Mn = 25, Cr = 24)


Why are Mn2+ compounds more stable than Fe2+ towards oxidation to their +3 state?


What is meant by ‘disproportionation’? 


Comment on the statement that elements of the first transition series possess many properties different from those of heavier transition elements.


Maximum oxidation state is shown by ____________.


Which of the following will not act as oxidising agents?

(i) \[\ce{CrO3}\]

(ii) \[\ce{MoO3}\]

(iii) \[\ce{WO3}\]

(iv) \[\ce{CrO^{2-}4}\]


Explain why does colour of KMnO4 disappear when oxalic acid is added to its solution in acidic medium.


Fill in the blanks by choosing the appropriate word(s) from those given in the brackets:

(activation energy, Threshold energy, increased, lowered, partially, full, d-d transition, Benzoic acid, benzaldehyde)

Only those transition metal ions will be coloured which have ______ filled d-orbitals facilitating ______.


A metallic ion 'M' reacts with chloride ion to form white precipitate which is readily soluble in aqueous ammonia. Identify 'M'?


Which of the following is non-metallic?


Agcl is soluble in NH4OH. The solubility is due to the information of:-


Match List - I with List - II.

List - I List - II
(A) [Fe(CN)6]3− (i) 5.92 BM
(B) [Fe(H2O)6]3+ (ii) 0 BM
(C) [Fe(CN)6]4− (iii) 4.90 BM
(D) [Fe(H2O)6]2+ (iv) 1.73 BM

Choose the correct answer from the options given below.


Why are all copper halides known except that copper iodide?


Which of the following ions acts as a typical transition metal ion?


The disproportionation of \[\ce{MnO^{2-}_4}\] in acidic medium resulted in the formation of two manganese compounds A and B. If the oxidation state of Mn in B is smaller than that of A, then the spin-only magnetic moment (µ) value of B in BM is ______. (Nearest integer)


Assertion (A): Transition metals show their highest oxidation state with oxygen.

Reason (R): The ability of oxygen to form multiple bonds to metals.


Consider the following standard electrode potential values:

\[\ce{Sn^{2+}_{ (aq)} + 2e^- -> Sn_{(s)}}\]; E0 = −0.14 V

\[\ce{Fe^{3+}_{ (aq)} + e^- -> Fe^{2+}_{ (aq)}}\]; E0 = +0.77 V

What is the cell reaction and potential for the spontaneous reaction that occurs?


Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical columns. Give special emphasis on the following point:

Oxidation states


Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical columns. Give special emphasis on the following point:

Atomic sizes


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×