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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Answer the following question: Which element of the first transition series has highest third ionisation enthalpy?

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प्रश्न

Answer the following question:

Which element of the first transition series has highest third ionisation enthalpy?

दीर्घउत्तर
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उत्तर

Among the elements of first transition series zinc has the highest third ionisation enthalpy. Electronic configuration of zinc is: \[\ce{3d^10 4s^2}\]

After the loss of two electrons from 4s orbital, Z and +2 Ion acquires \[\ce{3d^10}\] fully filled configuration which is highly stable therefore removal of third electron from \[\ce{3d^10}\] orbital will be more difficult and requires a large amount of energy.

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पाठ 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [पृष्ठ ११५]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 68.(ii).(a) | पृष्ठ ११५

संबंधित प्रश्‍न

Why +2 oxidation state of manganese is more stable?


Why do the transition elements have higher enthalpies of atomisation?


In the series Sc (Z = 21) to Zn (Z = 30), the enthalpy of atomization of zinc is the lowest, i.e., 126 kJ mol−1. Why?


To what extent do the electronic configurations decide the stability of oxidation states in the first series of the transition elements? Illustrate your answer with examples.


Following are the transition metal ions of 3d series:

Ti4+, V2+, Mn3+, Cr3+

(Atomic numbers: Ti = 22, V = 23, Mn = 25, Cr = 24)

Answer the following:

1) Which ion is most stable in an aqueous solution and why?

2) Which ion is a strong oxidising agent and why?

3) Which ion is colourless and why?


Why do transition elements show variable oxidation states ? In 3d series (Sc to Zn), which elements shows the maximum number of oxidation state and why ?


How is potassium dichromate prepared from chrome iron ore?


Explain why Mn2+ is more stable than Fe2+ towards oxidation to +3 state. (At. no. of Mn = 25, Fe = 26)


Electronic configuration of Mn2+ is ____________.


When \[\ce{KMnO4}\] solution is added to oxalic acid solution, the decolourisation is slow in the beginning but becomes instantaneous after some time because ______.


The magnetic moment is associated with its spin angular momentum and orbital angular momentum. Spin only magnetic moment value of Cr3+ ion is ______.


When acidified \[\ce{K2Cr2O7}\] solution is added to \[\ce{Sn^{2+}}\] salts then \[\ce{Sn^{2+}}\] changes to ______.


Mention any three processes where transition metals act as catalysts.


If enthalpies of formation of C2H4(g), CO2(g) and H2O(l) at 25°C and 1 atm pressure are 52, – 394 and – 286 kJ/mol respectively, the change in ethalpy for combustion of C2H4 is equal to


Among the following pairs of ions, the lower oxidation state in aqueous solution is more stable than the other in:-


In the ground state of atomic Fe (Z = 26), the spin-only magnetic moment is ______ × 10-1 BM.
(Round off to the nearest integer).

[Given: `sqrt3 = 1.73, sqrt2 = 1.41`]


Explain the magnetic properties of d-block (or transition) elements.


Explain the use of different transition metals as catalysts.


Give a reason for the following.

Some transition metals and their compounds get attracted towards the magnetic field.


Why are interstitial compounds well known for transition metals?


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