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प्रश्न
Compare the chemistry of actinoids with that of lanthanoids with special reference to electronic configuration.
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उत्तर
The general electronic configuration of lanthanoids is [Xe]54 4f1−14 5d0−1 6s2, while the general electronic configuration of actinoids is [Rn]86 5f1−14 6d1−2 7s2. Hence, lanthanoids belong to the 4f series and actinoids belong to the 5f series.
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संबंधित प्रश्न
Account for the following :
Zr and Hf have almost similar atomic radii.
Compare the chemistry of actinoids with that of the lanthanoids with special reference to atomic and ionic sizes.
Write the electronic configurations of the element with the atomic number 61.
Which trivalent ion has the maximum size in the Lanthanoid series, i.e., Lanthanum ion (La3+) to Luteium ion (Lu3+)?
(at. no. of Lanthanum = 57 and Lutetium = 71)
What is the action of the following on lanthanoids?
a. water
b. Sulphur, heat
c. nitrogen, heat
The f-block elements are known as ____________.
Although +3 oxidation states is the characteristic oxidation state of lanthanoids but cerium shows +4 oxidation state also. Why?
Match the compounds/elements given in Column I with uses given in Column II.
| Column I (Compound/element) | Column II (Use) | |
| (i) | Lanthanoid oxide | (a) Production of iron alloy |
| (ii) | Lanthanoid | (b) Television screen |
| (iii) | Misch metal | (c) Petroleum cracking |
| (iv) | Magnesium based alloy is constituent of | (d) Lanthanoid metal + iron |
| (v) | Mixed oxides of lanthanoids are employed | (e) Bullets |
| (f) In X-ray screen |
On the basis of Lanthanoid contraction, explain the following:
Stability of the complexes of lanthanoids.
On the basis of Lanthanoid contraction, explain the following:
Radii of 4d and 5d block elements.
How would you account for the following:
There is a greater range of oxidation states among the actinoids than among the lanthanides.
The titanium (Z = 22) compound that does not exist is:-
In lanthanoid the last electron enters (n - 2)f subshell where n is equal to ______.
Write any two consequences of Lanthanoid Contraction.
The lathanide ion that would show colour is ______.
State a reason for the following:
La(OH)3 is more basic than Lu(OH)3.
Why is Mn2+ ion more stable than Fe2+ ion?
(Atomic numbers of Mn = 25 and Fe = 26)
Assertion: There is a continuous increase in size among Lanthanoids with an increase in atomic number.
Reason: Lanthanoids do not show Lanthanoid contraction.
Name an important alloy which contains some of the lanthanoid metals.
