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Question
Compare the chemistry of actinoids with that of lanthanoids with special reference to electronic configuration.
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Solution
The general electronic configuration of lanthanoids is [Xe]54 4f1−14 5d0−1 6s2, while the general electronic configuration of actinoids is [Rn]86 5f1−14 6d1−2 7s2. Hence, lanthanoids belong to the 4f series and actinoids belong to the 5f series.
RELATED QUESTIONS
Define lanthanoid contraction.
Which among the following pairs of elements is 'not' an example of chemical twins?
Compare the chemistry of actinoids with that of the lanthanoids with special reference to chemical reactivity.
The chemistry of the actinoid elements is not so smooth as that of the Lanthanoids. Justify this statement by giving some examples from the oxidation state of these elements.
Explain, why lanthanum (Z = 57) forms La3+ ion, while cerium (Z = 58) forms Ce4+ ion?
What are the consequences of lanthanoid contraction?
Account for the following:
Zn, Cd and Hg are soft metals.
Which trivalent ion has the maximum size in the Lanthanoid series, i.e., Lanthanum ion (La3+) to Luteium ion (Lu3+)?
(at. no. of Lanthanum = 57 and Lutetium = 71)
Name an element of lanthanoid series which is well knwon to shown +4 oxidation state. Is it a strong oxidising agent or reducing agent?
Which of the following lanthanoids show +2 oxidation state besides the characteristic oxidation state +3 of lanthanoids?
(i) \[\ce{Ce}\]
(ii) \[\ce{Eu}\]
(iii) \[\ce{Yb}\]
(iv) \[\ce{Ho}\]
Match the compounds/elements given in Column I with uses given in Column II.
| Column I (Compound/element) | Column II (Use) | |
| (i) | Lanthanoid oxide | (a) Production of iron alloy |
| (ii) | Lanthanoid | (b) Television screen |
| (iii) | Misch metal | (c) Petroleum cracking |
| (iv) | Magnesium based alloy is constituent of | (d) Lanthanoid metal + iron |
| (v) | Mixed oxides of lanthanoids are employed | (e) Bullets |
| (f) In X-ray screen |
Match the property given in Column I with the element given in Column II.
| Column I (Property) | Column II (Element) | |
| (i) | Lanthanoid which shows +4 oxidation state |
(a) Pm |
| (ii) | Lanthanoid which can show +2 oxidation state |
(b) Ce |
| (iii) | Radioactive lanthanoid | (c) Lu |
| (iv) | Lanthanoid which has 4f7 electronic configuration in +3 oxidation state |
(d) Eu |
| (v) | Lanthanoid which has 4f14 electronic configuration in +3 oxidation state |
(e) Gd |
| (f) Dy |
On the basis of Lanthanoid contraction, explain the following:
Nature of bonding in \[\ce{La2O3}\] and \[\ce{Lu2O3}\] .
How would you account for the following:
There is a greater range of oxidation states among the actinoids than among the lanthanides.
Write any two consequences of Lanthanoid Contraction.
The lathanide ion that would show colour is ______.
Why is Mn2+ ion more stable than Fe2+ ion?
(Atomic numbers of Mn = 25 and Fe = 26)
