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प्रश्न
Compare the chemistry of actinoids with that of the lanthanoids with special reference to atomic and ionic sizes.
Compare the chemistry of actinoids with that of the lanthanoids in reference to atomic and ionic sizes.
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उत्तर
Both lanthanoids and actinoids show a decrease in the size of their atoms or ions in the +3 oxidation state. In lanthanoids this decrease is called lanthanoid contraction, while in actinoids it is called actinoid contraction. However, in actinoids, the contraction increases gradually due to the very low shielding effect of 5f-electrons from one element to another.
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संबंधित प्रश्न
What are chemical twins? Write ‘two’ examples.
Account for the following :
Zr and Hf have almost similar atomic radii.
Compare the chemistry of actinoids with that of lanthanoids with special reference to electronic configuration.
Compare the chemistry of actinoids with that of the lanthanoids with special reference to chemical reactivity.
Name the members of the lanthanoid series which exhibit +4 oxidation state and those which exhibit +2 oxidation state. Try to correlate this type of behavior with the electronic configurations of these elements.
Write the electronic configurations of the element with the atomic number 61.
Explain, why lanthanum (Z = 57) forms La3+ ion, while cerium (Z = 58) forms Ce4+ ion?
What are the consequences of lanthanoid contraction?
What is lanthanoid contraction? Write the.............
General electronic configuration of actinoids is `(n-2)f^(1-14)(n - 1)d^(0-2)ns^2`.Which of the following actinoids have one electron in 6d orbital?
(i) U (Atomic no. 92)
(ii) Np (Atomic no.93)
(iii) Pu (Atomic no. 94)
(iv) Am (Atomic no. 95)
Which of the following lanthanoids show +2 oxidation state besides the characteristic oxidation state +3 of lanthanoids?
(i) \[\ce{Ce}\]
(ii) \[\ce{Eu}\]
(iii) \[\ce{Yb}\]
(iv) \[\ce{Ho}\]
Although +3 is the characteristic oxidation state for lanthanoids but cerium also shows +4 oxidation state because:
(i) it has variable ionisation enthalpy
(ii) it has a tendency to attain noble gas configuration
(iii) it has a tendency to attain f 0 configuration
(iv) it resembles Pb4+
Match the compounds/elements given in Column I with uses given in Column II.
| Column I (Compound/element) | Column II (Use) | |
| (i) | Lanthanoid oxide | (a) Production of iron alloy |
| (ii) | Lanthanoid | (b) Television screen |
| (iii) | Misch metal | (c) Petroleum cracking |
| (iv) | Magnesium based alloy is constituent of | (d) Lanthanoid metal + iron |
| (v) | Mixed oxides of lanthanoids are employed | (e) Bullets |
| (f) In X-ray screen |
On the basis of Lanthanoid contraction, explain the following:
Stability of the complexes of lanthanoids.
Zr (Z = 40) and Hf (Z = 72) have similar atomic and ionic radii because of ______.
Write any two consequences of Lanthanoid Contraction.
Mischmetal is an alloy consisting mainly of ______.
Cerium (Z = S8) is an important member of lanthanoids. Which of the following statements about cerium is incorrect?
Mention uses of alloys.
