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प्रश्न
General electronic configuration of actinoids is `(n-2)f^(1-14)(n - 1)d^(0-2)ns^2`.Which of the following actinoids have one electron in 6d orbital?
(i) U (Atomic no. 92)
(ii) Np (Atomic no.93)
(iii) Pu (Atomic no. 94)
(iv) Am (Atomic no. 95)
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उत्तर
(i) U (Atomic no. 92)
(ii) Np (Atomic no.93)
Explanation:
Electronic configuration:
92U – 5f3 6d1 7s2
93Np – 5f4 6d1 7s2
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संबंधित प्रश्न
Define lanthanoid contraction.
Account for the following :
Zr and Hf have almost similar atomic radii.
Compare the chemistry of actinoids with that of lanthanoids with special reference to electronic configuration.
The chemistry of the actinoid elements is not so smooth as that of the Lanthanoids. Justify this statement by giving some examples from the oxidation state of these elements.
Write the electronic configurations of the element with the atomic number 61.
Explain, why lanthanum (Z = 57) forms La3+ ion, while cerium (Z = 58) forms Ce4+ ion?
Which trivalent ion has the maximum size in the Lanthanoid series, i.e., Lanthanum ion (La3+) to Luteium ion (Lu3+)?
(at. no. of Lanthanum = 57 and Lutetium = 71)
Which of the following lanthanoids show +2 oxidation state besides the characteristic oxidation state +3 of lanthanoids?
(i) \[\ce{Ce}\]
(ii) \[\ce{Eu}\]
(iii) \[\ce{Yb}\]
(iv) \[\ce{Ho}\]
Match the property given in Column I with the element given in Column II.
| Column I (Property) | Column II (Element) | |
| (i) | Lanthanoid which shows +4 oxidation state |
(a) Pm |
| (ii) | Lanthanoid which can show +2 oxidation state |
(b) Ce |
| (iii) | Radioactive lanthanoid | (c) Lu |
| (iv) | Lanthanoid which has 4f7 electronic configuration in +3 oxidation state |
(d) Eu |
| (v) | Lanthanoid which has 4f14 electronic configuration in +3 oxidation state |
(e) Gd |
| (f) Dy |
How would you account for the following:
There is a greater range of oxidation states among the actinoids than among the lanthanides.
Which of the following pairs has the same ionic size?
Zr (Z = 40) and Hf (Z = 72) have similar atomic and ionic radii because of ______.
State a reason for the following:
La(OH)3 is more basic than Lu(OH)3.
Why is Mn2+ ion more stable than Fe2+ ion?
(Atomic numbers of Mn = 25 and Fe = 26)
Assertion: There is a continuous increase in size among Lanthanoids with an increase in atomic number.
Reason: Lanthanoids do not show Lanthanoid contraction.
Name an important alloy which contains some of the lanthanoid metals.
Mention uses of alloys.
