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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

On the basis of Lanthanoid contraction, explain the following: Stability of the complexes of lanthanoids.

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प्रश्न

On the basis of Lanthanoid contraction, explain the following:

Stability of the complexes of lanthanoids.

दीर्घउत्तर
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उत्तर

As we move along the lanthanide series, the atomic size decreases. As a result, the charge/size ratio increases and the stability of the complexes also increases.

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पाठ 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [पृष्ठ ११५]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 67.(iii) | पृष्ठ ११५

संबंधित प्रश्‍न

What are chemical twins? Write ‘two’ examples.


What are lanthanoids?


Account for the following :

Zr and Hf have almost similar atomic radii.


What are the different oxidation states exhibited by the lanthanoids?


Compare the chemistry of actinoids with that of the lanthanoids with special reference to chemical reactivity.


The chemistry of the actinoid elements is not so smooth as that of the Lanthanoids. Justify this statement by giving some examples from the oxidation state of these elements.


Write the different oxidation states of iron


Explain effects of lanthanoid contraction.


What are the consequences of lanthanoid contraction?


Explain the cause of Lanthanoids contraction.


What is meant by Lanthanide contraction? Write the general electronic configuration of inner transition elements. 


The f-block elements are known as ____________.


General electronic configuration of actinoids is `(n-2)f^(1-14)(n - 1)d^(0-2)ns^2`.Which of the following actinoids have one electron in 6d orbital?

(i) U (Atomic no. 92)

(ii) Np (Atomic no.93)

(iii) Pu (Atomic no. 94)

(iv) Am (Atomic no. 95)


Which of the following lanthanoids show +2 oxidation state besides the characteristic oxidation state +3 of lanthanoids?

(i) \[\ce{Ce}\]

(ii) \[\ce{Eu}\]

(iii) \[\ce{Yb}\]

(iv) \[\ce{Ho}\]


Although +3 oxidation states is the characteristic oxidation state of lanthanoids but cerium shows +4 oxidation state also. Why?


In lanthanoid the last electron enters (n - 2)f subshell where n is equal to ______.


Write any two consequences of Lanthanoid Contraction.


Trivalent Lanthanoid ions such as La3+ (Z = 57) and Lu3+ (Z = 71) do not show any colour in their solution. Give a reason.


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