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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

On the basis of Lanthanoid contraction, explain the following: Trends in the stability of oxo salts of lanthanoids from La to Lu.

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प्रश्न

On the basis of Lanthanoid contraction, explain the following:

Trends in the stability of oxo salts of lanthanoids from \[\ce{La}\] to \[\ce{Lu}\].

दीर्घउत्तर
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उत्तर

The stability of Oxo salts is directly proportional to the size of atom, as we move from \[\ce{La}\] to \[\ce{Lu}\], the size of the atom decreases and hence the stability of oxo salts also decreases.

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पाठ 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [पृष्ठ ११५]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 67.(ii) | पृष्ठ ११५

संबंधित प्रश्‍न

Which among the following pairs of elements is 'not' an example of chemical twins?


What are the different oxidation states exhibited by the lanthanoids?


Compare the chemistry of actinoids with that of the lanthanoids with special reference to oxidation state.


Compare the chemistry of actinoids with that of the lanthanoids with special reference to atomic and ionic sizes.


Explain, why lanthanum (Z = 57) forms La3+ ion, while cerium (Z = 58) forms Ce4+ ion?


Explain effects of lanthanoid contraction.


Which trivalent ion has the maximum size in the Lanthanoid series, i.e., Lanthanum ion (La3+) to Luteium ion (Lu3+)? 

(at. no. of Lanthanum  = 57 and Lutetium = 71)


What is lanthanoid contraction?


The f-block elements are known as ____________.


General electronic configuration of actinoids is `(n-2)f^(1-14)(n - 1)d^(0-2)ns^2`.Which of the following actinoids have one electron in 6d orbital?

(i) U (Atomic no. 92)

(ii) Np (Atomic no.93)

(iii) Pu (Atomic no. 94)

(iv) Am (Atomic no. 95)


Although +3 oxidation states is the characteristic oxidation state of lanthanoids but cerium shows +4 oxidation state also. Why?


On the basis of Lanthanoid contraction, explain the following:

Nature of bonding in \[\ce{La2O3}\] and \[\ce{Lu2O3}\] .


On the basis of Lanthanoid contraction, explain the following:

Radii of 4d and 5d block elements.


The lathanide ion that would show colour is ______.


Why is Mn2+ ion more stable than Fe2+ ion?

(Atomic numbers of Mn = 25 and Fe = 26)


Trivalent Lanthanoid ions such as La3+ (Z = 57) and Lu3+ (Z = 71) do not show any colour in their solution. Give a reason.


Assertion: There is a continuous increase in size among Lanthanoids with an increase in atomic number.

Reason: Lanthanoids do not show Lanthanoid contraction.


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