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प्रश्न
Why is the highest oxidation state of a metal exhibited in its oxide or fluoride only?
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उत्तर
Due to its small size and high electronegativities, oxygen or fluorine elements can oxidize the metal to its higher oxidation state.
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संबंधित प्रश्न
Give reasons:
Transition metals show variable oxidation states.
How would you account for the following : Transition metals form coloured compounds
Account for the following:
E° value for the Mn3+/Mn2+ couple is much more positive than that for Cr3+/Cr2+.
Which of the 3d series of the transition metals exhibits the largest number of oxidation states and why?
How is the variability in oxidation states of transition metals different from that of the non-transition metals? Illustrate with examples.
What can be inferred from the magnetic moment value of the following complex species?
| Example | Magnetic Moment (BM) |
| K2[MnCl4] | 5.9 |
Complete and balance the following chemical equations
`Fe^(2+) + MnO_4^(-) + H^+ ->`
Why does the density of transition elements increase from Titanium to Copper? (at. no. Ti = 22, Cu = 29)
The transition metals show _________ character because of the presence of unpaired· electrons and Cu+ is ____________ because of its electronic configuration is [Ar]3d10
Explain why Mn2+ is more stable than Fe2+ towards oxidation to +3 state. (At. no. of Mn = 25, Fe = 26)
Reactivity of transition elements decreases almost regularly from Sc to Cu. Explain.
Match the properties given in Column I with the metals given in Column II.
| Column I (Property) | Column II (Metal) | |
| (i) | An element which can show +8 oxidation state | (a) \[\ce{Mn}\] |
| (ii) | 3d block element that can show | (b) \[\ce{Cr}\] |
| upto +7 oxidation state | (c) \[\ce{Os}\] | |
| (iii) | 3d block element with highest melting point | (d) \[\ce{Fe}\] |
Assertion (A): Cu cannot liberate hydrogen from acids.
Reason (R): Because it has positive electrode potential.
The complex showing a spin-span magnetic moment of 2.82 B.M. is :-
Give reason for the following statement:
Physical and chemical properties of the 4d and 5d series of the transition elements are quite similar to expected.
The value of Δ0 for \[\ce{RhCl^{3-}6}\] is 243 KJ/mol which wavelength of light will promote an electron from. The colour of the complex is ______.
Which of the following characteristics of transition metals is associated with their catalytic activity?
The given graph shows the trends in melting points of transition metals:
Explain the reason why Cr has the highest melting point and manganese (Mn) has a lower melting point.
Consider the following standard electrode potential values:
\[\ce{Fe^{3+}_{ (aq)} + e^- -> Fe^{2+}_{ (aq)}}\], E0 = +0.77 V
\[\ce{MnO^{-4}_{ (aq)} + 8H^+ + 5e^- -> Mn^{2+}_{ (aq)} + 4H2O_{(l)}}\], E0 = +1.51 V
What is the cell potential for the redox reaction?
A coordination compound has the formula \[\ce{CoCl3.4NH3}\]. It precipitates silver ions as AgCl and its molar conductance corresponds to a total of two ions.
Based on this information, answer the following question:
- Deduce the structural formula of the complex compound.
- Write the IUPAC name of the complex compound.
- Draw the geometrical isomers of the complex compound.
