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प्रश्न
Give an example and suggest a reason for the following feature of the transition metal chemistry:
The highest oxidation state is exhibited in oxoanions of a metal.
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उत्तर
Metal oxoanions show higher oxidation states, for example, in \[\ce{Cr2O^{2-}_7}\] the oxidation state of Cr is +6, while in \[\ce{MnO^-_4}\] the oxidation state of Mn is +7. The reason for the combination of metal with oxygen is that oxygen is a highly electronegative and oxidizing element.
संबंधित प्रश्न
Complete the following equations: Cr2O72- + 14H+ + 6I →
Complete the following equation:
\[\ce{2MnO4- + 6H+ + 5NO2- ->}\]
Complete the following equation :
`2MnO_4^(-)+6H^++5NO_2^(-)rarr`
Complete the following equations : 2 Na2CrO4 + 2 H + →
Indicate the steps in the preparation of KMnO4 from pyrolusite ore.
Complete the following equation :
Write the ionic equation showing the oxidation of Fe(II) salt by acidified dichromate solutions.
Generally transition elements and their salts are coloured due to the presence of unpaired electrons in metal ions. Which of the following compounds are coloured?
(i) \[\ce{KMnO4}\]
(ii) \[\ce{Ce(SO4)2}\]
(iii) \[\ce{TiCl}\]
(iv) \[\ce{Cu2 Cl2}\]
When \[\ce{Cu^2+}\] ion is treated with \[\ce{KI}\], a white precipitate is formed. Explain the reaction with the help of chemical equation.
The product formed upon heating methyl bromide with potassium tert-butoxide is
KMnO4 is coloured due to ______.
Why \[\ce{HCl}\] should not be used for potassium permanganate titrations?
What is the effect of pH on dichromate ion solution?
In the two tetrahedral structures of dichromate ion, ______.
Complete the reaction mentioning all the products formed:
\[\ce{2KMnO4 ->[\Delta]}\]
Complete the reaction mentioning all the products formed:
\[\ce{Cr2O^{2-}7 + 3H2S + 8H^+ ->}\]
Indicate the steps in the preparation of \[\ce{K2Cr2O7}\] from chromite ore.
Describe the preparation of potassium permanganate. How does the acidified permanganate solution react with SO2? Write the ionic equation for the reaction.
