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प्रश्न
In the two tetrahedral structures of dichromate ion, ______.
पर्याय
4 Cr–O bonds are equivalent in length
6 Cr–O bonds are equivalent in length
All Cr–O bonds are equivalent in length
All Cr–O bonds are non-equivalent
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उत्तर
In the two tetrahedral structures of dichromate ion, 6 Cr–O bonds are equivalent in length.
Explanation:
The Dichromate di-anion is made up of two tetrahedral molecules that share oxygen at their common corner. The structure of the chromate ion is tetrahedral. Due to resonance, the six terminal bonds in the dichromate ion have the same bond length. As a result, all six Cr–O bonds are equivalent.
6 Cr–O bonds are equivalent
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संबंधित प्रश्न
Complete the following equations:
When chromite ore FeCr2O4 is fused with NaOH in presence of air, a yellow-coloured compound (A) is obtained, which on acidification with dilute sulphuric acid gives a compound (B). Compound (B) on reaction with KCl forms an orange coloured crystalline compound (C).
(i) Write the formulae of the compounds (A), (B) and C.
(ii) Write one use of compound (C).
Write the formula of an oxo-anion of Manganese (Mn) in which it shows the oxidation state equal to its group number.
Generally transition elements and their salts are coloured due to the presence of unpaired electrons in metal ions. Which of the following compounds are coloured?
(i) \[\ce{KMnO4}\]
(ii) \[\ce{Ce(SO4)2}\]
(iii) \[\ce{TiCl}\]
(iv) \[\ce{Cu2 Cl2}\]
In the form of dichromate, \[\ce{Cr (VI)}\] is a strong oxidising agent in acidic medium but \[\ce{Mo (VI)}\] in \[\ce{MoO3}\] \[\ce{and W (VI)}\] in \[\ce{WO3}\] are not because:
(i) \[\ce{Cr(VI)}\] is more stable than \[\ce{Mo(VI)}\] and \[\ce{and W(VI)}\].
(ii) \[\ce{Mo(VI)}\] and \[\ce{and W(VI)}\] are more stable than \[\ce{Cr(VI)}\].
(iii) Higher oxidation states of heavier members of group-6 of transition series are more stable.
(iv) Lower oxidation states of heavier members of group-6 of transition series are more stable.
Potassium dichromate when heated with concentrated sulphuric acid and a soluble chloride, gives brown-red vapours of ______.
Complete the following ionic equation:
\[\ce{Cr2O^{2-}7 + 2OH^- ->}\]
Indicate the steps in the preparation of \[\ce{K2Cr2O7}\] from chromite ore.
Describe the preparation of potassium permanganate. How does the acidified permanganate solution react with oxalic acid? Write the ionic equation for the reaction.
Indicate the steps in the preparation of \[\ce{K2Cr2O7}\] from chromite ore.
