Advertisements
Advertisements
प्रश्न
When orange solution containing \[\ce{Cr2O^{2-}7}\] ion is treated with an alkali, a yellow solution is formed and when \[\ce{H^+}\] ions are added to yellow solution, an orange solution is obtained. Explain why does this happen?
Advertisements
उत्तर
This is due to the interconversion of dichromate (orange) to chromate ion (yellow).
\[\ce{\underset{\underset{(Orange)}{Dichromate}}{Cr2O^{2-}7} ⇌[OH^-][H^+] \underset{\underset{(Yellow)}{Chromate}}{CrO^{2-}4}}\]
APPEARS IN
संबंधित प्रश्न
Complete the following equations:

Complete the following equations:Cr2O72- + 2OH- →
Name the oxometal anions of the first series of the transition metals in which the metal exhibits the oxidation state equal to its group number.
Give an example and suggest a reason for the following feature of the transition metal chemistry:
A transition metal exhibits the highest oxidation state in oxides and fluorides.
Indicate the steps in the preparation of K2Cr2O7 from chromite ore.
Name a member of the lanthanoid series that is well-known to exhibit +2 oxidation state.
E0 value for Mn3+ Mn2+ couple is much more positive than that for Cr3-/ Cr2-.
Answer the following question.
When MnO2 is fused with KOH in the presence of KNO3 as an oxidizing agent, it gives a dark green compound (A). Compound (A) disproportionates in an acidic solution to give a purple compound (B). An alkaline solution of compound (B) oxidizes KI to compound (C) whereas an acidified solution of compound (B) oxidizes KI to (D). Identify (A), (B), (C), and (D).
Generally transition elements and their salts are coloured due to the presence of unpaired electrons in metal ions. Which of the following compounds are coloured?
(i) \[\ce{KMnO4}\]
(ii) \[\ce{Ce(SO4)2}\]
(iii) \[\ce{TiCl}\]
(iv) \[\ce{Cu2 Cl2}\]
In the form of dichromate, \[\ce{Cr (VI)}\] is a strong oxidising agent in acidic medium but \[\ce{Mo (VI)}\] in \[\ce{MoO3}\] \[\ce{and W (VI)}\] in \[\ce{WO3}\] are not because:
(i) \[\ce{Cr(VI)}\] is more stable than \[\ce{Mo(VI)}\] and \[\ce{and W(VI)}\].
(ii) \[\ce{Mo(VI)}\] and \[\ce{and W(VI)}\] are more stable than \[\ce{Cr(VI)}\].
(iii) Higher oxidation states of heavier members of group-6 of transition series are more stable.
(iv) Lower oxidation states of heavier members of group-6 of transition series are more stable.
When \[\ce{Cu^2+}\] ion is treated with \[\ce{KI}\], a white precipitate is formed. Explain the reaction with the help of chemical equation.
Potassium permanganate acts as an oxidant in neutral, alkaline as well as acidic media. The final products obtained from it in the three conditions are, respectively.
What is the effect of pH on dichromate ion solution?
Complete the reaction mentioning all the products formed:
\[\ce{Cr2O^{2-}7 + 3H2S + 8H^+ ->}\]
Indicate the steps in the preparation of K2Cr2O7 from chromite ore.
Indicate the steps in the preparation of \[\ce{K2Cr2O7}\] from chromite ore.
Indicate the steps in the preparation of \[\ce{K2Cr2O7}\] from chromite ore.
Describe the preparation of potassium permanganate. How does the acidified permanganate solution react with SO2? Write the ionic equation for the reaction.
