Advertisements
Advertisements
प्रश्न
Give an example and suggest a reason for the following feature of the transition metal chemistry:
The highest oxidation state is exhibited in oxoanions of a metal.
Advertisements
उत्तर
Metal oxoanions show higher oxidation states, for example, in \[\ce{Cr2O^{2-}_7}\] the oxidation state of Cr is +6, while in \[\ce{MnO^-_4}\] the oxidation state of Mn is +7. The reason for the combination of metal with oxygen is that oxygen is a highly electronegative and oxidizing element.
APPEARS IN
संबंधित प्रश्न
Complete the following chemical equation
8MnO4- + 3S2O32- + H2O →
Complete the following equation : MnO4- + 8H+ + 5e- →
Describe the preparation of potassium dichromate from iron chromite ore. What is the effect of increasing pH on a solution of potassium dichromate?
Describe the preparation of potassium dichromate from iron chromite ore. What is the effect of increasing pH on a solution of potassium dichromate?
Give an example and suggest a reason for the following feature of the transition metal chemistry:
The lowest oxide of transition metal is basic, the highest is amphoteric/acidic.
Complete the following equations:
`2MnO_4^(-)+16H^++5S^(2-)rarr`
Answer the following question.
When MnO2 is fused with KOH in the presence of KNO3 as an oxidizing agent, it gives a dark green compound (A). Compound (A) disproportionates in an acidic solution to give a purple compound (B). An alkaline solution of compound (B) oxidizes KI to compound (C) whereas an acidified solution of compound (B) oxidizes KI to (D). Identify (A), (B), (C), and (D).
Zinc carbonate is precipitated from zinc sulphate solution by the addition of ___________.
Which of the following reactions are disproportionation reactions?
(a) \[\ce{Cu^{+} -> Cu^{2+} + Cu}\]
(b) \[\ce{3MnO^{-}4 + 4H^{+} -> 2MnO^{-}4 + MnO2 + 2H2O}\]
(c) \[\ce{2KMnO4 -> K2MnO4 + MnO2 + O2}\]
(d) \[\ce{2MnO^{-}4 + 3Mn^{2+} + 2H2O -> 5MnO2 + 4H^{+}}\]
When \[\ce{Cu^2+}\] ion is treated with \[\ce{KI}\], a white precipitate is formed. Explain the reaction with the help of chemical equation.
When orange solution containing \[\ce{Cr2O^{2-}7}\] ion is treated with an alkali, a yellow solution is formed and when \[\ce{H^+}\] ions are added to yellow solution, an orange solution is obtained. Explain why does this happen?
What is the effect of pH on dichromate ion solution?
Potassium permanganate on heating at 513 K gives a product which is ______.
Potassium dichromate when heated with concentrated sulphuric acid and a soluble chloride, gives brown-red vapours of ______.
Complete the reaction mentioning all the products formed:
\[\ce{Cr2O^{2-}7 + 3H2S + 8H^+ ->}\]
Indicate the steps in the preparation of \[\ce{K2Cr2O7}\] from chromite ore.
Indicate the steps in the preparation of \[\ce{K2Cr2O7}\] from chromite ore.
Indicate the steps in the preparation of \[\ce{K2Cr2O7}\] from chromite ore.
