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प्रश्न
When \[\ce{Cu^2+}\] ion is treated with \[\ce{KI}\], a white precipitate is formed. Explain the reaction with the help of chemical equation.
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उत्तर
Reduction of \[\ce{Cu^2+}\] to \[\ce{Cu^+}\] takes place due to reaction with F ions.
This is given by the equation.
\[\ce{2Cu^2+ + 4I^- -> \underset{(White precipitate)}{Cu2I2 + I2}}\]
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संबंधित प्रश्न
When chromite ore FeCr2O4 is fused with NaOH in presence of air, a yellow-coloured compound (A) is obtained, which on acidification with dilute sulphuric acid gives a compound (B). Compound (B) on reaction with KCl forms an orange coloured crystalline compound (C).
(i) Write the formulae of the compounds (A), (B) and C.
(ii) Write one use of compound (C).
Complete the following equations : MnO4- + 4H+ + 3e- →
Complete the following equation : MnO4- + 8H+ + 5e- →
Name the oxometal anions of the first series of the transition metals in which the metal exhibits the oxidation state equal to its group number.
Describe the preparation of potassium dichromate from iron chromite ore. What is the effect of increasing pH on a solution of potassium dichromate?
Give an example and suggest a reason for the following feature of the transition metal chemistry:
A transition metal exhibits the highest oxidation state in oxides and fluorides.
Indicate the steps in the preparation of K2Cr2O7 from chromite ore.
Write the formula of an oxo-anion of Manganese (Mn) in which it shows the oxidation state equal to its group number.
Account for the following :
Manganese shows maximum number of oxidation states in 3d series.
Zinc carbonate is precipitated from zinc sulphate solution by the addition of ___________.
Generally transition elements and their salts are coloured due to the presence of unpaired electrons in metal ions. Which of the following compounds are coloured?
(i) \[\ce{KMnO4}\]
(ii) \[\ce{Ce(SO4)2}\]
(iii) \[\ce{TiCl}\]
(iv) \[\ce{Cu2 Cl2}\]
In the form of dichromate, \[\ce{Cr (VI)}\] is a strong oxidising agent in acidic medium but \[\ce{Mo (VI)}\] in \[\ce{MoO3}\] \[\ce{and W (VI)}\] in \[\ce{WO3}\] are not because:
(i) \[\ce{Cr(VI)}\] is more stable than \[\ce{Mo(VI)}\] and \[\ce{and W(VI)}\].
(ii) \[\ce{Mo(VI)}\] and \[\ce{and W(VI)}\] are more stable than \[\ce{Cr(VI)}\].
(iii) Higher oxidation states of heavier members of group-6 of transition series are more stable.
(iv) Lower oxidation states of heavier members of group-6 of transition series are more stable.
The product formed upon heating methyl bromide with potassium tert-butoxide is
KMnO4 is coloured due to ______.
Complete the reaction mentioning all the products formed:
\[\ce{2KMnO4 ->[\Delta]}\]
Complete the reaction mentioning all the products formed:
\[\ce{Cr2O^{2-}7 + 3H2S + 8H^+ ->}\]
Which of the following ions will have a magnetic moment value of 1.73 BM.
\[\ce{Sc^3+, Ti^3+, Ti^2+, Cu^2+, Zn^2+}\]
Indicate the step in the preparation of K2Cr2O7 from chromite ore.
Indicate the steps in the preparation of \[\ce{K2Cr2O7}\] from chromite ore.
