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प्रश्न
Give an example and suggest a reason for the following feature of the transition metal chemistry:
A transition metal exhibits the highest oxidation state in oxides and fluorides.
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उत्तर
The highest oxidation states of transition metals are observed in oxides and fluorides. Because oxygen and fluorine are highly electronegative elements and small in size, they are strong oxidising agents. For example, osmium displays a +6 oxidation state in OsF6, and vanadium displays a +5 oxidation state in V2O5.
संबंधित प्रश्न
Complete the following equations:
Complete the following equations: Cr2O72- + 14H+ + 6I →
Complete the following equations : 2 MnO2 + 4 KOH + O2 →
Complete the following equations:Cr2O72- + 2OH- →
Complete the following equation : MnO4- + 8H+ + 5e- →
Give an example and suggest a reason for the following feature of the transition metal chemistry:
The lowest oxide of transition metal is basic, the highest is amphoteric/acidic.
Indicate the steps in the preparation of K2Cr2O7 from chromite ore.
Indicate the steps in the preparation of KMnO4 from pyrolusite ore.
Complete the following equations:
`2MnO_4^(-)+16H^++5S^(2-)rarr`
Complete the following equation :
Answer the following question.
When MnO2 is fused with KOH in the presence of KNO3 as an oxidizing agent, it gives a dark green compound (A). Compound (A) disproportionates in an acidic solution to give a purple compound (B). An alkaline solution of compound (B) oxidizes KI to compound (C) whereas an acidified solution of compound (B) oxidizes KI to (D). Identify (A), (B), (C), and (D).
Which of the following reactions are disproportionation reactions?
(a) \[\ce{Cu^{+} -> Cu^{2+} + Cu}\]
(b) \[\ce{3MnO^{-}4 + 4H^{+} -> 2MnO^{-}4 + MnO2 + 2H2O}\]
(c) \[\ce{2KMnO4 -> K2MnO4 + MnO2 + O2}\]
(d) \[\ce{2MnO^{-}4 + 3Mn^{2+} + 2H2O -> 5MnO2 + 4H^{+}}\]
\[\ce{KMnO4}\] acts as an oxidising agent in alkaline medium. When alkaline \[\ce{KMnO4}\] is treated with \[\ce{KI}\], iodide ion is oxidised to ______.
The product formed upon heating methyl bromide with potassium tert-butoxide is
KMnO4 is coloured due to ______.
Why \[\ce{HCl}\] should not be used for potassium permanganate titrations?
Complete the following ionic equation:
\[\ce{Cr2O^{2-}7 + 2OH^- ->}\]
Indicate the step in the preparation of K2Cr2O7 from chromite ore.
Indicate the steps in the preparation of \[\ce{K2Cr2O7}\] from chromite ore.
