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प्रश्न
Give an example and suggest a reason for the following feature of the transition metal chemistry:
A transition metal exhibits the highest oxidation state in oxides and fluorides.
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उत्तर
The highest oxidation state of transition metals is displayed in oxides and fluorides. Because oxygen and fluorine are highly electronegative elements and small in size, they are strong oxidizing agents. For example, Osmium displays a +6 oxidation state in OsF6, and Vanadium displays a +5 oxidation state in V2O5.
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संबंधित प्रश्न
When chromite ore FeCr2O4 is fused with NaOH in presence of air, a yellow-coloured compound (A) is obtained, which on acidification with dilute sulphuric acid gives a compound (B). Compound (B) on reaction with KCl forms an orange coloured crystalline compound (C).
(i) Write the formulae of the compounds (A), (B) and C.
(ii) Write one use of compound (C).
Complete the following equations : 2 MnO2 + 4 KOH + O2 →
Complete the following equations : MnO4- + 4H+ + 3e- →
Describe the preparation of potassium dichromate from iron chromite ore. What is the effect of increasing pH on a solution of potassium dichromate?
Indicate the steps in the preparation of K2Cr2O7 from chromite ore.
Write the formula of an oxo-anion of Manganese (Mn) in which it shows the oxidation state equal to its group number.
Complete the following equations:
`2MnO_4^(-)+16H^++5S^(2-)rarr`
Complete the following chemical equations :
Cu + H2SO4(conc.) →
E0 value for Mn3+ Mn2+ couple is much more positive than that for Cr3-/ Cr2-.
Zinc carbonate is precipitated from zinc sulphate solution by the addition of ___________.
Why \[\ce{HCl}\] should not be used for potassium permanganate titrations?
The oxidation state of manganese in the product obtained in a reaction of potassium permanganate and hydrogen peroxide in a basic medium is ______.
Potassium dichromate when heated with concentrated sulphuric acid and a soluble chloride, gives brown-red vapours of ______.
Complete the reaction mentioning all the products formed:
\[\ce{Cr2O^{2-}7 + 3H2S + 8H^+ ->}\]
Which of the following ions will have a magnetic moment value of 1.73 BM.
\[\ce{Sc^3+, Ti^3+, Ti^2+, Cu^2+, Zn^2+}\]
Describe the preparation of potassium permanganate. How does the acidified permanganate solution react with oxalic acid? Write the ionic equation for the reaction.
Indicate the steps in the preparation of \[\ce{K2Cr2O7}\] from chromite ore.
