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प्रश्न
E0 value for Mn3+ Mn2+ couple is much more positive than that for Cr3-/ Cr2-.
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उत्तर
Much larger 3rd ionisation energy of Mn (where the required change is d5 to d4) is mainly responsible for this.
Mn3+ = 
Mn2+ = 
→ Half filled (more stable)
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संबंधित प्रश्न
Complete the following equations:
Give an example and suggest a reason for the following feature of the transition metal chemistry:
The lowest oxide of transition metal is basic, the highest is amphoteric/acidic.
Complete the following equation :
On addition of small amount of \[\ce{KMnO4}\] to concentrated \[\ce{H2SO4}\], a green oily compound is obtained which is highly explosive in nature. Identify the compound from the following.
Which of the following reactions are disproportionation reactions?
(a) \[\ce{Cu^{+} -> Cu^{2+} + Cu}\]
(b) \[\ce{3MnO^{-}4 + 4H^{+} -> 2MnO^{-}4 + MnO2 + 2H2O}\]
(c) \[\ce{2KMnO4 -> K2MnO4 + MnO2 + O2}\]
(d) \[\ce{2MnO^{-}4 + 3Mn^{2+} + 2H2O -> 5MnO2 + 4H^{+}}\]
Potassium permanganate acts as an oxidant in neutral, alkaline as well as acidic media. The final products obtained from it in the three conditions are, respectively.
Potassium dichromate when heated with concentrated sulphuric acid and a soluble chloride, gives brown-red vapours of ______.
Indicate the steps in the preparation of \[\ce{K2Cr2O7}\] from chomite ore.
Indicate the steps in the preparation of \[\ce{K2Cr2O7}\] from chromite ore.
Describe the preparation of potassium permanganate. How does the acidified permanganate solution react with SO2? Write the ionic equation for the reaction.
