Advertisements
Advertisements
Question
Give an example and suggest a reason for the following feature of the transition metal chemistry:
A transition metal exhibits the highest oxidation state in oxides and fluorides.
Advertisements
Solution
The highest oxidation state of transition metals is displayed in oxides and fluorides. Because oxygen and fluorine are highly electronegative elements and small in size, they are strong oxidizing agents. For example, Osmium displays a +6 oxidation state in OsF6, and Vanadium displays a +5 oxidation state in V2O5.
RELATED QUESTIONS
Complete the following equations:

Complete the following equation:
\[\ce{2MnO4- + 6H+ + 5NO2- ->}\]
Complete the following equations : 2 Na2CrO4 + 2 H + →
Complete the following equations : MnO4- + 4H+ + 3e- →
Name the oxometal anions of the first series of the transition metals in which the metal exhibits the oxidation state equal to its group number.
Describe the preparation of potassium dichromate from iron chromite ore. What is the effect of increasing pH on a solution of potassium dichromate?
Write the chemical equation for the preparation of 4 KMnO from 2. MnO Why does purple colour of acidified permanganate solution decolourise when it oxidises Fe2- to Fe3+ ?
Using IUPAC norms, write the formula of potassium trioxalatochromate(III).
On addition of small amount of \[\ce{KMnO4}\] to concentrated \[\ce{H2SO4}\], a green oily compound is obtained which is highly explosive in nature. Identify the compound from the following.
Which of the following reactions are disproportionation reactions?
(a) \[\ce{Cu^{+} -> Cu^{2+} + Cu}\]
(b) \[\ce{3MnO^{-}4 + 4H^{+} -> 2MnO^{-}4 + MnO2 + 2H2O}\]
(c) \[\ce{2KMnO4 -> K2MnO4 + MnO2 + O2}\]
(d) \[\ce{2MnO^{-}4 + 3Mn^{2+} + 2H2O -> 5MnO2 + 4H^{+}}\]
\[\ce{KMnO4}\] acts as an oxidising agent in alkaline medium. When alkaline \[\ce{KMnO4}\] is treated with \[\ce{KI}\], iodide ion is oxidised to ______.
When \[\ce{Cu^2+}\] ion is treated with \[\ce{KI}\], a white precipitate is formed. Explain the reaction with the help of chemical equation.
The product formed upon heating methyl bromide with potassium tert-butoxide is
KMnO4 is coloured due to ______.
What is the effect of pH on dichromate ion solution?
Potassium permanganate on heating at 513 K gives a product which is ______.
In the two tetrahedral structures of dichromate ion, ______.
Indicate the steps in the preparation of \[\ce{K2Cr2O7}\] from chromite ore.
Indicate the steps in the preparation of \[\ce{K2Cr2O7}\] from chromite ore.
