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प्रश्न
Describe the preparation of potassium permanganate. How does the acidified permanganate solution react with oxalic acid? Write the ionic equation for the reaction.
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उत्तर
Potassium permanganate can be made by the following methods:
In the laboratory, salts of the manganese (II) ion are oxidized by oxydisulfate to form permanganates.
\[\ce{2Mn^{2+} + 5S2O^{2-}_8 + 8H2O -> 2MnO^-_4 + 10SO^{2-}_4 + 16H^+}\]
The chemical reactions of acidic potassium permanganate are as follows:
\[\begin{array}{cc}
\ce{COO^-}\phantom{.......}\\
\ce{2MnO^-_4 + 16H^+ + 5 | -> 2Mn^{2+} + 8H2O + 10CO2 ^}\\
\ce{COO^-}\phantom{.......}
\end{array}\]
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संबंधित प्रश्न
When chromite ore FeCr2O4 is fused with NaOH in presence of air, a yellow-coloured compound (A) is obtained, which on acidification with dilute sulphuric acid gives a compound (B). Compound (B) on reaction with KCl forms an orange coloured crystalline compound (C).
(i) Write the formulae of the compounds (A), (B) and C.
(ii) Write one use of compound (C).
Complete the following equation : MnO4- + 8H+ + 5e- →
Give an example and suggest a reason for the following feature of the transition metal chemistry:
A transition metal exhibits the highest oxidation state in oxides and fluorides.
Indicate the steps in the preparation of K2Cr2O7 from chromite ore.
Indicate the steps in the preparation of KMnO4 from pyrolusite ore.
Complete the following chemical equations :
Cu + H2SO4(conc.) →
E0 value for Mn3+ Mn2+ couple is much more positive than that for Cr3-/ Cr2-.
Answer the following question.
When MnO2 is fused with KOH in the presence of KNO3 as an oxidizing agent, it gives a dark green compound (A). Compound (A) disproportionates in an acidic solution to give a purple compound (B). An alkaline solution of compound (B) oxidizes KI to compound (C) whereas an acidified solution of compound (B) oxidizes KI to (D). Identify (A), (B), (C), and (D).
On addition of small amount of \[\ce{KMnO4}\] to concentrated \[\ce{H2SO4}\], a green oily compound is obtained which is highly explosive in nature. Identify the compound from the following.
Which of the following is amphoteric oxide?
\[\ce{Mn2O7, CrO3, Cr2O3, CrO, V2O5, V2O4}\]
What is the effect of pH on dichromate ion solution?
Complete the following ionic equation:
\[\ce{Cr2O^{2-}7 + 2OH^- ->}\]
Which of the following ions will have a magnetic moment value of 1.73 BM.
\[\ce{Sc^3+, Ti^3+, Ti^2+, Cu^2+, Zn^2+}\]
Indicate the steps in the preparation of \[\ce{K2Cr2O7}\] from chromite ore.
Indicate the steps in the preparation of \[\ce{K2Cr2O7}\] from chromite ore.
Indicate the steps in the preparation of \[\ce{K2Cr2O7}\] from chromite ore.
Indicate the steps in the preparation of \[\ce{K2Cr2O7}\] from chromite ore.
Describe the preparation of potassium permanganate. How does the acidified permanganate solution react with SO2? Write the ionic equation for the reaction.
Indicate the steps in the preparation of \[\ce{K2Cr2O7}\] from chromite ore.
