Advertisements
Advertisements
Question
Describe the preparation of potassium permanganate. How does the acidified permanganate solution react with oxalic acid? Write the ionic equation for the reaction.
Advertisements
Solution
Potassium permanganate can be made by the following methods:
In the laboratory, salts of the manganese (II) ion are oxidized by oxydisulfate to form permanganates.
\[\ce{2Mn^{2+} + 5S2O^{2-}_8 + 8H2O -> 2MnO^-_4 + 10SO^{2-}_4 + 16H^+}\]
The chemical reactions of acidic potassium permanganate are as follows:
\[\begin{array}{cc}
\ce{COO^-}\phantom{.......}\\
\ce{2MnO^-_4 + 16H^+ + 5 | -> 2Mn^{2+} + 8H2O + 10CO2 ^}\\
\ce{COO^-}\phantom{.......}
\end{array}\]
RELATED QUESTIONS
Complete the following equations: Cr2O72- + 14H+ + 6I →
Complete the following chemical equation
8MnO4- + 3S2O32- + H2O →
Complete the following equations : 2 Na2CrO4 + 2 H + →
Complete the following equations:Cr2O72- + 2OH- →
Name the oxometal anions of the first series of the transition metals in which the metal exhibits the oxidation state equal to its group number.
Indicate the steps in the preparation of KMnO4 from pyrolusite ore.
Write the formula of an oxo-anion of Manganese (Mn) in which it shows the oxidation state equal to its group number.
Complete the following equations:
`2MnO_4^(-)+16H^++5S^(2-)rarr`
Account for the following :
Manganese shows maximum number of oxidation states in 3d series.
Write the chemical equation for the preparation of 4 KMnO from 2. MnO Why does purple colour of acidified permanganate solution decolourise when it oxidises Fe2- to Fe3+ ?
Write the ionic equation showing the oxidation of Fe(II) salt by acidified dichromate solutions.
Using IUPAC norms, write the formula of potassium trioxalatochromate(III).
Zinc carbonate is precipitated from zinc sulphate solution by the addition of ___________.
\[\ce{KMnO4}\] acts as an oxidising agent in alkaline medium. When alkaline \[\ce{KMnO4}\] is treated with \[\ce{KI}\], iodide ion is oxidised to ______.
Potassium permanganate acts as an oxidant in neutral, alkaline as well as acidic media. The final products obtained from it in the three conditions are, respectively.
Indicate the steps in the preparation of K2Cr2O7 from chromite ore.
Indicate the steps in the preparation of \[\ce{K2Cr2O7}\] from chromite ore.
Indicate the steps in the preparation of \[\ce{K2Cr2O7}\] from chromite ore.
Indicate the steps in the preparation of \[\ce{K2Cr2O7}\] from chromite ore.
