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Out of CuX2ClX2 and CuClX2, which is more stable and why?

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प्रश्न

Out of \[\ce{Cu2Cl2}\] and \[\ce{CuCl2}\], which is more stable and why?

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उत्तर

\[\ce{CuCl2}\]  is more stable than  \[\ce{Cu2Cl2}\] . The stability of \[\ce{CuCl2}\]  is because of high enthalpy of hydration of \[\ce{Cu^2+ (aq)}\] than that of \[\ce{Cu+ (aq)}\].

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अध्याय 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [पृष्ठ १११]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 37 | पृष्ठ १११

संबंधित प्रश्न

Which of the following cations are coloured in aqueous solutions and why ?

Sc3+, V3+, Ti4+, Mn2+ (At. Nos. Sc = 21, V = 23, Ti = 22, Mn = 25)


Account for the following: 

Cr2+ is a strong reducing agent.


The elements of 3d transition series are given as: Sc Ti V Cr Mn Fe Co

Answer the following: Which element has the highest m.p?


Calculate the ‘spin only’ magnetic moment of \[\ce{M^{2+}_{( aq)}}\] ion (Z = 27).


What is meant by ‘disproportionation’? 


Following are the transition metal ions of 3d series:

Ti4+, V2+, Mn3+, Cr3+

(Atomic numbers: Ti = 22, V = 23, Mn = 25, Cr = 24)

Answer the following:

1) Which ion is most stable in an aqueous solution and why?

2) Which ion is a strong oxidising agent and why?

3) Which ion is colourless and why?


Complete and balance the following chemical equations

`Fe^(2+) + MnO_4^(-) + H^+ ->`


Dissociation of H2S is suppressed in acidic medium.


How is potassium dichromate prepared from chrome iron ore?


Transition metals with lowest melting point is ______.


Maximum oxidation state is shown by ____________.


Account for the following: 

In case of transition elements, ions of the same charge in a given series show progressive decrease in radius with increasing atomic number.


On strong heating AgNO3, the gases evolved are:-


Which one of the following characters tie of the transition metal is associated with higher catalytic activity?


Match List - I with List - II.

List - I List - II
(A) [Fe(CN)6]3− (i) 5.92 BM
(B) [Fe(H2O)6]3+ (ii) 0 BM
(C) [Fe(CN)6]4− (iii) 4.90 BM
(D) [Fe(H2O)6]2+ (iv) 1.73 BM

Choose the correct answer from the options given below.


Why is the `"E"_(("V"^(3+)//"V"^(2+)))^"o"` value for vanadium comparatively low?


In order to protect iron from corrosion, which one will you prefer as a sacrificial electrode, Ni or Zn? Why? (Given standard electrode potentials of Ni, Fe and Zn are -0.25 V, -0.44 V and -0.76 V respectively.)


The second ionization enthalpies of chromium and manganese are 1592 and 1509 kJ/mol respectively. Explain the lower value of Mn.


A pair of coloured ions is ______.


Match List-I with List-II.

List-I List-II
A. Haber process I. Fe catalyst
B. Wacker oxidation II. PdCl2
C. Wilkinson catalyst III. [(PPh3)3RhCl]
D. Ziegler catalyst IV. TiCl4 with Al(CH3)3

Choose the correct answer from the options given below:


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