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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Reactivity of transition elements decreases almost regularly from Sc to Cu. Explain.

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प्रश्न

Reactivity of transition elements decreases almost regularly from Sc to Cu. Explain.

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उत्तर

Reactivity of an element is dependent on the value of ionization enthalpy. In moving from Sc, the first element to Cu, the ionization enthalpy increases regularly. Therefore, the reactivity decreases as we move from Sc to Cu.

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अध्याय 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [पृष्ठ १११]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 51 | पृष्ठ १११

संबंधित प्रश्न

Account for the following:

Mn shows the highest oxidation state of +7 with oxygen but with fluorine, it shows oxidation state of +4.


Write the formula of an oxo-anion of Chromium (Cr) in which it shows the oxidation state equal to its group number


The paramagnetic character in the 3d-transition series elements increases up to Mn and then decreases.


Which among the following transition metal has the lowest melting point?


Which is the most stable oxidation state of iron?


Maximum oxidation state is shown by ____________.


Match the catalysts given in Column I with the processes given in Column II.

Column I (Catalyst) Column II (Process)
(i) \[\ce{Ni}\] in the presence of hydrogen (a) Zieglar Natta catalyst
(ii) \[\ce{Cu2C12}\] (b) Contact process
(iii) \[\ce{V2O5}\] (c) Vegetable oil to ghee
(iv) Finely divided iron (d) Sandmeyer reaction
(v) \[\ce{TiCl4 + Al (CH3)3}\] (e) Haber's Process
  (f) Decomposition of KCIO3

Assertion: Separation of \[\ce{Zr}\] and \[\ce{Hf}\] is difficult.

Reason: Because \[\ce{Zr}\] and \[\ce{Hf}\] lie in the same group of the periodic table.


On the basis of the figure given below, answer the following questions:

  1. Why Manganese has lower melting point than Chromium?
  2. Why do transition metals of 3d series have lower melting points as compared to 4d series?
  3. In the third transition series, identify and name the metal with the highest melting point.

The element with atomic number 46 belongs to


Mercury is the only metal liquid at room temperature due to its:-


A complex in which dsp2 hybridisation takes place is ______.


Which of the following characteristics of transition metals is associated with their catalytic activity?


Account for the following:

Sc3+ is colourless whereas Ti3+ is coloured in an aqueous solution.


Account for the following:

Eu2+ with electronic configuration [Xe]4f76s2 is a strong reducing agent.


A pair of coloured ions is ______.


Give a reason for the following:

Transition metals possess a great tendency to form complex compounds.


A coordination compound has the formula \[\ce{CoCl3.4NH3}\]. It precipitates silver ions as AgCl and its molar conductance corresponds to a total of two ions.

Based on this information, answer the following question:

  1. Deduce the structural formula of the complex compound.
  2. Write the IUPAC name of the complex compound.
  3. Draw the geometrical isomers of the complex compound.

Match List-I with List-II.

List-I List-II
A. Haber process I. Fe catalyst
B. Wacker oxidation II. PdCl2
C. Wilkinson catalyst III. [(PPh3)3RhCl]
D. Ziegler catalyst IV. TiCl4 with Al(CH3)3

Choose the correct answer from the options given below:


The E° value for the Mn2+/Mn2+ couple is more positive than that of Cr3+/Cr2+ or Fe3+/Fe2+ due to the change of:


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