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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

What are inner transition elements?

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प्रश्न

What are inner transition elements?

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उत्तर

Lanthanoids and actinoids are called inner transition elements because inner f-orbitals are progressively filled and the last electron goes to the anti-penultimate f-orbital.

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अध्याय 4: The d-block and f-block Elements - Exercises [पृष्ठ ११६]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
अध्याय 4 The d-block and f-block Elements
Exercises | Q 4.28 (i) | पृष्ठ ११६

संबंधित प्रश्न

What are interstitial compounds?


Why do interstitial compounds have higher melting points than corresponding pure metals?


Which of the following cations are coloured in aqueous solutions and why ?

Sc3+, V3+, Ti4+, Mn2+ (At. Nos. Sc = 21, V = 23, Ti = 22, Mn = 25)


 
 
 

Complete the following chemical equations:

`(i) Cr_2O_7^(2-)+6Fe^(2+)+14H^+ ->`

`(ii) 2CrO_4^(2-)+2H^+ ->`

`(iii) 2MnO_4^-+5C_2O_4^(2-)+16H^+ ->`

 
 
 

How would you account for the following: Transition metals form complex compounds.


Give reasons:

Transition metals show variable oxidation states.


How would you account for the following:

Of the d4 species, Cr2+ is strongly reducing while manganese (III) is strongly oxidising.


Which metal in the first series of transition metals exhibits +1 oxidation state most frequently and why?


NF3 is possible, but NF5 is not. Why?


How would you account for the following? 

Zr (Z = 40) and Hf (Z = 72) have almost identical radii.

 


An analysis shows that FeO has a non-stoichiometric composition with formula Fe0.95O. Give reason.


Transition metals with lowest melting point is ______.


Explain why does colour of KMnO4 disappear when oxalic acid is added to its solution in acidic medium.


Assertion: The highest oxidation state of osmium is +8.

Reason: Osmium is a 5d-block element.


Read the passage given below and answer the following question.

Are there nuclear reactions going on in our bodies?

There are nuclear reactions constantly occurring in our bodies, but there are very few of them compared to the chemical reactions, and they do not affect our bodies much. All of the physical processes that take place to keep a human body running are chemical processes. Nuclear reactions can lead to chemical damage, which the body may notice and try to fix. The nuclear reaction occurring in our bodies is radioactive decay. This is the change of a less stable nucleus to a more stable nucleus. Every atom has either a stable nucleus or an unstable nucleus, depending on how big it is and on the ratio of protons to neutrons. The ratio of neutrons to protons in a stable nucleus is thus around 1 : 1 for small nuclei (Z < 20). Nuclei with too many neutrons, too few neutrons, or that are simply too big are unstable. They eventually transform to a stable form through radioactive decay. Wherever there are atoms with unstable nuclei (radioactive atoms), there are nuclear reactions occurring naturally. The interesting thing is that there are small amounts of radioactive atoms everywhere: in your chair, in the ground, in the food you eat, and yes, in your body.

The most common natural radioactive isotopes in humans are carbon-14 and potassium-40. Chemically, these isotopes behave exactly like stable carbon and potassium. For this reason, the body uses carbon-14 and potassium-40 just like it does normal carbon and potassium; building them into the different parts of the cells, without knowing that they are radioactive. In time, carbon-14 atoms decay to stable nitrogen atoms and potassium-40 atoms decay to stable calcium atoms. Chemicals in the body that relied on having a carbon-14 atom or potassium-40 atom in a certain spot will suddenly have a nitrogen or calcium atom. Such a change damages the chemical. Normally, such changes are so rare, that the body can repair the damage or filter away the damaged chemicals.

The natural occurrence of carbon-14 decay in the body is the core principle behind carbon dating. As long as a person is alive and still eating, every carbon-14 atom that decays into a nitrogen atom is replaced on average with a new carbon-14 atom. But once a person dies, he stops replacing the decaying carbon-14 atoms. Slowly the carbon-14 atoms decay to nitrogen without being replaced, so that there is less and less carbon-14 in a dead body. The rate at which carbon-14 decays is constant and follows first order kinetics. It has a half-life of nearly 6000 years, so by measuring the relative amount of carbon-14 in a bone, archeologists can calculate when the person died. All living organisms consume carbon, so carbon dating can be used to date any living organism, and any object made from a living organism. Bones, wood, leather, and even paper can be accurately dated, as long as they first existed within the last 60,000 years. This is all because of the fact that nuclear reactions naturally occur in living organisms.

Researchers have uncovered the youngest known dinosaur bone, dating around 65 million years ago. How was the age of this fossil estimated?


Read the passage given below and answer the following question.

Are there nuclear reactions going on in our bodies?

There are nuclear reactions constantly occurring in our bodies, but there are very few of them compared to the chemical reactions, and they do not affect our bodies much. All of the physical processes that take place to keep a human body running are chemical processes. Nuclear reactions can lead to chemical damage, which the body may notice and try to fix. The nuclear reaction occurring in our bodies is radioactive decay. This is the change of a less stable nucleus to a more stable nucleus. Every atom has either a stable nucleus or an unstable nucleus, depending on how big it is and on the ratio of protons to neutrons. The ratio of neutrons to protons in a stable nucleus is thus around 1 : 1 for small nuclei (Z < 20). Nuclei with too many neutrons, too few neutrons, or that are simply too big are unstable. They eventually transform to a stable form through radioactive decay. Wherever there are atoms with unstable nuclei (radioactive atoms), there are nuclear reactions occurring naturally. The interesting thing is that there are small amounts of radioactive atoms everywhere: in your chair, in the ground, in the food you eat, and yes, in your body.

The most common natural radioactive isotopes in humans are carbon-14 and potassium-40. Chemically, these isotopes behave exactly like stable carbon and potassium. For this reason, the body uses carbon-14 and potassium-40 just like it does normal carbon and potassium; building them into the different parts of the cells, without knowing that they are radioactive. In time, carbon-14 atoms decay to stable nitrogen atoms and potassium-40 atoms decay to stable calcium atoms. Chemicals in the body that relied on having a carbon-14 atom or potassium-40 atom in a certain spot will suddenly have a nitrogen or calcium atom. Such a change damages the chemical. Normally, such changes are so rare, that the body can repair the damage or filter away the damaged chemicals.

The natural occurrence of carbon-14 decay in the body is the core principle behind carbon dating. As long as a person is alive and still eating, every carbon-14 atom that decays into a nitrogen atom is replaced on average with a new carbon-14 atom. But once a person dies, he stops replacing the decaying carbon-14 atoms. Slowly the carbon-14 atoms decay to nitrogen without being replaced, so that there is less and less carbon-14 in a dead body. The rate at which carbon-14 decays is constant and follows first order kinetics. It has a half-life of nearly 6000 years, so by measuring the relative amount of carbon-14 in a bone, archeologists can calculate when the person died. All living organisms consume carbon, so carbon dating can be used to date any living organism, and any object made from a living organism. Bones, wood, leather, and even paper can be accurately dated, as long as they first existed within the last 60,000 years. This is all because of the fact that nuclear reactions naturally occur in living organisms.

Which are the two most common radioactive decays happening in human body?


Which of the following ions acts as a typical transition metal ion?


Assertion (A): Transition metals have high enthalpy of atomisation.

Reason (R): Greater number of unpaired electrons in transition metals results in weak metallic bonding.


Give a reason for the following.

Some transition metals and their compounds get attracted towards the magnetic field.


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