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Why EΘ values for Mn, Ni and Zn are more negative than expected? - Chemistry

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प्रश्न

Why EΘ values for Mn, Ni and Zn are more negative than expected?

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उत्तर

Negative E° values of Mn2+ and Zn2+ are because of stabilities of half-filled (3d10 : Mn2+) and fully-filled (3d10 : Zn2+) configuration respectively.Mn2+ ion has higher EΘ value because of highest negative enthalpy of hydrogen.

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अध्याय 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [पृष्ठ १११]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
अध्याय 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 33 | पृष्ठ १११

संबंधित प्रश्न

Which of the d-block elements may not be regarded as the transition elements?


Compare the stability of +2 oxidation state for the elements of the first transition series.


How would you account for the following:

Cobalt (II) is stable in aqueous solutions, but in the presence of complexing reagents, it is easily oxidised.


Comment on the statement that elements of the first transition series possess many properties different from those of heavier transition elements.


Write balanced chemical equations for the conversion of `CrO_4^(2-)` to `Cr_2O_7^(2-)` in acidic medium and `Cr_2O_7^(2-)` to `CrO_4^(2-)`
 in basic medium.


Transition metals with highest melting point is ____________.


Maximum oxidation state is shown by ____________.


Why does copper not replace hydrogen from acids?


When an oxide of manganese (A) is fused with KOH in the presence of an oxidising agent and dissolved in water, it gives a dark green solution of compound (B). Compound (B) disproportionates in neutral or acidic solution to give purple compound (C). An alkaline solution of compound (C) oxidises potassium iodide solution to a compound (D) and compound (A) is also formed. Identify compounds A to D and also explain the reactions involved.


Answer the following question:

Which element of the first transition series has highest third ionisation enthalpy?


Answer the following question:

Which element of the first transition series has lowest enthalpy of atomisation?


The element with atomic number 46 belongs to


Which of the following species has maximum magnetic momentum?


The basic character of transition metals monoxide follow the order.


Which of the following transition metal is not coloured?


Account for the following:

Transition metals form alloys.


The electrode potential of M2+/M of 3d-series elements shows the positive value for ______.


The oxidation state of Fe in [Fe(CO)5] is ______.


Give two similarities in the properties of Sc and Zn.


Give a reason for the following.

Some transition metals and their compounds get attracted towards the magnetic field.


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