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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Identify the metal and justify your answer. Carbonyl M(CO)X5

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प्रश्न

Identify the metal and justify your answer.

Carbonyl \[\ce{M(CO)5}\]

दीर्घउत्तर
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उत्तर

\[\ce{Fe(CO)5}\] as per EAN Rule. 

EAN Rule: Effective atomic number (EAN), number that represents the total number of electrons surrounding the nucleus of a metal atom in a metal complex. 

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अध्याय 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [पृष्ठ ११५]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 68.(b).(i) | पृष्ठ ११५

संबंधित प्रश्न

Why is Sc3+ colourless while Ti3+ coloured? (Atomic number Sc = 21, Ti =22)


Account for the following:

Cu+2 salts are coloured, while Zn2+ salts are white.


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Answer the following: Which element shows only +3 oxidation state?


Which is a stronger reducing agent, Cr2+ or Fe2+ and why?


Explain why Cu+ ion is not stable in aqueous solutions?


Calculate the number of unpaired electrons in the following gaseous ions:

Mn3+, Cr3+, V3+ and Ti3+. Which one of these is the most stable in an aqueous solution?


Give reasons Iron has the higher enthalpy of atomization than that of copper.


Why do transition metals exhibit higher enthalpy of atomization? 


Which among the following transition metal has the lowest melting point?


When acidified \[\ce{K2Cr2O7}\] solution is added to \[\ce{Sn^{2+}}\] salts then \[\ce{Sn^{2+}}\] changes to ______.


Transition elements form binary compounds with halogens. Which of the following elements will form \[\ce{MF3}\] type compounds?

(i) \[\ce{Cr}\]

(ii) \[\ce{Co}\]

(iii) \[\ce{Cu}\]

(iv) \[\ce{Ni}\]


Match the properties given in Column I with the metals given in Column II.

  Column I (Property) Column II (Metal)
(i) Element with highest second
ionisation enthalpy
(a) \[\ce{Co}\]
(ii) Element with highest
third ionisation enthalpy
(b) \[\ce{Cr}\]
(iii) \[\ce{M}\] in \[\ce{M(CO)6}\] is (c) \[\ce{Cu}\]
(iv) Element with highest heat
of atomisation
(d) \[\ce{Zn}\]
    (e) \[\ce{Ni}\]

Identify the metal and justify your answer.

\[\ce{MO3F}\]


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Give reason for the following statement:

[Ti(H2O)]3+ is coloured while [Sc(H2O)6]3+ is colourless.


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\[\ce{FeCr2O4 + Na2CO3 + O2 -> A + Fe2O3 + CO2}\]

\[\ce{A + H^+ -> B + H2O + Na^+}\]


Consider the following standard electrode potentials (E° in volts) in aqueous solution:

Element M3+/M M+/M
Al - 1.66 +0.55
Tl + 1.26 -0.34

Based on these data, which of the following statements is correct?


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Explain the reason why Cr has the highest melting point and manganese (Mn) has a lower melting point.


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Eu2+ with electronic configuration [Xe]4f76s2 is a strong reducing agent.


Decide which of the following atomic numbers are the atomic numbers of the inner transition elements:

29, 59, 74, 95, 102, 104


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