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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Identify the metal and justify your answer. Carbonyl M(CO)X5

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प्रश्न

Identify the metal and justify your answer.

Carbonyl \[\ce{M(CO)5}\]

दीर्घउत्तर
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उत्तर

\[\ce{Fe(CO)5}\] as per EAN Rule. 

EAN Rule: Effective atomic number (EAN), number that represents the total number of electrons surrounding the nucleus of a metal atom in a metal complex. 

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पाठ 8: The d-and f-Block Elements - Multiple Choice Questions (Type - I) [पृष्ठ ११५]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 8 The d-and f-Block Elements
Multiple Choice Questions (Type - I) | Q 68.(b).(i) | पृष्ठ ११५

संबंधित प्रश्‍न

How would you account for the following? 

Transition metals exhibit variable oxidation states.

 


Give reasons:

Transition metals show variable oxidation states.


How is the variability in oxidation states of transition metals different from that of the non-transition metals? Illustrate with examples.


Compare the stability of +2 oxidation state for the elements of the first transition series.


An antifriction alloy made up of antimony with tin and copper, which is extensively used in machine bearings is called _______.

(A) Duralumin

(B) Babbitt metal

(C) Spiegeleisen

(D) Amalgam


Write the formula of an oxo-anion of Chromium (Cr) in which it shows the oxidation state equal to its group number


Give reasons: 

E° value for the Mn3+/Mn2+ couple is much more positive than that for Fe3+/Fe2+.


Explain why transition elements form alloys.


Electronic configuration of a transition element X in +3 oxidation state is [Ar]3d5. What is its atomic number?


The magnetic moment is associated with its spin angular momentum and orbital angular momentum. Spin only magnetic moment value of Cr3+ ion is ______.


When acidified \[\ce{K2Cr2O7}\] solution is added to \[\ce{Sn^{2+}}\] salts then \[\ce{Sn^{2+}}\] changes to ______.


Which of the following ions show higher spin only magnetic moment value?

(i) \[\ce{Ti^3+}\]

(ii) \[\ce{Mn2+}\]

(iii) \[\ce{Fe2+}\]

(iv) \[\ce{Co3+}\]


The second and third rows of transition elements resemble each other much more than they resemble the first row. Explain why?


Assertion: \[\ce{Cu^2+}\] iodide is not known.

Reason: \[\ce{Cu^2+}\] oxidises \[\ce{I^-}\] to iodine.


The orientation of an atomic orbital is governed by


Match List - I with List - II.

List - I List - II
(A) [Fe(CN)6]3− (i) 5.92 BM
(B) [Fe(H2O)6]3+ (ii) 0 BM
(C) [Fe(CN)6]4− (iii) 4.90 BM
(D) [Fe(H2O)6]2+ (iv) 1.73 BM

Choose the correct answer from the options given below.


The disproportionation of \[\ce{MnO^{2-}_4}\] in acidic medium resulted in the formation of two manganese compounds A and B. If the oxidation state of Mn in B is smaller than that of A, then the spin-only magnetic moment (µ) value of B in BM is ______. (Nearest integer)


Which of the following transition metals shows +1 and +2 oxidation states?


Give a reason for the following:

Transition metals possess a great tendency to form complex compounds.


Why are interstitial compounds well known for transition metals?


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