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प्रश्न
Decide which of the following atomic numbers are the atomic numbers of the inner transition elements:
29, 59, 74, 95, 102, 104
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उत्तर
Elements having atomic numbers 59, 95, and 102 are classified as inner transition metals because they are lanthanoids and actinoids.
Pr (59): 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f3
Am (95): 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10 6p6 7s2 5f7
No (102): 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10 6p6 7s2 5f14
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संबंधित प्रश्न
Why is Sc3+ colourless while Ti3+ coloured? (Atomic number Sc = 21, Ti =22)
Explain why is Fe3+ more stable than Fe2+?
Account for the following:
E° value for the Mn3+/Mn2+ couple is much more positive than that for Cr3+/Cr2+.
In the series Sc (Z = 21) to Zn (Z = 30), the enthalpy of atomization of zinc is the lowest, i.e., 126 kJ mol−1. Why?
Write the factors which are related to the colour of transition metal ions.
Why does the density of transition elements increase from Titanium to Copper? (at. no. Ti = 22, Cu = 29)
Account for the following :
Ti4+ is colourless whereas V4+ is coloured in an aqueous solutions.
Give reasons for the following:
The transition metals generally form coloured compounds.
Transition metals with lowest melting point is ______.
Electronic configuration of a transition element X in +3 oxidation state is [Ar]3d5. What is its atomic number?
Interstitial compounds are formed when small atoms are trapped inside the crystal lattice of metals. Which of the following is not the characteristic property of interstitial compounds?
Match the catalysts given in Column I with the processes given in Column II.
| Column I (Catalyst) | Column II (Process) |
| (i) \[\ce{Ni}\] in the presence of hydrogen | (a) Zieglar Natta catalyst |
| (ii) \[\ce{Cu2C12}\] | (b) Contact process |
| (iii) \[\ce{V2O5}\] | (c) Vegetable oil to ghee |
| (iv) Finely divided iron | (d) Sandmeyer reaction |
| (v) \[\ce{TiCl4 + Al (CH3)3}\] | (e) Haber's Process |
| (f) Decomposition of KCIO3 |
Match the properties given in Column I with the metals given in Column II.
| Column I (Property) | Column II (Metal) | |
| (i) | Element with highest second ionisation enthalpy |
(a) \[\ce{Co}\] |
| (ii) | Element with highest third ionisation enthalpy |
(b) \[\ce{Cr}\] |
| (iii) | \[\ce{M}\] in \[\ce{M(CO)6}\] is | (c) \[\ce{Cu}\] |
| (iv) | Element with highest heat of atomisation |
(d) \[\ce{Zn}\] |
| (e) \[\ce{Ni}\] |
Assertion: \[\ce{Cu^2+}\] iodide is not known.
Reason: \[\ce{Cu^2+}\] oxidises \[\ce{I^-}\] to iodine.
Assertion (A): Cu cannot liberate hydrogen from acids.
Reason (R): Because it has positive electrode potential.
Account for the following:
In case of transition elements, ions of the same charge in a given series show progressive decrease in radius with increasing atomic number.
Which of the following characteristics of transition metals is associated with their catalytic activity?
Which of the following transition metals shows +1 and +2 oxidation states?
Give a reason for the following:
Zinc, cadmium and mercury are considered as d-block elements but not regarded as transition elements.
Match List-I with List-II.
| List-I | List-II |
| A. Haber process | I. Fe catalyst |
| B. Wacker oxidation | II. PdCl2 |
| C. Wilkinson catalyst | III. [(PPh3)3RhCl] |
| D. Ziegler catalyst | IV. TiCl4 with Al(CH3)3 |
Choose the correct answer from the options given below:
