- Carbon forms many compounds, from simple ones like methane to complex ones like DNA, due to its bonding versatility.
- Catenation allows carbon to form long chains or rings by bonding with itself.
- Carbon forms single, double, and triple covalent bonds, leading to saturated and unsaturated compounds.
- Being tetravalent, carbon forms four strong covalent bonds with elements like H, O, N, and Cl.
- Isomerism increases the number of carbon compounds by allowing different structures with the same molecular formula.
Definitions [25]
Definition: Covalent Molecule
The molecule formed due to the sharing of electrons (covalent bond) is called a covalent molecule.
Definition: Covalent Compound
The chemical bond that is formed between two combining atoms by mutual sharing of one or more pairs of electrons is called a covalent (or a molecular) bond, and the compound formed due to this bond is called a covalent compound.
Define a coordinate bond.
The bond formed between two atoms by sharing a pair of electrons, provided entirely by one of the combining atoms but shared by both, is called a coordinate bond.
Define a covalent bond.
The chemical bond formed between two combining atoms by mutual sharing of one or more pairs of electrons is called a covalent bond.
Define Allotrophy
When an element possess 2 or more different forms in the same state, they are called allotropes and the phenomenon is known as allotropy. Diamond and graphite are the 2 allotropes of carbon.
Define the following:
Adsorption
Adsorption is the property due to which a substance absorbs gases, liquids and solids on its surface.
Define the following:
Carbonization
The process of the slow conversion of vegetable matter into carbon-rich substances is called carbonization.
Define catenation.
Carbon possesses a unique property of combining with other carbon atoms to form long chains. This property is called catenation. The chains can be straight, branched or closed.
The self-linking property of atoms of an element to form very long straight or branched chains and cyclic rings is known as catenation. This property is shown by carbon whose small size and tetravalency helps it to form large structures by self-linking.
Definition: Tetravalency of Carbon
The characteristic of the carbon atom, by virtue of which it forms four covalent bonds, is called the tetravalency of carbon.
Definition: Catenation
The property of self-linking of atoms of an element through covalent bonds in order to form straight chains, branched chains and cyclic chains of different sizes is known as catenation.
Definition: Organic Compounds
Organic compounds are the compounds of carbon.
Define of chain isomerism.
When two or more compounds have a similar molecular formula but are different in the arrangement of carbon atoms in straight or branched chains, the compounds are referred to as chain isomers.
Define isomerism.
Compounds having the same molecular formula but different structural formulas are called isomers and the phenomenon is called isomerism.
Define a functional group.
An atom or a group of atoms attached to an alkyl group, which takes part in most of the chemical reactions, is called a functional group or functional radical.
Definition: Unsaturated Carbon Compounds
The compounds of carbon having double or triple bonds between the carbon atoms are known as unsaturated carbon compounds.
Definition: Saturated Compounds
The valencies of all the atoms are satisfied by single bonds between them. Such carbon compounds are called saturated compounds.
Definition: Functional Groups
The heteroatoms and the group containing these confer specific properties to the compound, regardless of the length and nature of the carbon chain and hence are called functional groups.
Definition: Alkanes
The saturated hydrocarbons are called alkanes.
Definition: Alkenes
The unsaturated hydrocarbons which contain one or more double bonds are called alkenes.
Definition: Alkynes
Those containing one or more triple bonds are called alkynes.
Definition: Structural Isomers
Compounds with identical molecular formula but different structures are called structural isomers.
Definition: Hydrocarbons
The carbon compounds which contain only carbon and hydrogen are called hydrocarbons.
Define Homologous series.
A series of compounds with similar chemical properties, in which members differ from one another by an additional CH2 group, is called a homologous series.
Definition: Homologous Series
The same functional group substitutes for hydrogen in a carbon chain is called a homologous series.
OR
A homologous series is a group of organic compounds having similar structure and similar chemical properties in which the successive compounds differ by a CH2 group.
OR
The series of compounds formed by joining the same functional group in the place of a particular hydrogen atom on the chains having sequentially increasing length is called homologous series.
Definition: Nomenclature
Nomenclature is the system of assignment of names to organic compounds.
Formulae [1]
Give the general formula of carboxylic acids.
CnH2n+1COOH (or RCOOH)
Key Points
Key Points: The Covalent Bond
- Carbon forms covalent bonds by sharing electrons to achieve a noble gas configuration.
- Covalent bonds can be single, double, or triple, as seen in molecules like H₂, O₂, and N₂.
- Covalent compounds have low melting and boiling points and are poor conductors of electricity.
- Carbon has allotropes such as diamond, graphite, and fullerene (C₆₀), each with different physical properties.
Key Points: Carbon: A Versatile Element
Key Points: Organic Compounds
Key Points: Homologous Series
Key points: Nomenclature of Carbon Compounds
- The IUPAC system provides a unique, systematic way to name carbon compounds based on structure, replacing confusing common names.
- An IUPAC name has three parts: prefix, parent, and suffix, reflecting the carbon chain and functional group.
- The parent name is based on the longest carbon chain, and its ending changes to –ane, –ene, or –yne depending on the number of bonds.
- Functional groups are shown as prefixes or suffixes, and the chain is numbered to give them the lowest possible number.
- If the suffix begins with a vowel, the final ‘e’ in the parent alkane name is dropped (e.g., propane → propanone).
Key Points: Combustion
Key Points: Ethanol
- Ethanol is a colourless liquid with a boiling point of 78 °C, soluble in water, and used in medicines, drinks, and as a clean-burning fuel (e.g., gasohol).
- Ethanol reacts with sodium to form sodium ethoxide and hydrogen gas is evolved.
- When heated with concentrated H₂SO₄ at 170 °C, ethanol undergoes dehydration to form ethene, an unsaturated compound.
- Methanol is highly poisonous, and industrial ethanol is made unfit for drinking by mixing methanol and adding a blue dye (denatured spirit).
Key Points: Ethanoic Acid
- Ethanoic acid (acetic acid) is a carboxylic acid; its 5–8% aqueous solution is vinegar, and it shows acidic nature by turning blue litmus red.
- Pure ethanoic acid freezes at 17 °C (290 K), so it is called glacial acetic acid.
- Being a weak acid, ethanoic acid is not completely ionised in aqueous solution.
- Ethanoic acid reacts with bases, carbonates, and bicarbonates to form a salt, water, and CO₂ (CO₂ turns lime water milky).
- It reacts with ethanol in the presence of conc. H₂SO₄ to form an ester (ethyl ethanoate) with a sweet smell (esterification).
Key Points: Soaps and Detergents
Important Questions [160]
- Name the following: CHA3−CHA2CH=CHA2
- Elements Forming Ionic Compounds Attain Noble Gas Electronic Configuration by Either Gaining Or Losing Electrons from Their Valence Shells. Explain Giving Reason Why Carbon Cannot Attain Such
- Carbon can neither form C4- cation nor C4 anion. Why?
- What Are Covalent Compounds?
- Why Covalent Compounds Are Different from Ionic Compounds?
- List Three Characteristic Properties of Covalent Compounds.
- It is observed that covalent compounds are had conductors of electricity. Give reason.
- The electron dot structure of chlorine molecule is:
- The number of single and double bonds present in a molecule of benzene (C6H6) respectively, are ______.
- Explain Why Carbon Forms Compounds Mainly by Covalent Bond.
- Assertion (A): Melting point and boiling point of ethanol are lower than that of sodium chloride. Reason (R): The forces of attraction between the molecules of ionic compounds are very strong.
- Show the covalent bond formation in nitrogen molecule.
- Elements Forming Ionic Compounds Attain Noble Gas Configuration by Either Gaining Or Losing Electrons from Their Outermost Shells. Give Reason to Explain Why Carbon Cannot Attain Noble Gas Configuration in this Manner to Form Its Compounds.
- Name the Type of Bonds Formed in Ionic Compounds and in the Compounds Formed by Carbon.
- Give Reason Why Carbon Compounds Are Generally Poor Conductors of Electricity.
- State the reason why carbon can neither form C4+ cations nor C4− anions but forms covalent compound.
- State the reason to explain why covalent compounds "are bad conductors of electricity".
- State the Reason to Explain Why Covalent Compounds "Have Low Melting and Boiling Points."
- State the reasons, why carbon cannot (i) Lose four electrons to form C4+ cation and (ii) Gain four electrons to form C4- anion. How does carbon overcome this problem to form compounds?
- Carbon prefers to share its valence electrons with other atoms of carbon or with atoms of other elements rather than gaining or losing the valence electrons
- List two differences between the properties exhibited by covalent compounds and ionic compounds.
- What is Methane? Draw Its Electron Dot Structure. Name the Type of Bonds Formed in this Compound. Why Are Such Compounds: (I) Poor Conductors of Electricity? and (Ii) Have Low Melting and
- Why Are Most Carbon Compounds Poor Conductors of Electricity?
- Compare the properties of ionic compounds and covalent compounds.
- Explain, Giving Reason, Why Carbon Neither Forms C4+ Cations Nor C4− Anions, but Forms Covalent Compounds Which Are Bad Conductors of Electricity and Have Low Melting Point and Low Boiling Point.
- Which Element Exhibits the Property of Catenation to Maximum Extent and Why?
- Write the number of covalent bonds in the molecule of butane, C4H10.
- Distinguish Between Ionic and Covalent Compounds Under the Following Properties:
- "Two different forms of carbon - diamond and graphite have different structure and very different physical properties even though their chemical properties are same." Explain why.
- Answer the Following Question. What is Methane?
- Answer the Following Question. Why Are Methane Compounds Have Low Melting and Boiling Points?
- Draw the Structures for Ethanoic Acid.
- Answer the Following Question. Why Are Methane Compounds Have Poor Conductors of Electricity?
- Give the Structural Difference Between Saturated and Unsaturated Hydrocarbons with Two Examples Each.
- Answer the Following Question. Name the Type of Bonds Formed in the Methane Compound.
- State Two Characteristic Features of Carbon Which When Put Together Give Rise to a Large Number of Carbon Compounds.
- Name of the Following Compounds :
- What is Hydrocarbon? Give Its One Example.
- Write the molecular formula of the 2nd and 3rd member of the homologous series whose first member is ethene.
- Answer the Following Question. Draw Methane Electron Dot Structure.
- Explain the Ways in Which Glucose is Broken Down in Absence Or Shortage of Oxygen.
- List the Conclusions You Will Draw While Studying the Following Properties of Ethanoic Acid :
- List Any Two Abiotic Components of an Ecosystem.
- Answer the Following Question. What Happens When Methane Compound Burns in Oxygen?
- What is homologous series?
- Two Statements Are Given - One Labeled Assertion a and the Other Labeled Reason R. Assertion A: In a Homologous Series of Alcohols, the Formula for the Second Member is C2h5oh and
- Name and draw the electron dot structure of first homologue of alkynes series.
- Name the third homologue of aldehydes.
- What is meant by homologous series of carbon compounds?
- Classify the following carbon compounds into two homologous series and name them. C3H4, C3H6, C4H6, C4H8, C5H8, C5H10
- Write the name and formula of the 2nd member of homologous series having general formula CnH2n.
- Write the Name and Molecular Formula of the First Member of the Homologous Series of Alkynes.
- Write the name and formula of the 2nd member of homologous series having general formula CnH2n + 2.
- Write the name and formula of the 2nd member of homologous series having general formula CnH2n – 2.
- The following vegetables are kept in a basket : Potato, Tomato, Radish, Brinjal, Carrot, Bottle-gourd Which two of these vegetables correctly represent the homologous structures?
- Write the molecular formula of two consecutive members of homologous series of aldehydes. State which part of these compounds determines their (i) physical and (ii) chemical properties.
- Write the next homologue of the following: C4H6
- Consider the carbon compounds having following molecular formula: (i) C3H6 (ii) C3H8 (iii) C4H6 (iv) C6H6 (v) C6H12 (i) State the number of double covalent bonds present in C3H8.
- Consider the carbon compounds having following molecular formula: (i) C2H2 (ii) C2H5 (iii) C3H7OH (iv) C2H6COOH (v) CH3CHO
- Consider the following molecular formulae of carbon compounds: (i) CH3COOH (ii) CH3OH (iii) C2H6 (iv) C3H4 (v) C4H8 (a) Which one of these compounds belongs to homologous series of alcohols?
- Consider the carbon compounds having following molecular formula: (i) C3H6 (ii) C3H8 (iii) C4H6 (iv) C6H6 (v) C6H12 (a) State the number of double covalent bonds present in C3H6.
- Write the chemical formula of two consecutive homologous of organic compounds having functional group - OH. What happens to the (i) boiling point and (ii) solubility of organic compounds.
- Write the Molecular Formula of the First Two Members of the Homologous Series Having Functional Group
- Write the molecular formula of first two members of homologous series having functional group -Cl.
- Name the third homologue of alcohols.
- Distinguish Between Homologous Organs and Analogous Organs. in Which Category Would You Place Wings of a Bird and Wings of a Bat? Justify Your Answer Giving a Suitable Reason.
- Define Homologous Series of Organic Compounds. List Its Two Characteristics. Write the Name and Formula of the First Member of the Series of Alkenes.
- Why homologous series of carbon compounds are so called? Write chemical formula of two consecutive members of a homologous series and state the part of these compounds that determines their
- Study the Different Conclusions Drawn by Students of a Class on the Basis of Observations of Preserved/Available Specimens of Plants and Animals.
- Write the molecular formula of first two members of homologous series having functional group −Br.
- Write the next homologue of the following: C2H4
- Write the molecular formula of the 2nd and 3rd member of the homologous series where the first member is ethyne.
- Write the molecular formula of first two members of homologous series having functional group – OH
- Give the Structural Formula of Ethanol.
- A carbon compound 'P' on heating with excess conc. H2SO4 forms another carbon compound 'Q' which on addition of hydrogen in the presence of nickel catalyst forms a saturated carbon compound 'R'.
- Name the compound formed when ethanol is heated in excess of conc. sulphuric acid at 443 K. Also, write the chemical equation of the reaction stating the role of conc.
- Write the Name and Structural Formula of the Compound Obtained When Ethanol is Heated at 443 K with Excess of Conc. H2SO4.
- Write the molecular formula of the 2nd and the 3rd member of the homologous series whose first member is methane.
- Write the Name and Molecular Formula of an Organic Compound Having Its Name Suffixed with 'Ol' and Having Two Carbon Atoms in Its Molecule. Write Balanced Chemical Equation to Indicate What
- An organic compound 'P' is a constituent of wine. 'P' on reacting with acidified K2Cr2O7 forms another compound 'Q'. When a piece of sodium is added to 'Q' a gas 'R' evolves which burns with a
- What is meant by a functional group in carbon compounds?
- Name the Oxidising Agent Used for the Conversion of Ethanol to Ethanoic Acid. Distinguish Between Ethanol and Ethanoic Acid on the Basis of (I) Litmus Test, (Ii) Reaction with Sodium Carbonate
- List in Tabular Form Three Physical and Two Chemical Properties on the Basis of Which Ethanol and Ethanoic Acid Can Be Differentiated.
- In a Tabular Form, Differentiate Between Ethanol and Ethanoic Acid Under the Following Heads:
- Write a Chemical Reaction to Show the Dehydration of Ethanol.
- With a Labelled Diagram Describe an Activity to Show the Formation of an Ester.
- Answer the Following Question. Write the Chemical Formula and Name of the Compound Which is the Active Ingredient of All Alcoholic Drinks. List Its Two Uses. Write the Chemical Equation and Name of
- Answer the Following Question. Why is the Conversion of Ethanol to Ethanoic Acid Considered an Oxidation Reaction? Write the Oxidizing Agent Used in the Reaction Involved.
- Draw the Structures for Ethanol
- 3 mL of ethanol is taken in a test tube and warmed gently in a water bath. A 5% solution of alkaline potassium permanganate is added to the first drop by drop to this solution, then in excess.
- Write the chemical equation for the following: Oxidation of ethanol
- Name the compound formed when ethanol is heated at 443 K in the presence of conc. HA2SOA4 and draw its electron dot structure. State the role of conc. HA2SOA4 in the reaction.
- What happens when ethanol is heated at 443K in the presence of conc. H2SO4? Write the role of conc. H2SO4 in this case.
- Draw electron dot structure of Ethanol.
- Which One of the Following Are the Correct Observations About Acetic Acid? (A) It Turns Blue Litmus Red and Smells like Vinegar (B) It Turns Blue Litmus Red and Smells like Burning Sulphur
- Write the chemical equation for the following: Saponification Reaction
- For Preparing Soap in the Laboratory We Require an Oil and a Base. Which of the Following Combinations of an Oil and a Base Would Be Best Suited for the Preparation of Soap?
- Acetic Acid Smells Like: (1) a Banana (2) Vinegar (3) an Orange (4) a Lemon
- Acetic Acid Solution Turns: (1) Blue Litmus Red (2) Red Litmus Blue (3) Blue Litmus Colourless (4) Red Litmus Colourless
- On Adding Nahco3 to Acetic Acid, a Gas is Evolved Which Turns Lime Water Milky Due to the Formation Of: (1) Calcium Bicarbonate (2) Calcium Hydroxide (3) Calcium Carbonate (4) Calcium Acetate
- A Student Puts a Drop of Acetic Acid First on a Blue Litmus Paper and Then on a Red Litmus Paper.
- A Student Puts a Drop of Reaction Mixture of a Saponification Reaction First a Blue Litmus Paper and Then on a Red Litmus Paper. He May Observe that
- A student is studying the properties of acetic acid in his school laboratory. List two physical and two chemical properties which he must observe and note in his record book.
- If you take a pinch of sodium hydrogen carbonate powder in a test-tube and add drop-by-drop acetic acid to it, what would you observe immediately? List any two main observations.
- (A) If You Are Asked to Report Your Observations About the Following Two Properties of Acetic Acid, What Would You Report? (I) Odour (Ii) Effect on Litmus
- What happens when ethanoic acid reacts with sodium hydroxide? Write equation of the reaction involved.
- Why is the conversion of ethanol into ethanoic acid an oxidation reaction?
- Draw the structure of butanoic acid.
- When you add a few drops of acetic acid to a test-tube containing sodium bicarbonate powder, which one of the following is your observation?
- Write the chemical equation for the following: Combustion of methane
- Write Three Different Chemical Reactions Showing the Conversion of Ethanoic Acid to Sodium Ethanoate. Write Balanced Chemical Equation in Each Case. Write the Name of the Reactants and the Products Other Ethanoic Acid and Sodium Ethanoate in Each Case.
- Complete the following chemical equations: CH3COOH+NaHCO3→
- Choose the Correct Option from Given Below: When Sodium Hydrogen Carbonate is Added to Ethanoic Acid a Gas Evolves. Consider the Following Statements About the Gas Evolved?
- Assertion (A): Esterification is a process in which a sweet-smelling substance is produced. Reason (R): When esters react with sodium hydroxide an alcohol and sodium salt of carboxylic acid
- While Studying Saponification Reaction, a Student Measures the Temperature of the Reaction Mixture and Also Finds Its Nature Using Blue/Red Litmus Paper. on the Basis of His Observations the Correct Conclusion Would Be
- A spatula full of sodium carbonate is taken in a test tube and 2 mL of dilute ethanoic acid is added to it. Write a chemical equation for the reaction.
- In an Experiment to Study the Properties of Ethanoic Acid, a Student Takes About 3 Ml of Ethanoic Acid in a Dry Test Tube. He Adds an Equal Amount of Distilled Water to It and Shakes the Test Tube
- Complete the following chemical equations : C2H5OH
- Distinguish Between Esterification and Saponification Reactions with the Help of Chemical Equations for Each.
- With a labelled diagram describe in brief an activity to show the formation of ester.
- Complete the following chemical equations: C2H5OH+O2→
- Complete the following chemical equations : C2H5OH + Na →
- Complete the following chemical equations :CH3COOH + Na2CO3 →
- A gas is liberated immediately with a brisk effervescence, when you add acetic acid to sodium hydrogen carbonate powder in a test tube. Name the gas and describe the test that confirms the identity of the gas.
- You have four test tubes, A, B, C and D containing sodium carbonate, sodium chloride, lime water and blue litmus solutions respectively. Out of these the material of which test tube/ test tubes would be suitable for the correct test of acetic/ethanoic acid
- Complete the following chemical equations: C2H5OH+CH3COOH
- Complete the following chemical equations :CH3COOH+NaOH→
- Complete the following chemical equations:CH3COOC2H5+NaOH→
- A spatula full of sodium carbonate is taken in a test tube and 2 mL of dilute ethanoic acid is added to it. Suggest a method of testing the gas liberated in the reaction.
- List Two Uses of Esters.
- How Esters Are Prepared ?
- What Are Esters ?
- A student takes about 6 ml of distilled water in each of the four test tubes P, Q, R and S. He then dissolves an equal amount of four different salts namely, sodium chloride in 'P', potassium chloride in 'Q', calcium chloride in 'R' and magnesium chloride in 'S'.
- While Studying Saponification Reaction for the Preparation of Soap, a Teacher Suggested to a Student to Add a Small Quantity of Common Salt to the Reaction Mixture. the Function of Common Salt in this Reaction is to
- n order to study saponification reaction, we first prepare 20% solution of sodium hydroxide. If we record the temperature of this solution just after adding sodium hydroxide flakes to water and also test its nature using litmus, it may be concluded that the process of making this solution is
- A student adds a few drops of ethanoic acid to test tubes X, Y and Z containing aqueous solutions of sodium chloride, sodium hydroxide and sodium carbonate, respectively.
- When You Add About 2 Ml of Acetic Acid to a Test Tube Containing an Equal Amount of Distilled Water and Leave the Test Tube to Settle After Shaking Its Contents, What Will You Observe in the Test Tube After About 5 Minutes?
- A student adds 2 mL of acetic acid to a test tube containing 2 mL of distilled water. He then shakes the test tube well and leaves it to settle for some time. After about 5 minutes he observes that in the test tube there is
- Name the oxidising agent used in the conversion of ethanol to ethanoic acid.
- What Do You Observe When You Drop a Few Drops of Acetic Acid to Test Tubes Containing
- Consider the Following Comments About Saponification Reactions
- What happens when a small piece of sodium is dropped in ethanol? Write the equation for this reactions.
- Why is glacial acetic acid called so?
- Write the chemical equation for the ethanol to ethanoic acid of an oxidation reaction.
- Write an equation showing saponification.
- When ethanol reacts with ethanoic acid in the presence of conc. H2SO4, a substance with fruity smell is produced. Answer the following
- A Student Adds a Spoon Full of Powdered Sodium Hydrogen Carbonate to a Flask Containing Ethanoic Acid. List Two Main Observations, He Must Note in His Note Book, About the Reaction that Takes Place. Also Write Chemical Equation Foe the Reaction.
- In an Experiment to Study the Properties of Acetic Acid a Student Takes About 2 Ml of Acetic Acid in a Dry Test Tube. He Adds About 2 Ml of Water to It and Shakes the Test Tube Well.
- A Student Takes 2 Ml Acetic Acid in a Dry Test Tube and Adds a Pinch of Sodium Hydrogen Carbonate to It. He Makes the Following Observations:
- How is ethanol to ethanoic acid an oxidation reaction different from the reaction in which ethanol burns in the presence of oxygen?
- Name the Functional Group Present in the Following Compounds:Hcooh
- Name the Functional Group Present in the Following Compound:C2h5cho
- A Student is Studying the Properties of Acetic Acid. List Two Physical Properties of Acetic Acid He Observes. What Happens When He Adds a Pinch of Sodium Hydrogen Carbonate to this Acid?
- While Studying Saponification Reactions, the Following Comments Were Noted Down by the Students
- Write the chemical equation for the following: Esterification Reaction
- Which of the Following Observations is True About Dilute Solution of Acetic Acid?
- A Student Takes Na2co3 Powder in a Test Tube and Pours Some Drops of Acetic Acid Over It. He Observes:
- A Student Adds 4 Ml of Acetic Acid to a Test Tube Containing 4 Ml of Distilled Water. He Then Shakes the Test Tube and Leaves It to Settle. After About 10 Minutes He Observes:
- On Adding 2 Ml Acetic Acid to 2 Ml of Water in a Test Tube, It Was Observed that (A) a Clear and Transparent Solution is Formed (B) a White Precipitate is Formed Almost Immediately
- On Adding Acetic Acid to Sodium Hydrogen Carbonate in a Test Tube, a Student Observes (A) No Reaction (B) a Colourless Gas with Pungent Smell
Concepts [15]
- Importance of Carbon
- The Covalent Bond
- Allotropes of Carbon > Diamond
- Allotropes of Carbon > Graphite
- Allotropes of Carbon > Fullerene
- Carbon: A Versatile Element
- Organic Compounds
- Classification of Hydrocarbons
- Carbon Compounds: Chains, Branches, Rings
- Homologous Series
- Nomenclature
- Chemical Properties of Carbon Compounds > Combustion
- Ethanol
- Ethanoic Acid
- Soaps and Detergents
