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Question
Consider the carbon compounds having following molecular formula:
(i) C3H6 (ii) C3H8 (iii) C4H6 (iv) C6H6 (v) C6H12
- State the number of double covalent bonds present in C3H6.
- Write the formula of first member of the homologous series to which the carbon compound C4H6 belongs.
- Which one of the above compounds forms a ring structure of carbon atoms?
- Identify, which of the above compounds, is a member of alkane series.
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Solution
(a) Only 1 double covalent bond is present, other is a triple covalent bond.
(b) C4H6 is an alkyne, The alkynes are a group of chemical compounds with carbon and hydrogen at least one triple bond. With a general molecular formula of Cn H2n-2, where n is any integer higher than 1, the group of compounds is a homologous series.
The first member of this homologous series is ethyne (C2H2). \[\ce{H-C=C-H}\]
(c) C6H6 (Benzene) will form the ring. The structure features triple-altemate double bonds and a six-carbon ring, which is symbolised by a hexagon.
(d) C3H8 is an alkane as it has each carbon bonded to four other atoms through single covalent bonds and follow general formula Cn H2n+2.
RELATED QUESTIONS
The following vegetables are kept in a basket :
Potato, Tomato, Radish, Brinjal, Carrot, Bottle-gourd
Which two of these vegetables correctly represent the homologous structures?
(A) Carrot and Tomato
(B) Potato and Brinjal
(C) Radish and Carrot
(D) Radish and Bottle-gourd
The molecular formula of an organic compound is C18H36. Name its homologous series.
The molecular formula of the third member of the homologous series of ketones is:
(a) C4H8O
(b) C3H6O
(c) C5H10O
(d) C6H12O
Give the structure of the second member of the alcohol group.
What is the difference in the molecular formula of any two adjacent homologues in terms of molecular mass?
Write a short note.
Homologous series
Complete the following table for homologous series of alcohols.
| Name | Molecular formula | Condensed structural formula | Number of carbon atom | Number of -CH2- units | Boiling point °C |
| Methanol | CH4O | CH3-OH | 1 | 1 | 63 |
| Ethanol | C2H6O | CH3–CH2-OH | 2 | 2 | 78 |
| Propanol | C3H8O | CH3–CH2–CH2-OH | ______ | ______ | 97 |
| Butanol | C4H10O | CH3–CH2–CH2–CH2–OH | ______ | ______ | 118 |
The first member of alkyne homologous series is
Define Homologous series.
Name the third homologue of aldehydes.
