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प्रश्न
Answer the following
Identify A and B in the following reactions.
\[\ce{C6H5CH2Br->[alco.][KCN]A ->[Na/ethanol]B.}\]
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उत्तर
\[\ce{\underset{\text{Benzyl bromide}}{C6H5 - CH2 - Br} ->[alcoholic KCN]\underset{\text{Phenylacetonitrile} (A)}{C6H5 - CH2 - C ≡ N} ->[Na/ethanol]\underset{\text{2-Phenylethylamine} (B)}{C6H5 - CH2 - CH2 - NH2}}\]
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संबंधित प्रश्न
Illustrate the following reaction giving suitable example in each case:Gabriel phthalimide synthesis
How do you convert the following: C6H5CONH2 to C6H5NH2
Give the structure of A, B and C in the following reaction:
\[\ce{CH3CH2I ->[NaCN] A ->[OH-][Partial hydrolysis] B ->[NaOH + Br2] C}\]
Give the structure of A, B and C in the following reaction:
\[\ce{C6H5N2Cl ->[CuCN] A ->[H2O/H+] B ->[NH3][\Delta] C}\]
Give the structure of A, B and C in the following reaction:
\[\ce{CH3CH2Br ->[KCN] A ->[LiAlH4] B ->[HNO2][0^\circ C] C}\]
Give the structure of A, B and C in the following reaction:
\[\ce{C6H5NO2 ->[Fe/HCl] A ->[NaNO2 + HCl][273 K] B ->[H2O/H+][\Delta] C}\]
Give the structures of A, B and C in the following reaction:
\[\ce{CH3COOH ->[NH3][\Delta] A ->[NaOBr] B ->[NaNO2/HCl] C}\]
Give the structures of A, B and C in the following reaction:
\[\ce{C6H5NO2 ->[Fe/HCl] A ->[HNO2][273 K] B ->[C6H5OH] C}\]
Write the reaction of aliphatic primary amine with nitrous acid.
Mention 'two' uses of propan-2-one.
Identify 'A' and 'B' in the following reaction and rewrite the complete reaction :
Give the structures of A, B and C in the following reactions :
Give the structures of A, B and C in the following reactions :
Account for the following:
Gabriel phthalimide synthesis is not preferred for preparing aromatic primary amines.
Answer in one sentence.
Which amide does produce ethanamine by Hofmann bromamide degradation reaction?
Answer in one sentence.
Predict the product of the following reaction.
\[\ce{Nitrobenzene ->[Sn/conc.HCl]?}\]
Answer the following
Explain Gabriel phthalimide synthesis.
Write reactions to prepare ethanamine from Acetonitrile.
Write the order of reactivity of alkyl halides with ammonia.
Write reactions to bring about the following conversions.
Acetamide to methylamine
Explain Hoffmann’s exhaustive alkylation with suitable reactions.
Why cannot aniline be prepared by Gabriel phthalimide synthesis?
Identify compound 'B' in following series of reactions?
\[\ce{Acetonitrile ->[Na/alcohol] A ->[NaNO2/dil.HCI] B}\]
Alkyl cyanides on reduction by sodium and ethanol give primary amines. This reaction is called as ____________.
The end product C of the following reaction is
\[\ce{C2H5NH2 ->[HNO2] A ->[PCl5] B ->[NH3][Alcohol] C}\]
Identify the major product (B).
____________ can be prepared exclusively by Gabriel phthalimide synthesis.
Which of the following reactions is appropriate for converting benzamide to aniline?
Which of the following amines forms a clear solution when treated with benzene sulphonyl chloride and excess of potassium hydroxide?
Which of the following reagents is used in Mendius reduction reaction of alkyl cyanide?
Which of the following amines cannot be prepared by Gabriel phthalimide synthesis?
The source of nitrogen in Gabriel synthesis of amines is ______.
The best reagent for converting 2–phenylpropanamide into 2-phenylpropanamine is ______.
The best reagent for converting, 2-phenylpropanamide into 1- phenylethanamine is ______.
Reduction of aromatic nitro compounds using \[\ce{Fe}\] and \[\ce{HCl}\] gives ______.
What is the product when \[\ce{C6H5CH2NH2}\] reacts with \[\ce{HNO2}\]?
Write following conversions:
nitrobenzene `->` acetanilide
How will you carry out the following conversion?
Match the reactions given in Column I with the statements given in Column II.
| Column I | Column II | ||
| (i) | Ammonolysis | (a) | Amine with lesser number of carbon atoms |
| (ii) | Gabriel phthalimide synthesis | (b) | Detection test for primary amines. |
| (iii) | Hoffmann Bromamide reaction | (c) | Reaction of phthalimide with \[\ce{KOH}\] and \[\ce{R-X}\] |
| (iv) | Carbylamine reaction | (d) | Reaction of alkylhalides with \[\ce{NH3}\] |
Describe Gabriel's phthalimide synthesis. (Give reaction)
A primary amine is formed by an amide on treatment with bromine and alkali. The primary amine has
A compound 'A' on reduction with iron scrap and hydrochloric acid gives compound 'B' with molecular formula C6H7N. Compound 'B' on reaction with CHCl3 and alcoholic KOH produces an obnoxious smell of carbylamine due to the formation of 'C'. Identify 'A', 'B' and 'C' and write the chemical reactions involved.
Give reasons for the following:
Ammonolysis of alkyl halides is not a good method to prepare pure primary amines.
Which of the following compound gives pink colour on reaction with phthalic anhydride in cone. H2SO4 followed by treatment with NaOH?
Methyl amine on reaction with chloroform in the presence of NaOH gives ______.
Which of the following amines can be prepared by Gabriel phthalimide reaction?
Which of the following statement(s) is/are incorrect in case of Hofmann bromamide degradation?
Identify the product ‘C’ in the following reaction.
\[\ce{Aniline ->[(CH3CH)2O][Pyridine] A ->[Br2][CH3COOH] B ->[H^+ or OH^-] C}\]
Amides can be converted into amines by the reaction named ______.
Identify A and B in the following reaction.
\[\ce{C6H5CH2Br ->[Alco.][KCN] A ->[Na/Ethanol][reduction] B}\]
Write a short note on the following:
Ammonolysis
Write a short note on Ammonolysis.
Write a short note on the following:
Ammonolysis.
Write a short note on the following:
Ammonolysis
