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Answer the following Identify A and B in the following reactions. CX6HX5CHX2Br→KCNalco⋅A→Na/ethanolB⋅

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प्रश्न

Answer the following

Identify A and B in the following reactions.

\[\ce{C6H5CH2Br->[alco.][KCN]A ->[Na/ethanol]B.}\]

एक पंक्ति में उत्तर
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उत्तर

\[\ce{\underset{\text{Benzyl bromide}}{C6H5 - CH2 - Br} ->[alcoholic KCN]\underset{\text{Phenylacetonitrile} (A)}{C6H5 - CH2 - C ≡ N} ->[Na/ethanol]\underset{\text{2-Phenylethylamine} (B)}{C6H5 - CH2 - CH2 - NH2}}\]

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अध्याय 13: Amines - Exercises [पृष्ठ २९७]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
अध्याय 13 Amines
Exercises | Q 3.01 | पृष्ठ २९७

संबंधित प्रश्न

Write a short note on Hoffmann bromamide degradation.


An aromatic compound 'A' of molecular formula C7H7ON undergoes a series of reactions as shown below. Write the structures of A, B, C, D and E in the following reactions :


How do you convert the following: Ethanenitrile to ethanamine


Give the structures of A, B and C in the following reactions :


Accomplish the following conversion:

Benzamide to toluene


Give the structure of A, B and C in the following reaction:

\[\ce{CH3CH2Br ->[KCN] A ->[LiAlH4] B ->[HNO2][0^\circ C] C}\]


Explain the mechanism of action of hydroiodic acid on 3-methylbutan-2-ol.


Identify 'A' and 'B' in the following reaction and rewrite the complete reaction :


Arrange the following in the increasing order of their pKvalues:

C6H5NH2, C2H5NH2, C6H5NHCH3


Write reactions for the preparation of ethanamine using Gabriel phthalimide synthesis.


Explain the following reaction with a suitable example.

Hofmann elimination reaction


Identify compound 'B' in following series of reactions?

\[\ce{Acetonitrile ->[Na/alcohol] A ->[NaNO2/dil.HCI] B}\]


Acetamide on reduction using Na/C2H5OH gives ____________.


Identify the product 'A' in the following reaction.

\[\ce{Aniline ->[(CH3CO)2O][Pyridine] A}\]


Identify the product obtained, when benzamide is treated with bromine and aqueous sodium hydroxide.


Identify the product obtained when benzyl chloride undergoes ammonolysis in presence of excess ammonia followed by the reaction with two moles of methyl iodide.


Which of the following amines exhibits maximum degree of intermolecular hydrogen bonding?


____________ can be prepared exclusively by Gabriel phthalimide synthesis.


\[\ce{CH3-CN ->[Na/C2H5OH]}\]

The product formed is ____________.


Which of the following reactions is appropriate for converting benzamide to aniline?


Which of the following amines forms a clear solution when treated with benzene sulphonyl chloride and excess of potassium hydroxide?


Identify the product obtained when benzamide is treated with bromine and aqueous sodium hydroxide?


Identify the INCORRECT statement regarding Hofmann bromamide reaction.


Which of the following compounds is obtained when quaternary ammonium hydroxide is strongly heated?


Which of the following does NOT give carbylamine test?


For producing amines, the reaction of nitro compounds with iron scrap is preferred because:


Quaternary ammonium salt is formed:


Given below are two statements labelled as Assertion (A) and Reason (R).

Assertion (A): Alkyl halides are insoluble in water.

Reason (R): Alkyl halides have halogen attached to sp3 hybrid carbon.

Select the most appropriate answer from the options given below:


Which of the following methods of preparation of amines will give same number of carbon atoms in the chain of amines as in the reactant?


The reagents that can be used to convert benzenediazonium chloride to benzene are:

(i) \[\ce{SnCl2/HCl}\]

(ii) \[\ce{CH3CH2OH}\]

(iii) \[\ce{H3PO2}\]

(iv) \[\ce{LiAlH4}\]


Which of the following amines can be prepared by Gabriel synthesis.

(i) Isobutyl amine

(ii) 2-Phenylethylamine

(iii) N-methylbenzylamine

(iv) Aniline


What is the product when \[\ce{C6H5CH2NH2}\] reacts with \[\ce{HNO2}\]?


How will you carry out the following conversion?


How will you carry out the following conversions?


How will you carry out the following conversions?


Match the reactions given in Column I with the statements given in Column II.

  Column I   Column II
(i) Ammonolysis (a) Amine with lesser number of carbon atoms
(ii) Gabriel phthalimide synthesis (b) Detection test for primary amines.
(iii) Hoffmann Bromamide reaction (c) Reaction of phthalimide with \[\ce{KOH}\] and \[\ce{R-X}\]
(iv) Carbylamine reaction (d) Reaction of alkylhalides with \[\ce{NH3}\]

Assertion: Only a small amount of \[\ce{HCl}\] is required in the reduction of nitro compounds with iron scrap and \[\ce{HCl}\] in the presence of steam.

Reason: \[\ce{FeCl2}\] formed gets hydrolysed to release \[\ce{HCl}\] during the reaction.


Assertion: Aromatic 1° amines can be prepared by Gabriel Phthalimide Synthesis.

Reason: Aryl halides undergo nucleophilic substitution with anion formed by phthalimide.


Describe Gabriel's phthalimide synthesis. (Give reaction)


The Gabriels' phthalimide synthesis is used in the synthesis of


Ethylamine can be prepared by the action of bromine and caustic potash on which compound?


Reduction of nitro alkanes yields which compound?


Which of the following compound is expected to be most basic?


When primary amines are treated with HCl, the product obtained is which of the following?


Which of the following compound gives pink colour on reaction with phthalic anhydride in cone. H2SO4 followed by treatment with NaOH?


  1. Phenyl methenamine
  2. N, N - Dimethylaniline
  3. N - Methyl aniline
  4. Benzenamine

Choose the correct order of the basic nature of the above amines.


Which of the following statement(s) is/are incorrect in case of Hofmann bromamide degradation?


Identify the product ‘C’ in the following reaction.

\[\ce{Aniline ->[(CH3CH)2O][Pyridine] A ->[Br2][CH3COOH] B ->[H^+ or OH^-] C}\]


Write short note on the following:

Ammonolysis


Identify A and B in the following reaction.

\[\ce{C6H5CH2Br ->[Alco.][KCN] A ->[Na/Ethanol][reduction] B}\]


Write a short note on Ammonolysis.


Write short note on the following:

Ammonolysis


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