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प्रश्न
Give the structure of A, B and C in the following reaction:
\[\ce{C6H5NO2 ->[Fe/HCl] A ->[NaNO2 + HCl][273 K] B ->[H2O/H+][\Delta] C}\]
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उत्तर
\[\ce{\underset{Nitrobenzene}{C6H5NO2} ->[Fe/HCl] \underset{(A)}{\underset{Aniline}{C6H5NH2}} ->[NaNO2 + HCl][273 K] \underset{(B)}{\underset{chloride}{\underset{Benzenediazonium}{C6H5\overset{+}{N}≡NCl-}}} ->[H2O/H+][\Delta] \underset{(C)}{\underset{Phenol}{C6H5OH}}}\]
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संबंधित प्रश्न
Identify the compounds 'A' and 'B' in the following equation:

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\[\ce{C6H5CH2Br->[alco.][KCN]A ->[Na/ethanol]B.}\]
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Reason (R): Alkyl halides have halogen attached to sp3 hybrid carbon.
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(ii) Acetic anyhdride/pyridine followed by conc.\[\ce{H2SO4}\] + conc.\[\ce{HNO3}\].
(iii) Dil. HCl followed by reaction with conc.\[\ce{H2SO4}\] + conc.\[\ce{HNO3}\].
(iv) Reaction with conc.\[\ce{HNO3}\] + conc.\[\ce{H2 SO4}\].
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| Column I | Column II | ||
| (i) | Ammonolysis | (a) | Amine with lesser number of carbon atoms |
| (ii) | Gabriel phthalimide synthesis | (b) | Detection test for primary amines. |
| (iii) | Hoffmann Bromamide reaction | (c) | Reaction of phthalimide with \[\ce{KOH}\] and \[\ce{R-X}\] |
| (iv) | Carbylamine reaction | (d) | Reaction of alkylhalides with \[\ce{NH3}\] |
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Write a short note on the following:
Ammonolysis
