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प्रश्न
Name the process of breaking C-X bond by ammonia in preparation of amines.
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उत्तर
The process of breaking C-X bond by ammonia in preparation of amines is known as ammonolysis.
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संबंधित प्रश्न
How is ethyl amine prepared from methyl iodide?
How are propan-1-amine and propan-2-amine prepared from oxime?
Write a short note on Hoffmann bromamide degradation.
How do you convert the following: C6H5CONH2 to C6H5NH2
Write a short note on the following:
Hoffmann’s bromamide reaction
Accomplish the following conversion:
Nitrobenzene to benzoic acid
Accomplish the following conversion:
Benzyl chloride to 2-phenylethanamine
Accomplish the following conversion:
Benzamide to toluene
Give the structures of A, B and C in the following reaction:
\[\ce{CH3COOH ->[NH3][\Delta] A ->[NaOBr] B ->[NaNO2/HCl] C}\]
Write the reaction of aromatic primary amine with nitrous acid.
Explain the mechanism of action of hydroiodic acid on 3-methylbutan-2-ol.
Mention 'two' uses of propan-2-one.
Give the structures of A, B and C in the following reactions :
Give the structures of A, B and C in the following reactions :
Account for the following:
Gabriel phthalimide synthesis is not preferred for preparing aromatic primary amines.
Answer in one sentence.
Predict the product of the following reaction.
\[\ce{Nitrobenzene ->[Sn/conc.HCl]?}\]
Answer the following
Explain Gabriel phthalimide synthesis.
Identify compound 'B' in following series of reactions?
\[\ce{Acetonitrile ->[Na/alcohol] A ->[NaNO2/dil.HCI] B}\]
The end product C of the following reaction is
\[\ce{C2H5NH2 ->[HNO2] A ->[PCl5] B ->[NH3][Alcohol] C}\]
Identify the product obtained, when benzamide is treated with bromine and aqueous sodium hydroxide.
Which of the following amines exhibits maximum degree of intermolecular hydrogen bonding?
Identify the major product (B).
____________ can be prepared exclusively by Gabriel phthalimide synthesis.
The reduction of alkyl cyanide with sodium and ethanol to give primary amines is, ____________.
Identify 'A' and 'B' in the following conversions.
\[\ce{CH3 - I ->[Alc. KCN][\Delta] A ->[Na/C2H5OH] B}\]
Which of the following compounds is obtained when quaternary ammonium hydroxide is strongly heated?
Which of the following does NOT give carbylamine test?
Amongst the following, the strongest base in aqueous medium is ______.
The source of nitrogen in Gabriel synthesis of amines is ______.
Best method for preparing primary amines from alkyl halides without changing the number of carbon atoms in the chain is ______.
Which of the following methods of preparation of amines will give same number of carbon atoms in the chain of amines as in the reactant?
What is the product when \[\ce{C6H5CH2NH2}\] reacts with \[\ce{HNO2}\]?
Suggest a route by which the following conversion can be accomplished.
How will you bring out the following conversion?
Which of the following reactions will not give a primary amine?
Ethylamine can be prepared by the action of bromine and caustic potash on which compound?
In the given reaction what is the X?
\[\begin{array}{cc}
\ce{O}\phantom{.......................}\\
||\phantom{.......................}\\
\phantom{}\ce{R - C - OH <-[H3O] Χ ->[H] RCH2NH2}
\end{array}\]
When primary amines are treated with HCl, the product obtained is which of the following?
Which of the following CANNOT be prepared by ammonolysis of alkyl halide?
Give reasons for the following:
Ammonolysis of alkyl halides is not a good method to prepare pure primary amines.
The amine 'A' when treated with nitrous acid gives yellow oily substance. The amine A is ______.
Which of the following statement(s) is/are incorrect in case of Hofmann bromamide degradation?
Amides can be converted into amines by the reaction named ______.
Write short note on the following:
Ammonolysis
Identify A and B in the following reaction.
\[\ce{C6H5CH2Br ->[Alco.][KCN] A ->[Na/Ethanol][reduction] B}\]
Write the name of reduction product formed when ethyl cyanide is treated with sodium and alcohol.
Write short note on the following.
Ammonolysis.
Write a short note on Ammonolysis.
Assertion: Amimonolysis of alkyl halides involves the reaction between alkyl halides and alcoholic ammonia.
Reason: Ammonolysis of alkyl halides produces secondary amines only.
Write a short note on the following:
Ammonolysis.
