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प्रश्न
Name the process of breaking C-X bond by ammonia in preparation of amines.
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उत्तर
The process of breaking C-X bond by ammonia in preparation of amines is known as ammonolysis.
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संबंधित प्रश्न
How is ethyl amine prepared from methyl iodide?
Write a short note on Hoffmann bromamide degradation.
Illustrate the following reaction giving suitable example in each case:Gabriel phthalimide synthesis
Give the structures of A, B and C in the following reactions :
Accomplish the following conversion:
Benzyl chloride to 2-phenylethanamine
Give the structure of A, B and C in the following reaction:
\[\ce{C6H5NO2 ->[Fe/HCl] A ->[NaNO2 + HCl][273 K] B ->[H2O/H+][\Delta] C}\]
Explain the mechanism of action of hydroiodic acid on 3-methylbutan-2-ol.
Arrange the following in the increasing order of their pKb values:
C6H5NH2, C2H5NH2, C6H5NHCH3
Give the structures of A, B and C in the following reactions :
Account for the following:
Gabriel phthalimide synthesis is not preferred for preparing aromatic primary amines.
Write structures of compounds A and B in each of the following reactions:
Answer in one sentence.
Predict the product of the following reaction.
\[\ce{Nitrobenzene ->[Sn/conc.HCl]?}\]
Answer the following
Identify A and B in the following reactions.
\[\ce{C6H5CH2Br->[alco.][KCN]A ->[Na/ethanol]B.}\]
Answer the following
Write a reaction to convert acetic acid into methylamine.
Answer the following
Explain Gabriel phthalimide synthesis.
Write reactions to prepare ethanamine from Acetonitrile.
Explain Hoffmann’s exhaustive alkylation with suitable reactions.
Why cannot aniline be prepared by Gabriel phthalimide synthesis?
Acetamide on reduction using Na/C2H5OH gives ____________.
Alkyl cyanides on reduction by sodium and ethanol give primary amines. This reaction is called as ____________.
Identify the product obtained, when benzamide is treated with bromine and aqueous sodium hydroxide.
Identify the product obtained when benzyl chloride undergoes ammonolysis in presence of excess ammonia followed by the reaction with two moles of methyl iodide.
Which nitrogen containing compound amongst the following would undergo Mendius reduction to furnish primary amine \[\ce{(R - NH2)}\]?
Which of the following does NOT give carbylamine test?
Nitro compounds are reduced by iron scrap and hydrochloric acid to yield one of the following compounds:
The source of nitrogen in Gabriel synthesis of amines is ______.
Amongst the given set of reactants, the most appropriate for preparing 2° amine is ______.
The best reagent for converting 2–phenylpropanamide into 2-phenylpropanamine is ______.
Hoffmann Bromamide Degradation reaction is shown by ______.
Reduction of aromatic nitro compounds using \[\ce{Fe}\] and \[\ce{HCl}\] gives ______.
Which of the following compounds is the weakest Brönsted base?
Among the following amines, the strongest Brönsted base is:
Which of the following methods of preparation of amines will give same number of carbon atoms in the chain of amines as in the reactant?
What is the product when \[\ce{C6H5CH2NH2}\] reacts with \[\ce{HNO2}\]?
Suggest a route by which the following conversion can be accomplished.
Write following conversions:
acetanilide `->` p-nitroaniline
How will you bring out the following conversion?
How will you carry out the following conversion?
How will you carry out the following conversion?
How will you carry out the following conversions?
The compound X is which of the following?
\[\ce{CH3CN ->[Na + C2H5OH] x}\]
Ethylamine can be prepared by the action of bromine and caustic potash on which compound?
In the given reaction what is the X?
\[\begin{array}{cc}
\ce{O}\phantom{.......................}\\
||\phantom{.......................}\\
\phantom{}\ce{R - C - OH <-[H3O] Χ ->[H] RCH2NH2}
\end{array}\]
Which of the following compound is expected to be most basic?
C6H5CONHCH3 can be converted into C6H5CH2NHCH3 by:-
Give reasons for the following:
Ammonolysis of alkyl halides is not a good method to prepare pure primary amines.
Write a short note on the following:
Ammonolysis
Write a short note on the following:
Ammonolysis
Write the name of reduction product formed when ethyl cyanide is treated with sodium and alcohol.
Write short note on the following:
Ammonolysis
Assertion: Amimonolysis of alkyl halides involves the reaction between alkyl halides and alcoholic ammonia.
Reason: Ammonolysis of alkyl halides produces secondary amines only.
Write a short note on the following:
Ammonolysis
