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प्रश्न
Write reactions to prepare ethanamine from Acetonitrile.
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उत्तर
Acetonitrile on Mendius reduction yields ethanamine.
\[\ce{\underset{\text{Acetonitrile}}{CH3 - C ≡ N} + 4[H] ->[Na/C2H5OH][or LiAlH] \underset{\text{Ethanamine}}{CH3 - CH2 - NH2}}\]
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संबंधित प्रश्न
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Answer in one sentence.
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(i)
(ii)
(iii)
(iv)
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(i) Acetyl chloride/pyridine followed by reaction with conc.\[\ce{H2SO4 }\] + conc. \[\ce{HNO3}\].
(ii) Acetic anyhdride/pyridine followed by conc.\[\ce{H2SO4}\] + conc.\[\ce{HNO3}\].
(iii) Dil. HCl followed by reaction with conc.\[\ce{H2SO4}\] + conc.\[\ce{HNO3}\].
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Identify A and B in the following reaction.
How will you bring out the following conversion?
How will you carry out the following conversion?
Match the reactions given in Column I with the statements given in Column II.
| Column I | Column II | ||
| (i) | Ammonolysis | (a) | Amine with lesser number of carbon atoms |
| (ii) | Gabriel phthalimide synthesis | (b) | Detection test for primary amines. |
| (iii) | Hoffmann Bromamide reaction | (c) | Reaction of phthalimide with \[\ce{KOH}\] and \[\ce{R-X}\] |
| (iv) | Carbylamine reaction | (d) | Reaction of alkylhalides with \[\ce{NH3}\] |
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\[\begin{array}{cc}
\ce{O}\phantom{.......................}\\
||\phantom{.......................}\\
\phantom{}\ce{R - C - OH <-[H3O] Χ ->[H] RCH2NH2}
\end{array}\]
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Write short note on the following:
Ammonolysis
Write short note on the following.
Ammonolysis.
