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प्रश्न
Write reactions to bring about the following conversions.
Acetamide to Ethylamine
Convert, acetamide into ethyl amine.
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उत्तर
\[\ce{CH3CONH2 ->[LiAH4][ether] CH3CH2NH2}\]
\[\ce{CH3CONH2 + 4[H] ->[LiAH4][ether] CH3CH2NH2 + H2O}\]
संबंधित प्रश्न
How is ethyl amine prepared from methyl iodide?
How are propan-1-amine and propan-2-amine prepared from oxime?
Write a short note on Hoffmann bromamide degradation.
Identify the compounds 'A' and 'B' in the following equation:
An aromatic compound 'A' of molecular formula C7H7ON undergoes a series of reactions as shown below. Write the structures of A, B, C, D and E in the following reactions :
How do you convert the following: C6H5CONH2 to C6H5NH2
How do you convert the following: Ethanenitrile to ethanamine
Give the structures of A, B and C in the following reactions :
Write a short note on the following:
Hoffmann’s bromamide reaction
Accomplish the following conversion:
Benzyl chloride to 2-phenylethanamine
Give the structure of A, B and C in the following reaction:
\[\ce{CH3CH2I ->[NaCN] A ->[OH-][Partial hydrolysis] B ->[NaOH + Br2] C}\]
Why cannot aromatic primary amines be prepared by Gabriel phthalimide synthesis?
Arrange the following in the increasing order of their pKb values:
C6H5NH2, C2H5NH2, C6H5NHCH3
The following amines is the product of Gabriel phthalimide synthesis.
Write reactions for the preparation of ethanamine using Gabriel phthalimide synthesis.
Why cannot aniline be prepared by Gabriel phthalimide synthesis?
Explain the following reaction with a suitable example.
Hofmann elimination reaction
Acetamide on reduction using Na/C2H5OH gives ____________.
Identify the product 'A' in the following reaction.
\[\ce{Aniline ->[(CH3CO)2O][Pyridine] A}\]
The end product C of the following reaction is
\[\ce{C2H5NH2 ->[HNO2] A ->[PCl5] B ->[NH3][Alcohol] C}\]
Identify the product obtained, when benzamide is treated with bromine and aqueous sodium hydroxide.
Which of the following amines exhibits maximum degree of intermolecular hydrogen bonding?
What product is formed when \[\ce{R - C ≡ N}\] is hydrolysed?
\[\ce{CH3-CN ->[Na/C2H5OH]}\]
The product formed is ____________.
Which of the following amines forms a clear solution when treated with benzene sulphonyl chloride and excess of potassium hydroxide?
In aqueous phase the order of basic strength of alkylamine is ______.
Identify product B in the following reaction.
\[\ce{Aniline ->[NaNO2][HCl] A ->[KI] B}\]
Which of the following reagents is used in Hofmann's elimination reaction of amines?
Benzylamine may be alkylated as shown in the following equation:
\[\ce{C6H5CH2NH2 + R - X -> C6H5CH2NHR}\]
Which of the following alkylhalides is best suited for this reaction through SN1 mechanism?
Hoffmann Bromamide Degradation reaction is shown by ______.
Which of the following compounds is the weakest Brönsted base?
Among the following amines, the strongest Brönsted base is:
Which of the following amines can be prepared by Gabriel synthesis.
(i) Isobutyl amine
(ii) 2-Phenylethylamine
(iii) N-methylbenzylamine
(iv) Aniline
Which of the following reactions are correct?
(i)
(ii)
(iii)
(iv)
Identify A and B in the following reaction.
Write following conversions:
nitrobenzene `->` acetanilide
How will you carry out the following conversions?
Match the reactions given in Column I with the statements given in Column II.
| Column I | Column II | ||
| (i) | Ammonolysis | (a) | Amine with lesser number of carbon atoms |
| (ii) | Gabriel phthalimide synthesis | (b) | Detection test for primary amines. |
| (iii) | Hoffmann Bromamide reaction | (c) | Reaction of phthalimide with \[\ce{KOH}\] and \[\ce{R-X}\] |
| (iv) | Carbylamine reaction | (d) | Reaction of alkylhalides with \[\ce{NH3}\] |
Assertion: Only a small amount of \[\ce{HCl}\] is required in the reduction of nitro compounds with iron scrap and \[\ce{HCl}\] in the presence of steam.
Reason: \[\ce{FeCl2}\] formed gets hydrolysed to release \[\ce{HCl}\] during the reaction.
Describe Gabriel's phthalimide synthesis. (Give reaction)
Account for the following:
Aniline cannot be prepared by the ammonolysis of chlorobenzene under normal conditions.
Reduction of nitro alkanes yields which compound?
Which of the following compound is expected to be most basic?
Which of the following CANNOT be prepared by ammonolysis of alkyl halide?
A compound 'A' on reduction with iron scrap and hydrochloric acid gives compound 'B' with molecular formula C6H7N. Compound 'B' on reaction with CHCl3 and alcoholic KOH produces an obnoxious smell of carbylamine due to the formation of 'C'. Identify 'A', 'B' and 'C' and write the chemical reactions involved.
Give reasons for the following:
Ammonolysis of alkyl halides is not a good method to prepare pure primary amines.
Which of the following amines can be prepared by Gabriel phthalimide reaction?
Which of the following statement(s) is/are incorrect in case of Hofmann bromamide degradation?
Which of the following would not be a good choice for reducing nitrobenzene to aniline?
Write a short note on the following:
Ammonolysis
Write short note on the following.
Ammonolysis.
Write a short note on Ammonolysis.
Write a short note on the following:
Ammonolysis
