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Chemistry Official Question Paper 2025-2026 HSC Science (General) 12th Standard Board Exam Question Paper Solution

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Chemistry [Official Question Paper ]
Marks: 70 Maharashtra State Board
HSC Science (General)
HSC Science (Electronics)
HSC Science (Computer Science)

Academic Year: 2025-2026
Date & Time: 18th February 2026, 11:00 am
Duration: 3h
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General Instructions:

The question paper is divided into four sections.

  1. Section A: Q. No. 1 contains Ten multiple choice type of questions carrying One mark each. Q. No. 2 contains Eight very short answer type of questions carrying One mark each.
  2. Section B: Q. No. 3 to Q. No. 14 are Twelve short answer type of questions carrying Two marks each, (Attempt any Eight)
  3. Section C: Q. No. 15 to Q. No. 26 are Twelve short answer type of questions carrying Three marks each, (Attempt any Eight)
  4. Section D: Q. No. 27 to Q. No. 31 are Five long answer type of questions carrying Four marks each, (Attempt any Three)
  5. Use of log table is allowed. Use of calculator is not allowed.
  6. Figures to the right indicate full marks.
  7. For multiple choice type questions, only the first attempt will be considered for evaluation.
  8. Physical constants:
    1. Avogadro Number = NA = 6.022 × 1023
    2. Gas constant = R = 0.08206 L . atm. K−1 . mol−1
    3. 1 Faraday = F = 96500 Coulomb

Section A
[10]1. | Select and write the correct answer for the following multiple choice type of questions:
[1]1. (i)

The electrolyte used in H2 - O2 fuel cell is ______.

aqueous KCl

aqueous KOH

aqueous HCl

aqueous KNO3

Concept: undefined - undefined
Chapter:
[1]1. (ii)

The oxidation state of bromine in HOBrO2 oxoacid is ______.

+7

+5

+3

+1

Concept: undefined - undefined
Chapter:
[1]1. (iii)

Acetonitrile may be prepared by heating the following reactants:

Ethyl chloride with alcoholic KCN.

Ethyl chloride with alcoholic AgCN.

Methyl chloride with alcoholic KCN.

Methyl chloride with alcoholic AgCN.

Concept: undefined - undefined
Chapter:
[1]1. (iv)

The carbonated water is an example of ______.

solid in liquid solution.

liquid in liquid solution.

gas in liquid solution.

liquid in gas solution.

Concept: undefined - undefined
Chapter:
[1]1. (v)

The unit of rate constant is per second, the order of reaction is ______.

Zero

First

Second

Third

Concept: undefined - undefined
Chapter:
[1]1. (vi)

A system releases 10 kJ of heat and performs 15 kJ of work on the surrounding. Hence the change in internal energy is ______.

+5 kJ

−5 kJ

+25 kJ

−25 kJ

Concept: undefined - undefined
Chapter:
[1]1. (vii)

The co-ordination complex ions [Co(NH3)5 (NO2)2⊕ and [Co(NH3)5 (ONO)2⊕ are ______ of each other.

ionization isomers

solvate isomers

linkage isomers

co-ordination isomers

Concept: undefined - undefined
Chapter:
[1]1. (viii)

The correct order for basic strength of amines and ammonia is ______.

NH3 > R - NH2 > R2NH > R3N

NH3 > R3N > R2NH > R - NH2

NH3 < R - NH2 > R3N > R2NH

NH3 < R - NH2 < R2NH > R3N

Concept: undefined - undefined
Chapter:
[1]1. (ix)

Amongst the following 3d-series elements, having highest value of first ionization enthalpy is:

Zn

Cu

Co

Sc

Concept: undefined - undefined
Chapter:
[1]1. (x)

The pOH of 0.01 M HCl solution is ______.

1

2

11

12

Concept: undefined - undefined
Chapter:
[8]2. | Answer the following questions:
[1]2. (i)

Write the name of product obtained, when selenium is treated with magnesium metal.

Concept: undefined - undefined
Chapter:
[1]2. (ii)

Write the SI unit of cell constant.

Concept: undefined - undefined
Chapter:
[1]2. (iii)

Name the radioactive element in lanthanoids.

Concept: undefined - undefined
Chapter: [8] Transition and Inner Transition Elements
[1]2. (iv)

Complete the following reaction:

Concept: undefined - undefined
Chapter:
[1]2. (v)

Write the IUPAC name of:

Concept: undefined - undefined
Chapter:
[1]2. (vi)

Cu crystallizes in fcc unit cell with edge length of 495 pm. What is the radius of Cu atom?

Concept: undefined - undefined
Chapter: [1] Solid State
[1]2. (vii)

Write the chemical name of Teflon.

Concept: undefined - undefined
Chapter:
[1]2. (viii)

Write the name of nanoparticle which acts as highly effective bacterial disinfectant.

Concept: undefined - undefined
Chapter:
Section B
[16]B | Attempt any EIGHT of the following questions:
[1]3. (a)

Define isomorphism.

Concept: undefined - undefined
Chapter: [1] Solid State
[1]3. (b)

Define unit cell.

Concept: undefined - undefined
Chapter: [1] Solid State [1] Solid State
[1]4. (i)

Explain the trend in the following property of group 17 elements:

Atomic radii

Concept: undefined - undefined
Chapter:
[1]4. (ii)

Explain the trend in the following property of group 17 elements:

Electronegativity

Concept: undefined - undefined
Chapter:
[1]5. (i)

Explain the following, giving two examples: 

Homoleptic

Concept: undefined - undefined
Chapter: [9] Coordination Compounds
[1]5. (ii)

Explain the following, giving two examples: 

Heteroleptic

Concept: undefined - undefined
Chapter: [9] Coordination Compounds
[1]6. (a)

Write the chemical equation for the reaction of glucose with bromine water.

Concept: undefined - undefined
Chapter:
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[1]6. (b)

Define Enantiomers.

Concept: undefined - undefined
Chapter: [10.01] Haloalkanes [10.02] Haloarenes
[1]7. (i)

Write example of one dimensional nanostructure of size less than 100 nm.

Concept: undefined - undefined
Chapter:
[1]7. (ii)

Write the hydrolysis reaction of ethyl methyl ether.

Concept: undefined - undefined
Chapter:
[2]8.

Calculate the osmotic pressure of solution containing 0.822 gm of sucrose in 300 mL of water at 298 K.

[Given: Molar mass of sucrose 342 g/mol, R = 0.08205 dm3. atm. K−1. mol−1]

Concept: undefined - undefined
Chapter:
[1]9. (a)

Write the mathematical equation of the first law of thermodynamics for an isochoric process.

Concept: undefined - undefined
Chapter: [3] Chemical Thermodynamics and Energetic [4] Chemical Thermodynamics
[1]9. (b)

Write the mathematical equation for the first law of thermodynamics for adiabatic process.

Concept: undefined - undefined
Chapter:
[1]10. (i)

Discuss the main points of similarity between lanthanoids and actinoids.

Concept: undefined - undefined
Chapter:
[1]10. (ii)

Distinguish between lanthanoid and actinoids.

Concept: undefined - undefined
Chapter: [8] Transition and Inner Transition Elements [8.02] F-block Elements
[1]11. (i)

What is the action of the following reagent on chlorobenzene?

Conc. HNO3

Concept: undefined - undefined
Chapter:
[1]11. (ii)

Write the product formed by Chlorobenzene treated with a fuming H2SO4 reaction.

Concept: undefined - undefined
Chapter: [10] Halogen Derivatives
[2]12.

Explain the following reaction:

Cannizzaro reaction

Concept: undefined - undefined
Chapter: [12.01] Aldehydes and Ketones
[2]13.

A chemical reaction occurs in two steps:

\[\ce{NO2Cl_{(g)} ->[slow] NO2_{(g)} + Cl_{(g)}}\]

\[\ce{NO2Cl_{(g)} + Cl_{(g)} ->[fast] NO2_{(g)} + Cl2_{(g)}}\]

  1. Write down the rate law.
  2. Identify the reaction intermediate.
Concept: undefined - undefined
Chapter:
[2]14.

The standard potential of electrode Cu++(0.02 M) | Cu(s) is 0.337 volt. Calculate its potential in volt.

Concept: undefined - undefined
Chapter:
Section C
[24]C | Attempt any EIGHT of the following questions:
[2]15. (i)

Derive the relationship between relative lowering of vapour pressure and molar mass of nonvolatile solute.

Concept: undefined - undefined
Chapter: [2] Solutions and Colligative Properties
[1]15. (ii)

State the two forms of the second law of thermodynamics.

Concept: undefined - undefined
Chapter:
[1.5]16. (i)

Write reactions to bring about the following conversions.

Acetamide to Ethylamine

Concept: undefined - undefined
Chapter: [13] Amines [13.01] Amines
[1.5]16. (ii)

Explain the amphoteric nature of water.

Concept: undefined - undefined
Chapter: [3] Ionic Equilibria
[1]17. (i)

Convert the following:

Ethanol into sodium ethoxide.

Concept: undefined - undefined
Chapter:
[1]17. (ii)

Convert the following:

Phenol into o-phenol sulfonic acid.

Concept: undefined - undefined
Chapter:
[1]17. (iii)

How will you carry out the following conversion?

Bromoethane to methoxyethane

Concept: undefined - undefined
Chapter:
[1]18. (i)

What is peptide linkage?

Concept: undefined - undefined
Chapter: [14.02] Proteins
[2]18. (ii)

Write any two characteristics of interhalogen compounds.

Concept: undefined - undefined
Chapter: [7] Elements of Groups 16, 17 and 18
[1]19. (i)

Write the observed electronic configuration of chromium (Z = 24).

Concept: undefined - undefined
Chapter:
[1]19. (ii)

Calculate magnetic moment of Ti3+ by using spin only formula. (Z of Ti = 22)

Concept: undefined - undefined
Chapter:
[1]19. (iii)

Define Green chemistry.

Concept: undefined - undefined
Chapter: [16] Green Chemistry and Nanochemistry
[1]20. (i)

Write examples of coordination metal complexes in biology.

Concept: undefined - undefined
Chapter:
[2]20. (ii)

Calculate the work done in oxidation of 2 moles of SO2 at 298 K, if \[\ce{SO2_{(g)} + \frac{1}{2}O2_{(g)} -> SO3_{(g)}}\]

[Given: R = 8.314 J/K/mol]

Concept: undefined - undefined
Chapter:
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[1]21. (i)

Write the formula to measure % atom economy according to green chemistry.

Concept: undefined - undefined
Chapter:
[1]21. (ii) (a)

Write reactions for the following conversions.

Benzene to Benzaldehyde

Concept: undefined - undefined
Chapter: [12] Aldehydes, Ketones and Carboxylic Acids [12.01] Aldehydes and Ketones
[1]21. (ii) (b)

Convert the following:

Cyclohexene into adipic acid.

Concept: undefined - undefined
Chapter: [12] Aldehydes, Ketones and Carboxylic Acids
[1.5]22. (i)

Write the reaction for the preparation of Nylon-6.

Concept: undefined - undefined
Chapter: [15] Polymers
[1.5]22. (ii)

The salt of Sc3+ ion is colourless and the salt of Mn3+ ion is coloured. Explain.

[Z of Sc = 21and Z of Mn = 25]

Concept: undefined - undefined
Chapter:
[1.5]23. (i)

Write postulates of Werner theory of co-ordination complexes.

Concept: undefined - undefined
Chapter: [9] Coordination Compounds
[1.5]23. (ii)

What is the action of ethane –1, 2–diol on acetone?

Concept: undefined - undefined
Chapter:
[1]24. (i)

Write Tollen’s reagent test for acetaldehyde.

Concept: undefined - undefined
Chapter:
[1]24. (ii) (a)

Draw the zwitter ion structure for sulphanilic acid.

Concept: undefined - undefined
Chapter:
[1]24. (ii) (b)

What is the action of benzene diazonium chloride on phenol in alkaline medium?

Concept: undefined - undefined
Chapter: [13.03] Diazonium Salts
[1]25. (i)

Define:

Common ion effect.

Concept: undefined - undefined
Chapter:
[2]25. (ii)

How is glucose prepared from starch?

Concept: undefined - undefined
Chapter: [14.01] Carbohydrates
[1]26. (i)

Draw the structure of 2, 4 - dinitrophenylhydrazone of acetaldehyde.

Concept: undefined - undefined
Chapter:
[2]26. (ii)

The rate of A + B → P is 3.6 × 10−2 mol/dm3/s. When [A] = 0.2 M and [B] = 0.1 M. Calculate the rate constant if reaction is first order in B and second order in A.

Concept: undefined - undefined
Chapter:
Section D
[12]D | Attempt any THREE of the following questions:
[1]27. (i) (a)

Define isotonic solutions.

Concept: undefined - undefined
Chapter: [2] Solutions [2] Solutions and Colligative Properties
[1]27. (i) (b)

Define molecularity of reaction.

Concept: undefined - undefined
Chapter: [6] Chemical Kinetics
[2]27. (ii)

State and explain Hess’s law of constant heat summation.

Concept: undefined - undefined
Chapter: [3] Chemical Thermodynamics and Energetic
[1]28. (i) (a)

Define:

Schotty defect

Concept: undefined - undefined
Chapter:
[1]28. (i) (b)

Define the following term:

Ferromagnetism

Concept: undefined - undefined
Chapter: [1] Solid State
[1]28. (ii)

Write the name of catalyst used in preparation of HDP.

Concept: undefined - undefined
Chapter:
[1]28. (iii)

Draw structure of isoprene unit of natural rubber.

Concept: undefined - undefined
Chapter:
[2]29. (i)

Calculate effective atomic number of Fe2⊕ in \[\ce{[Fe(CN)6]^{4\ominus}}\]

[Given: (Z = 26)]

Concept: undefined - undefined
Chapter:
[1]29. (ii)

Draw a neat labelled diagram of a lead accumulator.

Concept: undefined - undefined
Chapter: [5] Electrochemistry
[1]29. (iii)

Write two advantages of hydrogen-oxygen fuel cell.

Concept: undefined - undefined
Chapter:
[2]30. (i)

Convert, ethanoic acid to ethanol.

Concept: undefined - undefined
Chapter:
[2]30. (ii)

Explain the mechanism of alkaline hydrolysis of bromomethane.

Concept: undefined - undefined
Chapter:
[2]31. (i)

Answer the following in brief:

Acetic acid is 5% ionised in its decimolar solution. Calculate the dissociation constant of acid.

Concept: undefined - undefined
Chapter:
[1]31. (ii) (a)

Write chemical formula of epsom salt.

Concept: undefined - undefined
Chapter:
[1]31. (ii) (b)

Give the uses of sulphuric acid.

Concept: undefined - undefined
Chapter:

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