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प्रश्न
Explain the following, giving two examples:
Homoleptic
Explain a homoleptic complex with an example.
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उत्तर
Homoleptic refers to a coordination complex where all the ligands attached to the central metal ion are the same type. For example:
- [Cu(NH3)4]2+: This is a homoleptic complex where all four ligands are ammonia (NH3) molecules, coordinated to the copper (Cu2+) ion.
- [NiCl6]2−: In this homoleptic complex, all six ligands are chloride (Cl−) ions, coordinated to the nickel (Ni2+) ion.
Notes
Students should refer to the answer according to their questions.
संबंधित प्रश्न
Classify the following ligands into monodentate and polydentate —
- Ammonia
- Carbon monoxide
- Ethylene diamine
- Ethylene diamine tetra acetate ion
What is meant by unidentate ligand?
What is the coordination entity formed when excess of aqueous KCN is added to an aqueous solution of copper sulphate? Why is it that no precipitate of copper sulphide is obtained when H2S(g) is passed through this solution?
Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:
[Mn(H2O)6]SO4
Predict the co-ordination No. of cs+ ion if `r_(Cs)^+` = 1.69Å and `r_(Cl)^-` = 1.81Å.
IUPAC name of the following compound is
(a) 3 - Bromo- 3, 4- dimethylheptane
(b) 3, 4- dimethyl - 3- bromoheptane
(c) 5- Bromo- 4, 5- dimethylheptane
(d) 4, 5- dimethyl- 5- bromoheptane
Write IUPAC names of the following compounds:
Write the IUPAC name of the following complex:
[Co(NH3)5(CO3)]Cl
Write the IUPAC name of the following coordination compound:
[Cr(NH3)4(H2O)2]Cl3
The ligand triethylenetetramine is _______.
Write structures of compounds A and B of the following reaction :
Write structures of compounds A and B of the following reaction :
Ligand (en) is an example of ___________.
The oxidation number of Fe in K4[Fe(CN)6] is ____________.
Which of the following is non-ionizable?
In which of the following compounds, the Central metal atom/ion is in the lowest oxidation state?
When 0.1 mol \[\ce{CoCl3 (NH3)5}\] is treated with excess of \[\ce{AgNO3}\], 0.2 mol of \[\ce{AgCl}\] are obtained. The conductivity of solution will correspond to ______.
A coordination compound \[\ce{CrCl3.4H2O}\] precipitates silver chloride when treated with silver nitrate. The molar conductance of its solution corresponds to a total of two ions. Write structural formula of the compound and name it.
In which of the following compounds, the oxidation number of iodine is fractional?
Which of the following is an ionic ligand?
The co-ordinate number and the oxidation state of the element E in the complex [E(en)2(C2O4)]NO2 are respectively?
The complex which has no d electrons in the central atom is:-
The most stable ion is ______.
Which of the following ligands can exhibit linkage isomerism?
Metal attached with EDTA in an octahedral complex, has coordination number ______.
Ethylene diamine tetraacetate (EDTA) ion is ______.
What are Homoleptic complexes?
How many ions are produced from the complex Co(NH3)6]Cl2 in solution?
The equivalents of ethylene diamine required to replace the neutral ligands from the coordination sphere of the trans-complex of CoCl3.4NH3 is ______. (Round off to the Nearest Integer).
The following ligand is:
What is a chelate complex?
Which of the following species cannot act as a ligand? Give reason.
Assertion (A): EDTA is a hexadentate ligand.
Reason (R): EDTA has 2 nitrogen and 4 oxygen donor atoms.
What is meant by the chelate effect? Give an example.
What is meant by the chelate effect? Give an example.
What is meant by the chelate effect? Give an example.
In the complex ion \[\ce{[CoCl(en)2ONO]+}\], the coordination number and the oxidation number of the central metal ion are ______ and ______.
Explain the following, giving two examples:
Coordination number
Give two examples of unidentate ligands.
Give two examples of ambidentate ligands.
Statement I: [Co(NH3)6]3+ is a homoleptic compleх whereas [Co(NH3)4Cl2]+ is a heteroleptic complex.
Statement II: Complex [Co(NH3)6]3+ has only one kind of ligands but [Co(NH3)4Cl2]+ has more than one kind of ligands.
In the light of the above statements, Choose the correct answer form the options given below.
