मराठी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

A coordination compound CrClX3⋅4HX2O precipitates silver chloride when treated with silver nitrate. The molar conductance of its solution corresponds to a total of two ions. Write structural formula

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प्रश्न

A coordination compound \[\ce{CrCl3.4H2O}\] precipitates silver chloride when treated with silver nitrate. The molar conductance of its solution corresponds to a total of two ions. Write structural formula of the compound and name it.

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उत्तर

If it forms silver chloride then there is one free chlorine atom outside the coordination sphere. The structural formula has to be \[\ce{[Cr(H2O)4Cl2]Cl}\]. The name of this complex is tetraaquadichlorido chromium (III) chloride.

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पाठ 9: Coordination Compounds - Exercises [पृष्ठ १२४]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 9 Coordination Compounds
Exercises | Q III. 25. | पृष्ठ १२४

संबंधित प्रश्‍न

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Coordination entity


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[PtCl2(NH3)4][PtCl4]


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Which of the following complexes are heteroleptic?

(i) \[\ce{[Cr(NH3)6]^{3+}}\]

(ii) \[\ce{[Fe(NH3)4]Cl2]^+}\]

(iii) \[\ce{[Mn(CN)6]^{4-}}\]

(iv) \[\ce{[Co(NH3)4]Cl2]}\]


Identify the correct statements for the behaviour of ethane-1, 2-diamine as a ligand.

(i) It is a neutral ligand.

(ii) It is a didentate ligand.

(iii) It is a chelating ligand.

(iv) It is a unidentate ligand.


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Column I (Complex ion) Column II (Colour)
A. \[\ce{[Co(NH3)6]^{3+}}\] 1. Violet
B. \[\ce{[Ti(H2O)6]^{3+}}\] 2. Green
C. \[\ce{[Ni(H2O)6]^{2+}}\] 3. Pale blue
D. \[\ce{(Ni(H2O)4 (en)]^{2+} (aq)}\] 4. Yellowish orange
  5. Blue

Match the coordination compounds given in Column I with the central metal atoms given in Column II and assign the correct code:

Column I (Coordination Compound) Column II (Central metal atom)
A. Chlorophyll 1. rhodium
B. Blood pigment 2. cobalt
C. Wilkinson catalyst 3. calcium
D. Vitamin B12 4. iron
  5. magnesium

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Coordination polyhedron


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What is meant by ambidentate ligand?


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