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प्रश्न
Write applications of co-ordination compounds in medicine and electroplating.
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उत्तर
Applications of coordination compounds:
1) In medicine:
- Cisplatin [PtCl2(NH3)2] is useful in treatment of cancer.
- EDTA is useful in treatment of poisoning by lead.
2) In electroplating
Stable complexes with very small dissociation in solution are used for electroplating with silver and gold.
- The complex K[Ag(CN)2] is used for electroplating with silver
- The complex K[Au(CN)2] is used for electroplating with gold
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संबंधित प्रश्न
Write the structure and IUPAC names of all the metamers represented by formula C4H10
Which of the following compounds is used as a semipermeable membrane?
(a) Potassium ferrocyanide
(b) Potassium argentocyanide
(c) Sodium meta aluminate
(d) Copper ferrocyanide
Predict the co-ordination No. of cs+ ion if `r_(Cs)^+` = 1.69Å and `r_(Cl)^-` = 1.81Å.
Write IUPAC names of the following compounds
Write IUPAC names of the following compounds:
How is Benzonitrile converted to Benzophenone?
Write structures of compounds A, B and C in of the following reactions
Write structures of compounds A, B and C in of the following reactions
Following compounds are given to you :
2-Bromopentane, 2-Bromo-2-methylbutane, 1-Bromopentane
1) Write the compound which is most reactive towards SN2 reaction.
2) Write the compound which is optically active.
3) Write the compound which is most reactive towards β-elimination reaction.
Write the structures of compounds A, B and C in the following reactions:
Write the structures of compounds A, B and C in the following reactions
Which of the following is non-ionizable?
When 0.1 mol \[\ce{CoCl3 (NH3)5}\] is treated with excess of \[\ce{AgNO3}\], 0.2 mol of \[\ce{AgCl}\] are obtained. The conductivity of solution will correspond to ______.
When 1 mol \[\ce{CrCl3.6H2O}\] is treated with excess of \[\ce{AgNO3}\], 3 mol of \[\ce{AgCl}\] are obtained. The formula of the complex is ______.
Match the coordination compounds given in Column I with the central metal atoms given in Column II and assign the correct code:
| Column I (Coordination Compound) | Column II (Central metal atom) |
| A. Chlorophyll | 1. rhodium |
| B. Blood pigment | 2. cobalt |
| C. Wilkinson catalyst | 3. calcium |
| D. Vitamin B12 | 4. iron |
| 5. magnesium |
Match the compounds given in Column I with the oxidation state of cobalt present in it (given in Column II) and assign the correct code:
| Column I (Compound) | Column II (Oxidation state of Co) |
| A. \[\ce{[Co(NCS)(NH3)5](SO3)}\] | 1. + 4 |
| B. \[\ce{[Co(NH3)4 CL2]SO4}\] | 2. 0 |
| C. \[\ce{Na4[Co(S2O3)3]}\] | 3. + 1 |
| D. \[\ce{[Co2(CO)8]}\] | 4. + 2 |
| 5. + 3 |
Which one of the following does not achieve an octet of electrons in the central atom?
Which one of the following ligands forms a chelate?
The co-ordinate number and the oxidation state of the element E in the complex [E(en)2(C2O4)]NO2 are respectively?
The complex which has no d electrons in the central atom is:-
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The correct order of the spin-only magnetic moment of metal ions in the following low spin complexes,
\[\ce{[V(CN)6]^{4-}, [Fe(CN)6]^{4-}, [Ru(NH3)6]^{3+} and [Cr(NH3)6]^2}\] is:
Which of the following species cannot act as a ligand? Give reason.
Assertion (A): EDTA is a hexadentate ligand.
Reason (R): EDTA has 2 nitrogen and 4 oxygen donor atoms.
What is meant by the chelate effect? Give an example.
What is meant by the chelate effect? Give an example.
Explain the ligand.
Explain the following, giving two examples:
Coordination polyhedron
