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प्रश्न
Write applications of co-ordination compounds in medicine and electroplating.
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उत्तर
Applications of coordination compounds:
1) In medicine:
- Cisplatin [PtCl2(NH3)2] is useful in treatment of cancer.
- EDTA is useful in treatment of poisoning by lead.
2) In electroplating
Stable complexes with very small dissociation in solution are used for electroplating with silver and gold.
- The complex K[Ag(CN)2] is used for electroplating with silver
- The complex K[Au(CN)2] is used for electroplating with gold
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संबंधित प्रश्न
Classify the following ligands into monodentate and polydentate —
- Ammonia
- Carbon monoxide
- Ethylene diamine
- Ethylene diamine tetra acetate ion
Explain the following, giving two examples:
Coordination entity
What is meant by unidentate ligand?
Predict the co-ordination No. of cs+ ion if `r_(Cs)^+` = 1.69Å and `r_(Cl)^-` = 1.81Å.
Write IUPAC names of the following compounds:
Following compounds are given to you :
2-Bromopentane, 2-Bromo-2-methylbutane, 1-Bromopentane
1) Write the compound which is most reactive towards SN2 reaction.
2) Write the compound which is optically active.
3) Write the compound which is most reactive towards β-elimination reaction.
Write structures of compounds A and B of the following reaction :
Ligand (en) is an example of ___________.
The oxidation number of Fe in K4[Fe(CN)6] is ____________.
What is the coordination number of chromium in \[\ce{[Cr(NH3)2(H2O2)2]Cl3}\]?
Which of the following is non-ionizable?
The correct \[\ce{IUPAC}\] name of \[\ce{[Pt(NH3)2Cl2]}\] is ______.
Arrange the following complexes in the increasing order of conductivity of their solution:
[Co(NH3)3Cl3], [Co(NH3)4Cl2]Cl, [Co(NH3)6]Cl3, [Cr(NH3)5Cl]Cl2
Match the complex ions given in Column I with the colours given in Column II and assign the correct code:
| Column I (Complex ion) | Column II (Colour) |
| A. \[\ce{[Co(NH3)6]^{3+}}\] | 1. Violet |
| B. \[\ce{[Ti(H2O)6]^{3+}}\] | 2. Green |
| C. \[\ce{[Ni(H2O)6]^{2+}}\] | 3. Pale blue |
| D. \[\ce{(Ni(H2O)4 (en)]^{2+} (aq)}\] | 4. Yellowish orange |
| 5. Blue |
Oxidation number of cobalt in K[Co(CO)4] is
The co-ordinate number and the oxidation state of the element E in the complex [E(en)2(C2O4)]NO2 are respectively?
According to IUPAC nomenclatures, sodium nitroprusside is named as
Which of the following ligands can exhibit linkage isomerism?
Metal attached with EDTA in an octahedral complex, has coordination number ______.
Why chelate complexes are more stable than complexes with unidentate ligands?
What are Heteroleptic complexes?
The following ligand is:
Total sodium ions which are present in one formula unit of sodium ethane-1, 2-diaminetetraacetatochromate (II) and sodium hexanitrito cobaltate (III) are ______.
Assertion (A): EDTA is a hexadentate ligand.
Reason (R): EDTA has 2 nitrogen and 4 oxygen donor atoms.
Is the central metal atom in coordination complexes a Lewis acid or a Lewis base? Explain.
What is meant by the chelate effect? Give an example.
Explain with two examples of the following:
Ligand
Explain the following, giving two examples:
Coordination number
